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Topics in Catalysis

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08.07.2020 | Original Paper

Hydrogenation of Citral on Pt/SiO₂ Catalysts: Effect of Sn Addition and Type of Solvent

verfasst von: C. A. Barrales-Cortés, H. Pérez-Pastenes, J. C. Piña-Victoria, T. Viveros-García

Erschienen in: Topics in Catalysis | Ausgabe 5-6/2020

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Abstract

This work deals with the liquid-phase hydrogenation of citral over Pt monometallic and PtSn bimetallic catalysts supported on commercial silica. Bimetallic catalysts contain different Sn/Pt molar ratio of 0.5, 1.0 and 1.5. Cyclohexane or 2-propanol were used as solvent. The catalysts were characterized by N₂-physisorption, XRD, NH₃-TPD, H₂-chemisorption, and TPR. Both XRD and TPR results showed the formation of PtSn and Pt₃Sn. The proportion of Pt–Sn alloys was related to the Sn/Pt molar ratio: the greater the Sn/Pt molar ratio, the greater the amount of PtSn alloy species. The amount of these species was related to the catalytic activity and selectivity in the hydrogenation of citral. Pt monometallic catalysts showed a high initial catalytic activity with high selectivity to citronellal. Bimetallic catalysts exhibited high activity and selectivity to unsaturated alcohols as geraniol and nerol. With cyclohexane as solvent, a greater amount of Pt₃Sn species promote consecutive hydrogenations, and with a greater amount of PtSn alloy the formation of compounds related to cyclization of citronellal was observed. The results showed that using a balanced amount of species (Pt₃Sn and PtSn) and 2-propanol as solvent, a synergic effect that promotes high activity and selectivity to geraniol and nerol was observed maintaining the same levels of selectivity along reaction time.

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Titel: Hydrogenation of Citral on Pt/SiO2 Catalysts: Effect of Sn Addition and Type of Solvent
verfasst von: C. A. Barrales-Cortés
H. Pérez-Pastenes
J. C. Piña-Victoria
T. Viveros-García
Publikationsdatum: 08.07.2020
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 5-6/2020
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-020-01312-0

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