Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2016

01.09.2016 | Original Paper

Hydrophobically associating terpolymers of acrylamide, alkyl acrylamide, and methacrylic acid as EOR thickeners

verfasst von: Sareh Dastan, Shadi Hassnajili, Elaheh Abdollahi

Erschienen in: Journal of Polymer Research | Ausgabe 9/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

N-Hexadecylacrylamide with long hydrophobic groups was reacted with acrylamide and methacrylic acid to prepare the hydrophobically modified terpolymers based on polyacrylamide (HMPAM) for polymer flooding. The HMPAM polymer was synthesized by adjusting the polymerization conditions such as initiator concentration, time, and monomer ratios. The structure of the obtained terpolymer was characterized by IR spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The results of DSC and TGA analyses revealed that the hydrophobic modification of polymer backbone enhanced the rigidity and thermal stability of the polymer. The rheological properties of the polymers were evaluated over a wide range of parameters. The results indicated that the HMPAM displayed a better performance on viscosification, interfacial tension, and salt, temperature, and shear resistance than the copolymer without hydrophobic groups (COPAM). Core flood tests showed that oil recovery could be enhanced by about 10.23 % for HMPAM versus only 4.9 % for the COPAM under equal condition of 1000 mg/L polymer.
Vorheriger Artikel Chitosan-maghemite-LiClO4 – a new green conducting superpara magnetic nanocomposite
Nächster Artikel Bio-based epoxy networks incorporating covalent and melamine cyanurate-type multiple hydrogen-bonding crosslinkages

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Lake LW (1989) Enhanced oil recovery. Prentice-Hall, Englewood Cliffs
2.
Quadri SMR, Jiran L, Shoaib M, Hashmet MR, AlSumaiti AM, Alhassan SM (2015) Application of biopolymer to improve oil recovery in high temperature high salinity carbonate reservoirs. Soc Pet Eng. doi:10.​2118/​177915-MS
3.
Quadri SMR, Shoaib M, AlSumaiti AM, Alhassan SM (2015) Screening of polymers for eor in high temperature, high salinity and carbonate reservoir conditions. Int Pet Technol Conf. doi:10.​2523/​IPTC-18436-MS
4.
Van Poollen HK (1980) Fundamentals of enhanced oil recovery. PennWell, Tulsa, Okla, p 87
5.
Yang MH (1999) The rheological behavior of polyacrylamide solution. J Polym Eng 19(5):371–381CrossRef
6.
Sabhapondit A, Borthakur A, Haque I (2003) Characterization of acrylamide polymers for enhanced oil recovery. J Appl Polym Sci 87(12):1869–1878CrossRef
7.
Vinu R, Madras G (2008) Photocatalytic degradation of poly(acrylamide-co-acrylic acid). J Phys Chem B 112(30):8928–8935CrossRef
8.
Abhijit S, Achinta B, Keka O, Ajay M (2010) Effects of alkali, salts, and surfactant on rheological behaviour of partially hydrolysed polyacrylamide solutions. J Chem Eng Data 55(10):4315–4322CrossRef
9.
Taylor KC, Nasr-El-Din HA (1998) Water-soluble hydrophobically associating polymers for improved oil recovery: a literature review. J Pet Sci Eng 19:265–280CrossRef
10.
Shashkina YA, Zaroslov YD, Smirnov VA, Philippova OE, Khokhlov AR, Pryakhina TA et al (2003) Hydrophobic aggregation in aqueous solutions of hydrophobically modified polyacrylamide in the vicinity of overlap concentration. Polymer 44(8):2289–2293CrossRef
11.
Feng YJ, Billon L, Grassl B, Bastiat G, Borisov O, François J (2005) Hydrophobically associating polyacrylamides and their partially hydrolyzed derivatives prepared by post-modification. 2. Properties of non-hydrolyzed polymers in pure water and brine. Polymer 46(22):9283–9295CrossRef
12.
Zhong C, Huang R, Xu J (2008) Characterization, solution behavior, and microstructure of a hydrophobically associating nonionic copolymer. J Solut Chem 37:1227–1243CrossRef
13.
Wever DAZ, Picchioni F, Broekhuisa AA (2011) Polymers for enhanced oil recovery: a paradigm for structure property relationship in aqueous solution. Prog Polym Sci 36:1558–1628CrossRef
14.
Guo Y, Liu J, Zhang X, Feng R, Li H, Zhang J, Lv X, Luo P (2012) Solution property investigation of combination flooding systems consisting of gemini-non-ionic mixed surfactant and hydrophobically associating polyacrylamide for enhanced oil recovery. Energy Fuel 26:2116–2123CrossRef
15.
Guillaume D, David R, Rene T, Bruno G (2010) How to get the best out of hydrophobically associative polymers for IOR? New experimental insights. SPE Improved Oil Recovery Symposium, 129884
16.
Lai N, Dong W, Ye Z, Dong J, Qin X, Chen W, Ke C (2013) A water-soluble acrylamide hydrophobically associating polymer: synthesis, characterization, and properties as EOR chemical. J Appl Polym Sci 129:1888–1896CrossRef
17.
Liu X, Jiang W, Gou S, Ye Z, Feng M, Lai N, Liang L (2013) Synthesis and evaluation of novel water-soluble copolymers based on acrylamide and modular β-cyclodextrin. Carbohydr Polym 96:47–56CrossRef
18.
Volpert E, Selb J, Candau F (1996) Influence of the hydrophobe structure on composition, microstructure, and rheology in associating polyacrylamides prepared by micellar copolymerization. Macromolecules 29:1452–1463CrossRef
19.
Candau F, Selb J (1999) Hydrophobically-modified polyacrylamides prepared by micellar polymerization. Adv Colloid Interf Sci 79:149–172CrossRef
20.
Lara-Ceniceros AC, Rivera-Vallejo C, Jimenez-Regalado EJ (2007) Synthesis, characterization and rheological properties of three different associative polymers obtained by micellar polymerization. Polym Bull 58:425–433CrossRef
21.
Zhong C, Wang W, Yang M (2012) Synthesis and solution properties of an associative polymer with excellent salt-thickening. J Appl Polym Sci 125:4049–4059CrossRef
22.
Zhong C, Jiang L, Peng X (2010) Synthesis and solution behavior of comb-like terpolymers with poly(ethylene oxide) macromonomer. J Polym Sci Part A Polym Chem 48:1241–1250CrossRef
23.
Zhang P, Wang Y, Chen W, Yu H, Qi Z, Li K (2011) Preparation and solution characteristics of a novel hydrophobically associating terpolymer for enhanced oil recovery. J Solut Chem 40:447–457CrossRef
24.
Vittadello ST, Biggs S (1998) Shear history effects in associative thickener solutions. Macromolecules 31:7691–7697CrossRef
25.
Abu-Sharkh BF, Yahaya GO, Ali SA, Kazi IW (2001) Solution and interfacial behavior of hydrophobically modified water-soluble block copolymers of acrylamide and N-phenethyl acrylamide. J Appl Polym Sci 82:467–476CrossRef
26.
Gao B, Xu R, Yu S, Xu L, Ge Z (2004) Studies on microstructure and aqueous solution properties of block copolymer of acrylamide-styrene. Colloid Polym Sci 282:1008–1015CrossRef
27.
Yahaya GO, Ahdab AA, Ali SA, Abu-Sharkh BF, Hamad EZ (2001) Solution behavior of hydrophobically associating water-soluble blockcopolymers of acrylamide and N-benzylacrylamide. Polymer 42:3363–3372CrossRef
28.
Shi LT, Li C, Zhu SS, Xu J, Sun BZ, Ye ZB (2013) Study on properties of branched hydrophobically modified polyacrylamide for polymer flooding. Journal of Chemistry 2013, Article ID 675826.
29.
Kuang W, Xia Y (2014) A novel dendritic-like terpolymer as a viscosifying additive for enhanced oil recovery. Mater Lett 115:109–112CrossRef
30.
Branham KD, Davis DL, Middleton JC, McCormick CL (1994) Water-soluble polymers: 59. Investigation of the effects of polymer microstructure on the associative behaviour of amphiphilic terpolymers of acrylamide, acrylic acid and N-[(4-decyl)phenyl]acrylamide. Polymer 35:4429–4436CrossRef
31.
Vignes R (2000) Dimethyl sulfoxide (DMSO): a “new” clean, unique, superior solvent. American Chemical Society annual meeting, Washington, DC
32.
Garay-Jimenez JC, Young A, Gergeres D, Greenhalgh K, Turos E (2008) Methods for purifying and detoxifying sodium dodecyl sulfate-stabilized polyacrylate nanoparticles. Nanomedicine 4(2):98–105
33.
Bai F, Yang X, Huang W (2004) Synthesis of narrow or monodisperse poly(divinylbenzene) microspheres by distillation-precipitation polymerization. Macromolecules 37:9746–9752.
34.
McCormick CL, Nonaka T, Johnson CB (1988) Water-soluble copolymers: 27. Synthesis and aqueous solution behavior of associative acrylamide/N-alkylacrylamide copolymers. Polymer 29:731–739CrossRef
35.
Xue W, Hamley IW, Castelletto V, Olmsted PD (2004) Synthesis and characterization of hydrophobically modified polyacrylamides and some observations on rheological properties. Eur Polym J 40:47–56CrossRef
36.
Smith GL, McCormick CL (2001) Water-soluble polymers. 80. Rheological and photophysical studies of ph-responsive terpolymers containing hydrophobic twin-tailed acrylamide monomers. Macromolecules 34:5579–5586CrossRef
37.
Hassanajili S, Abdolahi E (2013) Influence of various reaction media on the thermal and rheological properties of poly(acrylamide-co-N-hexadecylacrylamide). J Appl Polym Sci 131:39939
38.
Maia AMS, Borsali R, Balaban RC (2009) Comparison between a polyacrylamide and a hydrophobically modified polyacrylamide flood in a sandstone core. Mater Sci Eng C 29:505–509CrossRef
39.
Alameri W, Teklu TW, Graves RM, Kazemi H, AlSumaiti AM (2014) Wettability alteration during low-salinity waterflooding in carbonate reservoir cores. Soc Pet Eng. doi:10.​2118/​171529-MS
40.
Al-sumaiti Ali M, Kazemi H (2012) Experimental and numerical modeling of double displacement oil recovery process in tight fractured carbonate reservoirs. Soc Pet Eng. doi:10.​2118/​161186-MS
41.
Alameri W, Teklu TW, Graves RM, Kazemi H, AlSumaiti AM (2015) Experimental and numerical modeling of low-salinity waterflood in a low permeability carbonate reservoir. Soc Pet Eng. doi:10.​2118/​174001-MS
42.
Liu XJ, Jiang WC, Gou SH, Ye ZB, Xie XD (2012) Synthesis and evaluation of a water-soluble acrylamide binary sulfonates copolymer on MMT crystalline interspace and EOR. J Appl Polym Sci 125:1252–1260CrossRef
43.
Awolayo A, Sarma H, AlSumaiti AM (2014) A laboratory study of ionic effect of smart water for enhancing oil recovery in carbonate reservoirs. Soc Pet Eng. doi:10.​2118/​169662-MS
44.
Lin Y, Leijun M, Ronghua H (2001) Synthesis and aqueous solution behavior of hydrophobically modified polyelectrolytes. J Appl Polym Sci 82:3552–3557CrossRef
45.
46.
Gao B, Guo H, Wang J, Zhang Y (2008) Preparation of hydrophobic association polyacrylamide in a new micellar copolymerization system and its hydrophobically associative property. Macromolecules 41:2890–2897CrossRef
47.
Avoce D, Liu HY, Zhu XX (2003) N-Alkylacrylamide copolymers with (meth)acrylamide derivatives of cholic acid: synthesis and thermosensitivity. Polymer 44:1081–1087CrossRef
48.
Shena Y, Zhanga X, Lub J, Zhanga A, Chena K, Li X (2009) Effect of chemical composition on properties of pH-responsive poly(acrylamide-co-acrylic acid) microgels prepared by inverse microemulsion polymerization. Colloids Surf A 350:87–90CrossRef
49.
Yang ZL, Gao BY, Li CX, Yue QY, Liu B (2010) Synthesis and characterization of hydrophobically associating cationic polyacrylamide. Chem Eng J 161:27–33CrossRef
50.
Li G, Gong X, Wang C, Li N, Wang Z (2013) Study on preparation and associative properties of fluorinated hydrophobically associating polyacrylamide. J Polym Res 20:200CrossRef
51.
Wang C, Li X, Li P, Niu Y, Yang X (2013) Preparation and self-assembly properties of silicone-modified hydrophobically associating polyacrylamide. J Polym Res 20:147CrossRef
52.
Zhong C, Luo P, Ye Z, Chen H (2009) Characterization and solution properties of a novel water-soluble terpolymer for enhanced oil recovery. Polym Bull 62:79–89CrossRef
53.
Ghannam M, Esmail N (2002) Flow behavior of enhanced oil recovery alcoflood polymers. J Appl Polym Sci 85(14):2896–2904CrossRef
54.
Martel KE, Martel R, Lefebvre R, Ge´linas PJ (1998) Laboratory study of polymer solutions used formobility control during in situ NAPL recovery. Ground Water Monit Rem 18(2):103–113CrossRef
55.
Healy RN, Reed RL (1974) Physicochemical aspects of microemulsion flooding. Soc Petrol Eng J 14:491–50CrossRef
56.
Cayias JL, Schechter RS, Wade WH (1976) Modeling crude oils for low interfacial tension. Soc Petrol Eng J 16(06):351–357CrossRef
57.
Wang X, Li L (2016) How does the anionic surfactant SDS affect the association of hydrophobically end-modified PNIPAM chains in aqueous solution? Polymer 88:123–132CrossRef
58.
Li Y, Kwak JCT (2003) Rheology and binding studies in aqueous systems of hydrophobically modified acrylamide and acrylic acid copolymers and surfactants. Colloids Surf A 225:169–180CrossRef
59.
Biggs S, Selb J, Candau F (1992) Effect of surfactant on the solution properties of hydrophobically modified polyacrylamide. Langmuir 8:838–847CrossRef
60.
Zhou H, Song GQ, Zhang YX, Chen JY, Jiang M, Hogen-Esch TE, Dieing R, Ma L, Haeussling L (2001) Hydrophobically modified polyelectrolytes. 4. Synthesis and solution properties of fluorocarbon-containing poly(acrylic acid). Macromol Chem Phys 202:3057–3064CrossRef
61.
Zhuang DQ, Da JCAH, Zhang YX, Dieing R, Ma L, Haeussling L (2001) Hydrophobically modified polyelectrolytes II: synthesis and characterization of poly(acrylic acid-co-alkylacrylate). Polym Adv Technol 12:616–625CrossRef
62.
Moeini F, Hemmati-Sarapardeh A, Ghazanfari MH, Masihi M, Ayatollahi S (2014) Toward mechanistic understanding of heavy crude oil/brine interfacial tension: the roles of salinity, temperature and pressure. Fluid Phase Equilib 375:191–200CrossRef
Metadaten
Titel
Hydrophobically associating terpolymers of acrylamide, alkyl acrylamide, and methacrylic acid as EOR thickeners
verfasst von
Sareh Dastan
Shadi Hassnajili
Elaheh Abdollahi
Publikationsdatum
01.09.2016
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2016
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-1058-6

Weitere Artikel der Ausgabe 9/2016

Journal of Polymer Research 9/2016 Zur Ausgabe

ORIGINAL PAPER

One-pot synthesis of poly-(3-hexylthiophene) with variable degrees of molar mass and regioregularity

ORIGINAL PAPER

Positron annihilation spectroscopy and mechanical properties studies for epoxy matrices reinforced with different nanoparticles

REVIEW PAPER

Prospects of conducting polymer and graphene as counter electrodes in dye-sensitized solar cells

ORIGINAL PAPER

Structural color of polymeric physical gels

ORIGINAL PAPER

Synthesis and dynamic mechanical study of core–shell structure epoxy/polyacrylate composite particle

Short Communication

Replacement of surface roughening using polyvinyl alcohol coating in the fabrication of nafion-based ionic polymer metal composite (IPMC) actuators

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise