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Erschienen in: Cellulose 12/2021

04.07.2021 | Original Research

Immobilization of nZVI particles on cotton fibers for rapid decolorization of organic dyes

Erschienen in: Cellulose | Ausgabe 12/2021

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Abstract

Nanoscale zero-valent iron (nZVI) particles have been frequently used to treat pollutants as an excellent reactive nanomaterial in last two decades. However, loading nZVI particles on the substrate with large surface area, easy handling and in particular, production on a large scale is still a problem. Herein, a facile approach was developed for in-situ preparation of nanoscale zero-valent iron (nZVI) particles on cotton fibers at room temperature. The cotton fabric was firstly oxidized to generate carboxylic groups for complexing ferric ions. Then, nZVI particles were immobilized on cotton fabric by reducing agent sodium borohydride. The nZVI immobilized cotton fabric (nZVI@cotton fabric) was thoroughly characterized and could decolorize more than 96% methylene blue and brilliant green within 40 min, respectively. The sorption isotherm study revealed that the reactive sorption of methylene blue on nZVI@cotton fabric fits the Freundlich model. The degradation intermediates of methylene blue were identified by HPLC/MS and possible degradation pathway was proposed. The method of immobilizing nZVI particles on carboxylated cotton fibers may be promising to prepare fibrous, easy handling reactive compounds for environmental remediation.

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Metadaten
Titel
Immobilization of nZVI particles on cotton fibers for rapid decolorization of organic dyes
Publikationsdatum
04.07.2021
Erschienen in
Cellulose / Ausgabe 12/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-021-03993-6

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