Skip to main content
Erschienen in: Clean Technologies and Environmental Policy 6/2015

01.08.2015 | Original Paper

Impact of process conditions on preparation of porous carbon from date palm seeds by KOH activation

verfasst von: K. Suresh Kumar Reddy, Ahmed Al Shoaibi, C. Srinivasakannan

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 6/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Date palm seed being one of the major waste biomass produced in UAE, is assessed for its potential to be an appropriate precursor for preparation of porous carbon by utilizing KOH as an activating agent through application of process optimization. Process optimization was performed using the popular response surface methodology adopting a Box–Behnken design, to maximize porous carbon BET surface area and % yield, by altering activation temperature, activation time and impregnation ratio. The chemical reactions involved during the impregnation and the carbonization processes for these hydroxide/lignocellulose mixtures present in date palm seed have been proposed. A deep insight has been obtained concerning the possible reactions mechanism. The adsorption capacity was estimated using Iodine adsorption, which infers micropore nature of the porous carbon and it can be utilized for an effective waste water treatment with smaller molecular size substrates.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Adinata D, Daud WMWA, Aroua MK (2007) Preparation and characterization of activated carbon from palm shell by chemical activation with K2CO3. Bioresour Technol 98(1):145–149CrossRef Adinata D, Daud WMWA, Aroua MK (2007) Preparation and characterization of activated carbon from palm shell by chemical activation with K2CO3. Bioresour Technol 98(1):145–149CrossRef
Zurück zum Zitat Baquero MC, Giraldo L, Moreno JC, Suraz-Garcia F, Martinez-Alonso A, Tascon JMD (2003) Activated carbons by pyrolysis of coffee bean husks in presence of phosphoric acid. J Anal Appl Pyrol 70(2):779–784CrossRef Baquero MC, Giraldo L, Moreno JC, Suraz-Garcia F, Martinez-Alonso A, Tascon JMD (2003) Activated carbons by pyrolysis of coffee bean husks in presence of phosphoric acid. J Anal Appl Pyrol 70(2):779–784CrossRef
Zurück zum Zitat El-Hendawy AA (2009) An insight into the KOH activation mechanism through the production of microporous activated carbon for the removal of Pb2+ cations. Appl Surf Sci 255(6):3723–3730CrossRef El-Hendawy AA (2009) An insight into the KOH activation mechanism through the production of microporous activated carbon for the removal of Pb2+ cations. Appl Surf Sci 255(6):3723–3730CrossRef
Zurück zum Zitat El-Naas MH, Al-Zuhair S, Abu Alhaija M (2010) Reduction of COD in refinery wastewater through adsorption on date-pit activated carbon. J Hazardous Mater 173(1–3):750–757CrossRef El-Naas MH, Al-Zuhair S, Abu Alhaija M (2010) Reduction of COD in refinery wastewater through adsorption on date-pit activated carbon. J Hazardous Mater 173(1–3):750–757CrossRef
Zurück zum Zitat Gonen F, Aksu Z (2008) Use of response surface methodology (RSM) in the evaluation of growth and copper (II) bioaccumulation properties of candida utilis in molasses medium. J Hazardous Mater 154(1–3):731–738CrossRef Gonen F, Aksu Z (2008) Use of response surface methodology (RSM) in the evaluation of growth and copper (II) bioaccumulation properties of candida utilis in molasses medium. J Hazardous Mater 154(1–3):731–738CrossRef
Zurück zum Zitat Guo J, Luo Y, Chong Lua A, Chi R, Chen Y, Bao X, Xiang S (2007) Adsorption of hydrogen sulphide (H2S) by activated carbons derived from oil-palm shell. Carbon 45(2):330–336CrossRef Guo J, Luo Y, Chong Lua A, Chi R, Chen Y, Bao X, Xiang S (2007) Adsorption of hydrogen sulphide (H2S) by activated carbons derived from oil-palm shell. Carbon 45(2):330–336CrossRef
Zurück zum Zitat Hameed BH, Tan IAW, Ahmed AL (2008) Optimization of basic dye removal by oil palm fiber-based activated carbon using response surface methodology. J Hazardous Mater 158(2–3):324–332CrossRef Hameed BH, Tan IAW, Ahmed AL (2008) Optimization of basic dye removal by oil palm fiber-based activated carbon using response surface methodology. J Hazardous Mater 158(2–3):324–332CrossRef
Zurück zum Zitat Hameed BH, Salman JM, Ahmad AL (2009) Adsorption isotherm and kinetic modeling of 2, 4-D pesticide on activated carbon derived from date stones. J Hazardous Mater 163(1):121–126CrossRef Hameed BH, Salman JM, Ahmad AL (2009) Adsorption isotherm and kinetic modeling of 2, 4-D pesticide on activated carbon derived from date stones. J Hazardous Mater 163(1):121–126CrossRef
Zurück zum Zitat Hebeish A, Ramadan MA, Abdel-Halim E, Abo-Okeil A (2011) An effective adsorbent based on sawdust for removal of direct dye from aqueous solutions. Clean Technol Environ Policy 13(5):713–718CrossRef Hebeish A, Ramadan MA, Abdel-Halim E, Abo-Okeil A (2011) An effective adsorbent based on sawdust for removal of direct dye from aqueous solutions. Clean Technol Environ Policy 13(5):713–718CrossRef
Zurück zum Zitat Kashif R, Suresh Kumar reddy K, Shoaibi AA, Srinivasakannan C (2013) Sulfur-impregnated porous carbon for removal of mercuric chloride: optimization using RSM. Clean Technol Environ Policy 15(6):1041–1048CrossRef Kashif R, Suresh Kumar reddy K, Shoaibi AA, Srinivasakannan C (2013) Sulfur-impregnated porous carbon for removal of mercuric chloride: optimization using RSM. Clean Technol Environ Policy 15(6):1041–1048CrossRef
Zurück zum Zitat Lyubchik SB, Benoit R, Beguin F (2002) Influence of chemical modifications of anthracite on the porosity of the resulting activated carbons. Carbon 40(8):1287–1294CrossRef Lyubchik SB, Benoit R, Beguin F (2002) Influence of chemical modifications of anthracite on the porosity of the resulting activated carbons. Carbon 40(8):1287–1294CrossRef
Zurück zum Zitat Prahas D, Kartika Y, Indraswati N, Ismadji S (2008) Activated carbon from jackfruit peel waste by H3PO4 chemical activation: pore structure and surface chemistry characterization. Chem Eng J 140(1–3):32–42CrossRef Prahas D, Kartika Y, Indraswati N, Ismadji S (2008) Activated carbon from jackfruit peel waste by H3PO4 chemical activation: pore structure and surface chemistry characterization. Chem Eng J 140(1–3):32–42CrossRef
Zurück zum Zitat Rashidi NA, Yusup S, Borhan A, Loong LH (2014) Experimental and modeling studies of carbon dioxide adsorption by porous biomass derived activated carbon. Clean Technol Environ Policy 16(7):1353–1361CrossRef Rashidi NA, Yusup S, Borhan A, Loong LH (2014) Experimental and modeling studies of carbon dioxide adsorption by porous biomass derived activated carbon. Clean Technol Environ Policy 16(7):1353–1361CrossRef
Zurück zum Zitat Salam JM, Njoku VO, Hameed BH (2011) Bentazon and carbofuran adsorption onto date seed activated carbon: kinetics and equilibrium. Chem Eng J 173(2):361–368CrossRef Salam JM, Njoku VO, Hameed BH (2011) Bentazon and carbofuran adsorption onto date seed activated carbon: kinetics and equilibrium. Chem Eng J 173(2):361–368CrossRef
Zurück zum Zitat Sentorun-shalaby C, Ucak-Astalioglu MG, Artok L, Sarici C (2006) Preparation and characterization of activated carbons by one step steam pyrolysis/activation from apricot stones. Microporous Mesoporous Mater 88:126–134CrossRef Sentorun-shalaby C, Ucak-Astalioglu MG, Artok L, Sarici C (2006) Preparation and characterization of activated carbons by one step steam pyrolysis/activation from apricot stones. Microporous Mesoporous Mater 88:126–134CrossRef
Zurück zum Zitat Sudaryanto Y, Hartono SB, Irawaty W, Hindarso H, Ismadji S (2006) High surface area activated carbon prepared from cassava peel by chemical activation. Bioresour Technol 97(5):734–739CrossRef Sudaryanto Y, Hartono SB, Irawaty W, Hindarso H, Ismadji S (2006) High surface area activated carbon prepared from cassava peel by chemical activation. Bioresour Technol 97(5):734–739CrossRef
Zurück zum Zitat Suresh Kumar Reddy K, Shoaibi AA, Srinivasakannan C (2012a) A comparison of microstructure and adsorption characteristics of activated carbons by CO2 and H3PO4 activation from date palm pits. New Carbon Mater 27(5):344–351CrossRef Suresh Kumar Reddy K, Shoaibi AA, Srinivasakannan C (2012a) A comparison of microstructure and adsorption characteristics of activated carbons by CO2 and H3PO4 activation from date palm pits. New Carbon Mater 27(5):344–351CrossRef
Zurück zum Zitat Suresh Kumar Reddy K, Shoaibi AA, Srinivasakannan C (2012b) Activated carbon from date palm seed: process optimization using response surface methodology. Waste Biomass Valor 3:149–156CrossRef Suresh Kumar Reddy K, Shoaibi AA, Srinivasakannan C (2012b) Activated carbon from date palm seed: process optimization using response surface methodology. Waste Biomass Valor 3:149–156CrossRef
Zurück zum Zitat Tan IAW, Hameed BH, Ahmad AL (2008) Optimization of preparation conditions for activated carbons from coconut husk using response surface methodology. Chem Eng J 137(3):462–470CrossRef Tan IAW, Hameed BH, Ahmad AL (2008) Optimization of preparation conditions for activated carbons from coconut husk using response surface methodology. Chem Eng J 137(3):462–470CrossRef
Zurück zum Zitat Wang J, Kaskel S (2012) KOH activation of carbon-based materials for energy storage. J Mater Chem 22:23710–23725CrossRef Wang J, Kaskel S (2012) KOH activation of carbon-based materials for energy storage. J Mater Chem 22:23710–23725CrossRef
Zurück zum Zitat Wang H, Gao Q, Hu J (2009) High hydrogen storage capacity of porous carbons prepared by using activated carbon. J Am Chem Soc 131(20):7016–7022CrossRef Wang H, Gao Q, Hu J (2009) High hydrogen storage capacity of porous carbons prepared by using activated carbon. J Am Chem Soc 131(20):7016–7022CrossRef
Zurück zum Zitat Yang T, Lua AC (2003) Characteristics of activated carbons prepared from pistachio-nut shells by physical activation. J Colloid Interface Sci 267(2):408–417CrossRef Yang T, Lua AC (2003) Characteristics of activated carbons prepared from pistachio-nut shells by physical activation. J Colloid Interface Sci 267(2):408–417CrossRef
Zurück zum Zitat Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, Celzard A (2011) Optimization of activated carbon for hydrogen storage. Int J Hydrogen Energ 36(18):11746–11751CrossRef Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, Celzard A (2011) Optimization of activated carbon for hydrogen storage. Int J Hydrogen Energ 36(18):11746–11751CrossRef
Zurück zum Zitat Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, Celzard A (2012) Impact of synthesis conditions of KOH activated carbons on their hydrogen storage capacities. Int J Hydrogen Energy 37(19):14278–14284CrossRef Zhao W, Fierro V, Zlotea C, Aylon E, Izquierdo MT, Latroche M, Celzard A (2012) Impact of synthesis conditions of KOH activated carbons on their hydrogen storage capacities. Int J Hydrogen Energy 37(19):14278–14284CrossRef
Metadaten
Titel
Impact of process conditions on preparation of porous carbon from date palm seeds by KOH activation
verfasst von
K. Suresh Kumar Reddy
Ahmed Al Shoaibi
C. Srinivasakannan
Publikationsdatum
01.08.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Clean Technologies and Environmental Policy / Ausgabe 6/2015
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI
https://doi.org/10.1007/s10098-014-0875-8

Weitere Artikel der Ausgabe 6/2015

Clean Technologies and Environmental Policy 6/2015 Zur Ausgabe