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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 12/2021

01.12.2021 | Original Paper

Impact of ZnCdS/M (M = Co, Fe, Mn, V) doping on the structure and optical properties of PVA/PVP polymer

verfasst von: Zein K. Heiba, Mohamed Bakr Mohamed, A. M. El-naggar, Y. Altowairqi, A. M. Kamal

Erschienen in: Journal of Polymer Research | Ausgabe 12/2021

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Abstract

Nano Zn0.75Cd0.25S and Zn0.65Cd0.25M0.1S (M = Co, Fe, Mn, V) doped 70%PVA/30%PVP polymer blends were formed. The synchrotron x-ray diffraction was employed to investigate the nature of the nanofiller. Rietveld analysis of x-ray diffraction data revealed a single ZnS phase for the nanofillers and confirmed the inclusion of the M-metal into the ZnS lattice. SEM images of PVA/PVP doped blends revealed uniform film morphology and nanofiller distribution. The highest transmittance (90%) was observed in the undoped blend at the visible region, and it decreased as the PVA/PVP doped with the nanofiller reached its minimum value (15%) as the blend doped with Zn0.75Cd0.25S (ZCS). The refractive index value of blended polymer changed in the order 0.750.25ZCS > ZCS/Co > ZCS/Mn > ZCS/V > ZCS/Fe > undoped blended polymer at 600 nm. The highest dielectric values were observed in PVA/PVP blend doped with ZSC/Mn or ZSC/Co. The nonlinear optical parameters reached their highest value in UV and visible regions as the blended polymer doped with ZSC/Mn and ZCS, respectively. The emitted colors of different blended polymers and their intensities were depended on the kind of nanofillers and the excitation wavelengths.
Vorheriger Artikel Recycled high performance polyester fibers for cement designed from micromechanics theory
Nächster Artikel Effect of a novel bio-based β-nucleating agent on the properties of isotactic polypropylene

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Metadaten
Titel
Impact of ZnCdS/M (M = Co, Fe, Mn, V) doping on the structure and optical properties of PVA/PVP polymer
verfasst von
Zein K. Heiba
Mohamed Bakr Mohamed
A. M. El-naggar
Y. Altowairqi
A. M. Kamal
Publikationsdatum
01.12.2021
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 12/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02840-3

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