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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2019

07.03.2019 | Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

In situ sol–gel preparation of ZrO2 in nano-composite polymer electrolyte of PVDF-HFP/MG49 for lithium-ion polymer battery

verfasst von: Lee Tian Khoon, Mark-Lee Wun Fui, Nur Hasyareeda Hassan, Mohd Sukor Su’ait, Raman Vedarajan, Noriyoshi Matsumi, Mohammad Bin Kassim, Loh Kee Shyuan, Azizan Ahmad

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2019

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Abstract

Nano-composite polymer electrolyte (NCPE), poly(vinylidenefluoride-hexafluoropropylene)-poly(methylmethacrylate) grafted natural rubber with lithium tetrafluoroborate and zirconia (PVdF-HFP/MG49-LiBF4-ZrO2) was prepared by a facile one-pot in situ sol–gel method. The influence of zirconia nano-fillers on the electrochemical, chemical and structural properties of polymer electrolyte was investigated. The interaction of polymer electrolyte and zirconia was explored via density functional theory (DFT). Electrochemical impedance spectroscopy study showed that the optimum ionic conductivity is 2.39 × 10−3 S cm−1 (6 wt% zirconia). X-ray diffractogram results revealed a decreasing trend of crystalline phases and no lithium salt peaks were observed upon the addition of zirconia. As a result, the LiBF4 salt was well-solvated in the polymer matrix with a one-fold increase in lithium transference number. Remarkably, a good electrochemical stability was achieved at 6.9 V from a linear sweep voltammetry (LSV) analysis. Observations from the infrared spectra indicate that chemical interactions occurred at the carbonyl and fluoride functional groups and is further corroborated by DFT studies. Micrograph images showed that the zirconia nano-particles were successfully produced (7–15 nm). The nanocomposite polymer electrolyte possesses promising charge/discharge performance and has the potential to be applied in lithium-ion polymer battery.
Vorheriger Artikel Sol-gel mediated synthesis of silica nanoparticle from Bambusa vulgaris leaves and its environmental applications: kinetics and isotherms studies
Nächster Artikel Sol-gel-assisted preparation of SiO2@Co3O4 heterostructure from laboratory glass waste as a potential anode for lithium-ion battery

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Metadaten
Titel
In situ sol–gel preparation of ZrO2 in nano-composite polymer electrolyte of PVDF-HFP/MG49 for lithium-ion polymer battery
verfasst von
Lee Tian Khoon
Mark-Lee Wun Fui
Nur Hasyareeda Hassan
Mohd Sukor Su’ait
Raman Vedarajan
Noriyoshi Matsumi
Mohammad Bin Kassim
Loh Kee Shyuan
Azizan Ahmad
Publikationsdatum
07.03.2019
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2019
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-019-04936-1

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