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Journal of Materials Science

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21.05.2018 | Energy materials

Influence of cation doping (Li⁺, Na⁺, K⁺) on photocatalytic activity of MIL-53(Fe)

verfasst von: Prince George, Kamini Chaudhari, Pradip Chowdhury

Erschienen in: Journal of Materials Science | Ausgabe 16/2018

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Abstract

The work highlights the influence of cation doping on photocatalytic activity of MIL-53(Fe) in artificial light. The effect of intrinsic factors, viz. band-gap energy, electron conductivity and surface area, influencing photocatalysis was studied in detail w.r.t. the degradation of brilliant green dye both in the presence and in the absence of H₂O₂ as an electron scavenger. Reduction in band gap after cation doping was observed for Li⁺ (1.81 eV), Na⁺ (1.875 eV) and K⁺ (1.89 eV) when compared with the parent MIL-53(Fe) (1.95 eV). However, the photoactivity of the synthesized materials was in the following progression: MIL-53(Fe)(81.6%) > Li-MIL-53(Fe)(27.6%) > Na-MIL-53(Fe)(25.77%) > K-MIL-53(Fe) (24.18%). Effect of structural distortions in the octahedral backbone of MIL-53(Fe) due to cation doping was inferred as the plausible reason behind such behavior. The degree of electron delocalization and specific surface areas were found to be in the following progression: Na-MIL-53(Fe) (very low, 7.72 m² g⁻¹) < K-MIL-53(Fe) (low, 28.38 m² g⁻¹) < Li-MIL-53(Fe) (moderate, 42.14 m² g⁻¹) < MIL-53(Fe) (high, 51.71 m² g⁻¹), indicating that the intrinsic material properties have combinatorial influence on photocatalytic activity.

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Titel: Influence of cation doping (Li+, Na+, K+) on photocatalytic activity of MIL-53(Fe)
verfasst von: Prince George
Kamini Chaudhari
Pradip Chowdhury
Publikationsdatum: 21.05.2018
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 16/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-018-2443-9

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