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Journal of Materials Science
Erschienen in: Journal of Materials Science 14/2018

12.04.2018 | Composites

Influence of Ionic Liquid-Based Metal–Organic Hybrid on Thermal Degradation, Flame Retardancy, and Smoke Suppression Properties of Epoxy Resin Composites

verfasst von: Fei Xiao, Kun Wu, Fubin Luo, Sa Yao, Maoping Lv, Haimei Zou, Mangeng Lu

Erschienen in: Journal of Materials Science | Ausgabe 14/2018

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Abstract

A new multifunctional ionic liquid-based metal–organic hybrid (PMAIL) was synthesized by anion exchange between as-synthesized phosphonate-based ionic liquid and phosphomolybdic acid and applied to epoxy resin (EP) as an efficient flame retardant. As expected, with only 1 wt% addition of PMAIL, the char yield of EP-PMAIL1 composite at 700 °C was significantly improved by 108.3% from 12.0% for neat epoxy resin to 25.0%, demonstrating the outstanding catalytic charring effect of PMAIL. Meanwhile, EP-PMAIL6 composite (6 wt% addition) can reach V-0 rating in the UL-94 vertical burning tests easily, and its peak heat release rate and total smoke production of EP-PMAIL6 were dropped by 31.0 and 15.4%, respectively, compared with neat EP. Moreover, the results from cone calorimetry tests showed that the char yield of EP-PMAIL6 was enhanced by 162% from 9.5 to 24.9% compared with neat EP, resulting in a strong intumescent char layer structure with outstanding fire retardance and mechanical properties. The thermo-oxidative stable protective layer retarded the transfer of heat and flammable volatiles during combustion and protected the epoxy matrix from further degradation. In conclusion, our results might provide a new perspective for producing composites with excellent flame retardancy and smoke suppression properties using ionic liquid-based metal–organic hybrid.
Vorheriger Artikel Implementation of functionalized multiwall carbon nanotubes on magnetorheological elastomer
Nächster Artikel Flexible electrospun MWCNTs/Ag3PO4/PAN ternary composite fiber membranes with enhanced photocatalytic activity and stability under visible-light irradiation

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Metadaten
Titel
Influence of Ionic Liquid-Based Metal–Organic Hybrid on Thermal Degradation, Flame Retardancy, and Smoke Suppression Properties of Epoxy Resin Composites
verfasst von
Fei Xiao
Kun Wu
Fubin Luo
Sa Yao
Maoping Lv
Haimei Zou
Mangeng Lu
Publikationsdatum
12.04.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 14/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2318-0

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