Skip to main content
Erschienen in: Journal of Materials Science: Materials in Electronics 11/2012

01.11.2012

Influence of TiO2 nanoparticles on the photovoltaic efficiency of the ITO/PEDOT:PSS/fluorine copolymers/polythiophene: TiO2/Al architecture

verfasst von: E. Gondek, Y. Djaoued, J. Robichaud, P. Karasiński, I. V. Kityk, A. Danel, K. J. Plucinski

Erschienen in: Journal of Materials Science: Materials in Electronics | Ausgabe 11/2012

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Results of a study on the application of a copolymer of fluorine as acceptor and 1H-pyrazolo[3,4-b]quinoxaline as a donor in bulk heterojunction solar cells are given. To the best of our knowledge, 1H-pyrazolo[3,4-b]quinoxaline co-polymers were not applied in organic photovoltaic devices yet. Organic photovoltaic devices as well as devices of active layers with TiO2 nanocrystals of different crystallite size were investigated. The methods of polymer and TiO2 nanocrystllites synthesis are presented and their physical properties are given. The fabricated photovoltaic structures possess high values of U oc voltage as as well as relatively high parameters of I sc currents. The maximally achieved parameters corresponded to open circuit voltage U oc  = 1.13[V], and short current density Isc = 33.49[μA] under illumination 1,3 [μW cm−2], which correspond to energy conversion efficiency equal to about 0.80 %. The TiO2 nanocrystallites play a crucial role in the photovoltaics parameters.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat E. Hymakis, I. Alexandrou, G.A.J. Amaratunga, High open-circuit voltage photovoltaic devices from carbon-nanotube-polymer composites. J. Appl. Phys. 93, 1764–1768 (2003)CrossRef E. Hymakis, I. Alexandrou, G.A.J. Amaratunga, High open-circuit voltage photovoltaic devices from carbon-nanotube-polymer composites. J. Appl. Phys. 93, 1764–1768 (2003)CrossRef
2.
Zurück zum Zitat C.N. Hoth, S.A. Choulis, P. Schilinsky, C.J. Brabe, High photovoltaic performance of inkjet printed polymer: Fullerene blends. Adv. Mater. 19, 3973–3978 (2007)CrossRef C.N. Hoth, S.A. Choulis, P. Schilinsky, C.J. Brabe, High photovoltaic performance of inkjet printed polymer: Fullerene blends. Adv. Mater. 19, 3973–3978 (2007)CrossRef
3.
Zurück zum Zitat S.E. Shaheen, R. Radspinner, N. Peyghambarian, G.E. Jabbour, Fabrication of bulk heterojunction plastic solar cells by screen printing. Appl. Phys. Lett. 79, 2996–2998 (2001)CrossRef S.E. Shaheen, R. Radspinner, N. Peyghambarian, G.E. Jabbour, Fabrication of bulk heterojunction plastic solar cells by screen printing. Appl. Phys. Lett. 79, 2996–2998 (2001)CrossRef
4.
Zurück zum Zitat F.C. Krebs, Fabrication and processing of polymer solar cells: A review of painting and coating techniques. Sol. Energy Mater. Sol. Cells 93, 394–412 (2009)CrossRef F.C. Krebs, Fabrication and processing of polymer solar cells: A review of painting and coating techniques. Sol. Energy Mater. Sol. Cells 93, 394–412 (2009)CrossRef
5.
Zurück zum Zitat J. Alstrup, M. Jørgensen, A.J. Medford, F.C. Krebs, Ultra fast and parsimonious material screening for polymer solar cells using differentially pumped slot-die coating. Appl. Mater. Interfaces 2, 2819–2827 (2010)CrossRef J. Alstrup, M. Jørgensen, A.J. Medford, F.C. Krebs, Ultra fast and parsimonious material screening for polymer solar cells using differentially pumped slot-die coating. Appl. Mater. Interfaces 2, 2819–2827 (2010)CrossRef
6.
Zurück zum Zitat G.A. Chamberlain, Organic solar cells: A review. Solar Cells 8, 47–83 (1983)CrossRef G.A. Chamberlain, Organic solar cells: A review. Solar Cells 8, 47–83 (1983)CrossRef
7.
Zurück zum Zitat C.W. Tang, Twolayer organic photovoltaic cell. Appl. Phys. Lett. 48, 183–185 (1986)CrossRef C.W. Tang, Twolayer organic photovoltaic cell. Appl. Phys. Lett. 48, 183–185 (1986)CrossRef
8.
Zurück zum Zitat J.J.M. Hals, K. Pichler, R.H. Friend, S.C. Moratti, A.B. Holmes, Exciton diffusion and dissociation in a poly(pphenylenevinylene)/C60 heterojunction photovoltaic cell. Appl. Phys. Lett. 68, 3120–3122 (1996)CrossRef J.J.M. Hals, K. Pichler, R.H. Friend, S.C. Moratti, A.B. Holmes, Exciton diffusion and dissociation in a poly(pphenylenevinylene)/C60 heterojunction photovoltaic cell. Appl. Phys. Lett. 68, 3120–3122 (1996)CrossRef
9.
Zurück zum Zitat Y.J. Lin, L. Wang, W.Y. Chiu, Novel poly(3-methyltiophene)-TiO2 hybrid materials for photovoltaic cells. Thin Solid Films 511–512, 199–202 (2006)CrossRef Y.J. Lin, L. Wang, W.Y. Chiu, Novel poly(3-methyltiophene)-TiO2 hybrid materials for photovoltaic cells. Thin Solid Films 511–512, 199–202 (2006)CrossRef
10.
Zurück zum Zitat R. Yang, R. Tian, J. Yan, Y. Zhang, J. Yang, Q. Hou, W. Yang, C. Zhang, Y. Cao, Deep-red electroluminescent polymers: Synthesis and characterization of new low-band-gap conjugated copolymers for light-emitting diodes and photovoltaic devices. Macromolecules 38, 244–253 (2005)CrossRef R. Yang, R. Tian, J. Yan, Y. Zhang, J. Yang, Q. Hou, W. Yang, C. Zhang, Y. Cao, Deep-red electroluminescent polymers: Synthesis and characterization of new low-band-gap conjugated copolymers for light-emitting diodes and photovoltaic devices. Macromolecules 38, 244–253 (2005)CrossRef
11.
Zurück zum Zitat M.-C. Yuan, M.-Y. Chiu, C.-M. Chiang, K.-H. Wei, Synthesis and characterization of pyrido[3,4-b]pyrazine-based low-bandgap copolymers for bulk heterojunction solar cells. Macromolecules 43, 6270–6277 (2010)CrossRef M.-C. Yuan, M.-Y. Chiu, C.-M. Chiang, K.-H. Wei, Synthesis and characterization of pyrido[3,4-b]pyrazine-based low-bandgap copolymers for bulk heterojunction solar cells. Macromolecules 43, 6270–6277 (2010)CrossRef
12.
Zurück zum Zitat H. Zhou, L. Yang, S. Xiao, S. Liu, W. You, Donor-acceptor polymers incorporating alkylated dithienylbenzothiadiazole for vbulk heterojunction solar cells: Pronounced effect of positioning alkyl chains. Macromolecules 43, 811–820 (2010)CrossRef H. Zhou, L. Yang, S. Xiao, S. Liu, W. You, Donor-acceptor polymers incorporating alkylated dithienylbenzothiadiazole for vbulk heterojunction solar cells: Pronounced effect of positioning alkyl chains. Macromolecules 43, 811–820 (2010)CrossRef
13.
Zurück zum Zitat P.-I. Lee, S.L.-C. Hsu, P. Lin, White-light-emitting diodes from single polymer systems based on polyfluorine copolymers with quinoxaline derivatives. Macromolecules 43, 8051–8057 (2010)CrossRef P.-I. Lee, S.L.-C. Hsu, P. Lin, White-light-emitting diodes from single polymer systems based on polyfluorine copolymers with quinoxaline derivatives. Macromolecules 43, 8051–8057 (2010)CrossRef
14.
Zurück zum Zitat C.-H. Chen, C.-H. Hsieh, M. Dubose, Y.-J. Cheng, C.-S. Hsu, Synthesis and characterization of bridged bithiophene-based conjugated polymers for photovoltaic applications: Acceptor strength and ternary blends. Macromolecules 43, 697–708 (2010)CrossRef C.-H. Chen, C.-H. Hsieh, M. Dubose, Y.-J. Cheng, C.-S. Hsu, Synthesis and characterization of bridged bithiophene-based conjugated polymers for photovoltaic applications: Acceptor strength and ternary blends. Macromolecules 43, 697–708 (2010)CrossRef
15.
Zurück zum Zitat J.-H. Tsai, W.-Y. Lee, W.-Ch. Chen, Ch.-Y. Yu, G.-W. Hwang, Ch. Ting, New two-dimensional thiophene-acceptor conjugated copolymers for field effect transistor and photovoltaic cell applications. Chem. Mater. 22, 3290–3299 (2010)CrossRef J.-H. Tsai, W.-Y. Lee, W.-Ch. Chen, Ch.-Y. Yu, G.-W. Hwang, Ch. Ting, New two-dimensional thiophene-acceptor conjugated copolymers for field effect transistor and photovoltaic cell applications. Chem. Mater. 22, 3290–3299 (2010)CrossRef
16.
Zurück zum Zitat E. Gondek, I.V. Kityk, A. Danel, 6-N, N-diarylsubstituted 1H-pyrazolo[3,4-b]quinoxalines-novel materials for single-layered photovoltaic devices. J. Mater. Sci.: Mater. Electron. 20(5), 461–468 (2009)CrossRef E. Gondek, I.V. Kityk, A. Danel, 6-N, N-diarylsubstituted 1H-pyrazolo[3,4-b]quinoxalines-novel materials for single-layered photovoltaic devices. J. Mater. Sci.: Mater. Electron. 20(5), 461–468 (2009)CrossRef
17.
Zurück zum Zitat E. Gondek, I.V. Kityk, A. Danel, A. Wisła, M. Pokładko, J. Sanetra, B. Sahraoui, Electroluminescence of several pyrazoloquinoline and quinoksaline derivatives. Mater. Lett. 60, 3301–3306 (2006)CrossRef E. Gondek, I.V. Kityk, A. Danel, A. Wisła, M. Pokładko, J. Sanetra, B. Sahraoui, Electroluminescence of several pyrazoloquinoline and quinoksaline derivatives. Mater. Lett. 60, 3301–3306 (2006)CrossRef
18.
Zurück zum Zitat Powder Diffraction File, ICDD, JCPDS, Swarthmore, PA, 1988 (Card Nos. 21–1272, and 29–1360) Powder Diffraction File, ICDD, JCPDS, Swarthmore, PA, 1988 (Card Nos. 21–1272, and 29–1360)
19.
Zurück zum Zitat S. Balaji, Y. Djaoued, J. Robichaud, Phonon confinement studies in nanocrystalline anatase-TiO2 thin films by micro Raman spectroscopy. J. Raman Spectrosc. 37, 1416–1422 (2006)CrossRef S. Balaji, Y. Djaoued, J. Robichaud, Phonon confinement studies in nanocrystalline anatase-TiO2 thin films by micro Raman spectroscopy. J. Raman Spectrosc. 37, 1416–1422 (2006)CrossRef
20.
Zurück zum Zitat H. Zhang, J.F. Banfield, Thermodynamic analysis of phase stability of nanocrystalline titania. J. Mater. Chem. 8, 2073–2076 (1998)CrossRef H. Zhang, J.F. Banfield, Thermodynamic analysis of phase stability of nanocrystalline titania. J. Mater. Chem. 8, 2073–2076 (1998)CrossRef
21.
Zurück zum Zitat H. Zhang, J.F. Banfield, Understanding polymorphic phase transformation behavior during growth of nanocrystalline aggregates: Insights from TiO2. J. Phys. Chem. B 104, 3481–3487 (2000)CrossRef H. Zhang, J.F. Banfield, Understanding polymorphic phase transformation behavior during growth of nanocrystalline aggregates: Insights from TiO2. J. Phys. Chem. B 104, 3481–3487 (2000)CrossRef
22.
Zurück zum Zitat E. Berteaud, International tables for X-ray crystallography (Kynoch Press, Birmingham, 1968), p. 318 E. Berteaud, International tables for X-ray crystallography (Kynoch Press, Birmingham, 1968), p. 318
23.
Zurück zum Zitat G.D. Sharma, P. Suresh, S.K. Dharma, M.S. Roy, Optical and electrical properties of hybryd photovoltaic devices from poly(3-phenyl hydrazowe thiophen) (PPHT) and TiO2 blend films. Sol. Energy Mater. Sol. Cells 92, 61–70 (2008)CrossRef G.D. Sharma, P. Suresh, S.K. Dharma, M.S. Roy, Optical and electrical properties of hybryd photovoltaic devices from poly(3-phenyl hydrazowe thiophen) (PPHT) and TiO2 blend films. Sol. Energy Mater. Sol. Cells 92, 61–70 (2008)CrossRef
24.
Zurück zum Zitat W. Schärtl, Light Scattering from Polymer Solutions and Nanoparticle Dispersions (Springer, Berlin, 2007) W. Schärtl, Light Scattering from Polymer Solutions and Nanoparticle Dispersions (Springer, Berlin, 2007)
25.
Zurück zum Zitat P. Karasiński, J. Jaglarz, M. Reben, E. Skoczek, J. Mazur, Porous silica xerogel films as antireflective coatings—fabrication and characterization. Opt. Mater. 33, 1989–1994 (2011)CrossRef P. Karasiński, J. Jaglarz, M. Reben, E. Skoczek, J. Mazur, Porous silica xerogel films as antireflective coatings—fabrication and characterization. Opt. Mater. 33, 1989–1994 (2011)CrossRef
26.
Zurück zum Zitat P. Karasiński, E. Gondek, S. Drewniak, I.V. Kityk, Nano-sized blue spectral shift in sol–gel derived mesoporous titania films. J. Sol-Gel. Sci. Technol. 61, 355–361 (2012)CrossRef P. Karasiński, E. Gondek, S. Drewniak, I.V. Kityk, Nano-sized blue spectral shift in sol–gel derived mesoporous titania films. J. Sol-Gel. Sci. Technol. 61, 355–361 (2012)CrossRef
Metadaten
Titel
Influence of TiO2 nanoparticles on the photovoltaic efficiency of the ITO/PEDOT:PSS/fluorine copolymers/polythiophene: TiO2/Al architecture
verfasst von
E. Gondek
Y. Djaoued
J. Robichaud
P. Karasiński
I. V. Kityk
A. Danel
K. J. Plucinski
Publikationsdatum
01.11.2012
Verlag
Springer US
Erschienen in
Journal of Materials Science: Materials in Electronics / Ausgabe 11/2012
Print ISSN: 0957-4522
Elektronische ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-012-0703-z

Weitere Artikel der Ausgabe 11/2012

Journal of Materials Science: Materials in Electronics 11/2012 Zur Ausgabe

Neuer Inhalt