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Erschienen in:
1999 | OriginalPaper | Buchkapitel
Inorganic and Bioinorganic Reaction Kinetics Under High Pressure
verfasst von : Rudi Van Eldik
Erschienen in: High Pressure Molecular Science
Verlag: Springer Netherlands
Enthalten in: Professional Book Archive
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The elucidation of the mechanisms of thermal reactions in inorganic and bioinorganic chemistry through the application of high pressure kinetic techniques is described. High pressure kinetic and thermodynamic data are used to construct volume profiles for typical reactions that include ligand substitution, activation of small molecules, and electron transfer processes. The mechanistic information obtained from such profiles is discussed in detail.