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2019 | OriginalPaper | Buchkapitel

7. Interactions of the Kaolin Minerals with Complex Organic Molecules

verfasst von : Jacob (Theo) Kloprogge

Erschienen in: Spectroscopic Methods in the Study of Kaolin Minerals and Their Modifications

Verlag: Springer International Publishing

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Abstract

In this chapter, the interactions of complex organic molecules with the kaolin group 1:1 clay minerals, will be described in applications such as in the formation of nanocomposites and slow release systems for drugs or pesticides/herbicides, together with the effects of these molecules on the clay internal and external surfaces The reactive molecules are either inserted between the successive clay layers, thereby breaking the hydrogen bonds between the hydroxyl groups of the octahedral sheet on one side and the oxygen atoms of the tetrahedral siloxane sheet on the other side or adsorbed on the external surfaces. In addition, grafting of molecules onto the clay mineral layer surface will be discussed. Van der Waals type forces and dipole-dipole interactions also contribute to bonding to the layer surfaces. Vibrational spectroscopic methods such as Infrared and Raman spectroscopy, sometimes in combination with other spectroscopic techniques, have been used on a regular basis to demonstrate the interactions.

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Vorheriges Kapitel Intercalation of the Kaolin Minerals with Simple Molecules

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Titel: Interactions of the Kaolin Minerals with Complex Organic Molecules
verfasst von: Jacob (Theo) Kloprogge
Verlag: Springer International Publishing
Buch: Spectroscopic Methods in the Study of Kaolin Minerals and Their Modifications
Print ISBN: 978-3-030-02371-3

Electronic ISBN: 978-3-030-02373-7

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-3-030-02373-7_7