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Erschienen in:
Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules Kapitel lesen Erstes Kapitel lesen

2013 | OriginalPaper | Buchkapitel

Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features

verfasst von : Gerald Kehr, Sina Schwendemann, Gerhard Erker

Erschienen in: Frustrated Lewis Pairs I

Verlag: Springer Berlin Heidelberg

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Abstract

Intramolecular vicinal and geminal frustrated Lewis pairs (FLPs) featuring bulky substituents at phosphorus or nitrogen and strongly electron-withdrawing bulky pentafluorophenyl substituents at boron undergo a variety of addition and/or activation reactions with small molecules. A number of examples of such reactions are presented and discussed, among them the FLP activation of dihydrogen to give zwitterionic phosphonium (or ammonium)/hydridoborate zwitterions. Intramolecular FLPs also add to organic carbonyl compounds (including carbon dioxide), to alkenes and alkynes (including conjugated dienes, diynes or enynes), to heterocumulenes, to azides, and to nitric oxide.

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Vorheriges Kapitel Discovery of Frustrated Lewis Pairs: Intermolecular FLPs for Activation of Small Molecules
Nächstes Kapitel Frustrated Lewis Pair Mediated Hydrogenations
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Metadaten
Titel
Intramolecular Frustrated Lewis Pairs: Formation and Chemical Features
verfasst von
Gerald Kehr
Sina Schwendemann
Gerhard Erker
Copyright-Jahr
2013
Verlag
Springer Berlin Heidelberg
Buch
Frustrated Lewis Pairs I

Print ISBN: 978-3-642-36696-3

Electronic ISBN: 978-3-642-36697-0

Copyright-Jahr: 2013

DOI
https://doi.org/10.1007/128_2012_373

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