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Erschienen in: Journal of Polymer Research 12/2021

01.12.2021 | ORIGINAL PAPER

Investigation of hygrothermal aging on the polyurethane-based (PUB) adhesive: substantiating competition scenario between sub-aging thermo-oxidation and hydrolytic phenomena

verfasst von: Mamoon Shaafaey, Amir Bahrololoumi, Hamid Mohammadi, Sharif Alazhary, Roozbeh Dargazany

Erschienen in: Journal of Polymer Research | Ausgabe 12/2021

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Abstract

In this work, the effects of accelerated thermo-oxidative, hydrolytic and hygrothermal aging on the mechanical and chemical properties of a polyurethane based (PUB) adhesive are presented. The adhesive is extensively used in automobile industry particularly as a glass sealant. PUB is inevitably exposed to the hygrothermal environment during service life and the integrity of matrix interface is most vulnerable. This study focuses on weighing and comparing effects of different aging environments on material behavior; it showed that hygrothermal aging is a competition between two sub-aging phenomena i.e., thermo-oxidation and hydrolytic aging. Samples were exposed to 0%RH, 80%RH and submerged condition in distilled water. Uni-axial tensile tests, Differential Scanning Calorimetry (DSC) analysis, Dynamic Mechanical Analysis (DMA), Fourier Transform Infrared Spectroscopy (FTIR) Analysis, Scanning Electron Microscopy (SEM), cross-link analysis and swelling tests were carried out on as-received and aged samples. Accelerated aging process was conducted at different temperatures (60°C, 80°C and 95°C) and for different exposure durations of 1, 10, 30, and 90 days. This work confirms that the effect of hygrothermal aging is a result of competition between thermo-oxidation and hydrolytic aging environments. The total mechanical and environmental damage incurred by specimens is a collaborative effect of all exposure environments involved i.e., aging time, temperature, oxygen, water and humidity. The results are confirmed by chemical test outcomes as well.

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Metadaten
Titel
Investigation of hygrothermal aging on the polyurethane-based (PUB) adhesive: substantiating competition scenario between sub-aging thermo-oxidation and hydrolytic phenomena
verfasst von
Mamoon Shaafaey
Amir Bahrololoumi
Hamid Mohammadi
Sharif Alazhary
Roozbeh Dargazany
Publikationsdatum
01.12.2021
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 12/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-021-02718-4

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