Skip to main content
Erschienen in: Journal of Materials Science 20/2014

01.10.2014 | Original Paper

Ion-exchange kinetics and thermal decomposition characteristics of Fe2+-exchanged alginic acid membrane for the formation of iron oxide nanoparticles

verfasst von: Zihua Wang, Jia Liu, Girish M. Kale, Mojtaba Ghadiri

Erschienen in: Journal of Materials Science | Ausgabe 20/2014

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The ion-exchange kinetics of Fe2+ cations in aqueous solution with H+ from alginic acid have been analyzed in this study as a function of contact time lengths using inductively coupled plasma-atomic emission spectrometry analysis. The kinetic parameters have been evaluated using pseudo 1st or 2nd order models, and a consistent ion-exchange mechanism is suggested. Furthermore, an insight into the calcination of Fe2+ ion-exchanged alginic acid process has been obtained by using simultaneous thermo-gravimetric analysis coupled with differential scanning calorimetry and high temperature X-ray diffraction.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Gombotz WR, Wee SF (1998) Protein release from alginate matrices. Adv Drug Deliver Rev 31:267–285CrossRef Gombotz WR, Wee SF (1998) Protein release from alginate matrices. Adv Drug Deliver Rev 31:267–285CrossRef
2.
Zurück zum Zitat Wu J, Kong T, Yeung KWK, Shum HC, Cheung KMC, Wang L, To MKT (2013) Fabrication and characterization of monodisperse PLGA-alginate core-shell microspheres with monodisperse size and homogeneous shells for controlled drug release. Acta Biomater 9:7410–7419CrossRef Wu J, Kong T, Yeung KWK, Shum HC, Cheung KMC, Wang L, To MKT (2013) Fabrication and characterization of monodisperse PLGA-alginate core-shell microspheres with monodisperse size and homogeneous shells for controlled drug release. Acta Biomater 9:7410–7419CrossRef
3.
Zurück zum Zitat Moshaverinia A, Ansari S, Chen C, Xu X, Akiyama K, Snead ML, Zadeh HH, Shi S (2013) Co-encapsulation of anti-BMP2 monoclonal antibody and mesenchymal stem cells in alginate microspheres for bone tissue engineering. Biomaterials 34:6572–6579CrossRef Moshaverinia A, Ansari S, Chen C, Xu X, Akiyama K, Snead ML, Zadeh HH, Shi S (2013) Co-encapsulation of anti-BMP2 monoclonal antibody and mesenchymal stem cells in alginate microspheres for bone tissue engineering. Biomaterials 34:6572–6579CrossRef
4.
Zurück zum Zitat Jiang T, Feng L, Wang Y (2013) Effect of alginate/nano-Ag coating on microbial and physicochemical characteristics of shiitake mushroom (Lentinus edodes) during cold storage. Food Chem 141:954–960CrossRef Jiang T, Feng L, Wang Y (2013) Effect of alginate/nano-Ag coating on microbial and physicochemical characteristics of shiitake mushroom (Lentinus edodes) during cold storage. Food Chem 141:954–960CrossRef
5.
Zurück zum Zitat Vu CHT, Won K (2013) Novel water-resistant UV-activated oxygen indicator for intelligent food packaging. Food Chem 140:52–56CrossRef Vu CHT, Won K (2013) Novel water-resistant UV-activated oxygen indicator for intelligent food packaging. Food Chem 140:52–56CrossRef
6.
Zurück zum Zitat Wang ZH, Kale GM, Ghadiri M (2011) Novel ion-exchange process for the preparation of metal oxide nanopowders from sodium alginate. J Am Ceram Soc 95:3124–3129CrossRef Wang ZH, Kale GM, Ghadiri M (2011) Novel ion-exchange process for the preparation of metal oxide nanopowders from sodium alginate. J Am Ceram Soc 95:3124–3129CrossRef
7.
Zurück zum Zitat Wang ZH, Kale GM, Ghadiri M (2012) Alginate mediated novel ion-exchange process for the production of CexGd1-xO2-δ nanopowders. Chem Eng J 198–199:149–153CrossRef Wang ZH, Kale GM, Ghadiri M (2012) Alginate mediated novel ion-exchange process for the production of CexGd1-xO2-δ nanopowders. Chem Eng J 198–199:149–153CrossRef
8.
Zurück zum Zitat Beermann N, Vayssieres L, Lindquist SE, Hagfeldt A (2000) Photoelectrochemical studies of oriented nanorod thin films of hematite. J Electrochem Soc 147:2456–2461CrossRef Beermann N, Vayssieres L, Lindquist SE, Hagfeldt A (2000) Photoelectrochemical studies of oriented nanorod thin films of hematite. J Electrochem Soc 147:2456–2461CrossRef
9.
Zurück zum Zitat Zeng SY, Tang KB, Li TW, Liang ZH, Wang D, Wang YK, Qi YX, Zhou WW (2008) Facile route for the fabrication of porous hematite nanoflowers: its synthesis, growth mechanism, application in the lithium ion battery, and magnetic and photocatalytic properties. J Phys Chem C 112:4836–4843CrossRef Zeng SY, Tang KB, Li TW, Liang ZH, Wang D, Wang YK, Qi YX, Zhou WW (2008) Facile route for the fabrication of porous hematite nanoflowers: its synthesis, growth mechanism, application in the lithium ion battery, and magnetic and photocatalytic properties. J Phys Chem C 112:4836–4843CrossRef
10.
Zurück zum Zitat Chauhan P, Annapoorni S, Trikha SK (1999) Humidity-sensing properties of nanocrystalline haematite thin films prepared by sol–gel processing. Thin Solid Films 346:266–268CrossRef Chauhan P, Annapoorni S, Trikha SK (1999) Humidity-sensing properties of nanocrystalline haematite thin films prepared by sol–gel processing. Thin Solid Films 346:266–268CrossRef
11.
Zurück zum Zitat Frank SN, Bard AJ (1977) Heterogeneous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powders. J Phys Chem 81:1484–1488CrossRef Frank SN, Bard AJ (1977) Heterogeneous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powders. J Phys Chem 81:1484–1488CrossRef
12.
Zurück zum Zitat Yu T, Zhu YW, Xu XJ, Yeong KS, Shen ZX, Chen P, Lim CT, Thong JT, Sow CH (2006) Substrate-friendly synthesis of metal oxide nanostructures using a hotplate. Small 2:80–84CrossRef Yu T, Zhu YW, Xu XJ, Yeong KS, Shen ZX, Chen P, Lim CT, Thong JT, Sow CH (2006) Substrate-friendly synthesis of metal oxide nanostructures using a hotplate. Small 2:80–84CrossRef
13.
Zurück zum Zitat Fan ZY, Wen XG, Yang SH, Lu JG (2005) Controlled p- and n-type doping of Fe2O3 nanobelt field effect transistors. Appl Phys Lett 87:013113CrossRef Fan ZY, Wen XG, Yang SH, Lu JG (2005) Controlled p- and n-type doping of Fe2O3 nanobelt field effect transistors. Appl Phys Lett 87:013113CrossRef
14.
Zurück zum Zitat Chernomordik BD, Russell HB, Cvelbar U, Jasinski JB, Kumar V, Deutsch T, Sunkara MK (2012) Photoelectrochemical activity of as-grown, α-Fe2O3 nanowire array electrodes for water splitting. Nanotechnology 23:194009CrossRef Chernomordik BD, Russell HB, Cvelbar U, Jasinski JB, Kumar V, Deutsch T, Sunkara MK (2012) Photoelectrochemical activity of as-grown, α-Fe2O3 nanowire array electrodes for water splitting. Nanotechnology 23:194009CrossRef
15.
Zurück zum Zitat Khairou KS, Al-Gethami WM, Hassan RM (2002) Kinetics and mechanism of sol–gel transformation between sodium alginate polyelectrolyte and some heavy divalent metal ions with formation of capillary structure polymembranes ionotropic gels. J Membr Sci 209:445–456CrossRef Khairou KS, Al-Gethami WM, Hassan RM (2002) Kinetics and mechanism of sol–gel transformation between sodium alginate polyelectrolyte and some heavy divalent metal ions with formation of capillary structure polymembranes ionotropic gels. J Membr Sci 209:445–456CrossRef
16.
Zurück zum Zitat Wang ZH, Kale GM, Yuan QC, Ghadiri M (2012) X-ray micro-tomography of freeze dried nickel alginate beads and transformation into NiO nanopowders. RCS Adv 2:9993–9997 Wang ZH, Kale GM, Yuan QC, Ghadiri M (2012) X-ray micro-tomography of freeze dried nickel alginate beads and transformation into NiO nanopowders. RCS Adv 2:9993–9997
17.
Zurück zum Zitat Cheung C, Porter JF, McKay G (2001) Sorption kinetic analysis for the removal of cadmium ions from effluents using bone char. Water Res 35:605–612CrossRef Cheung C, Porter JF, McKay G (2001) Sorption kinetic analysis for the removal of cadmium ions from effluents using bone char. Water Res 35:605–612CrossRef
18.
Zurück zum Zitat Lagergren S (1898) Zur theorie der sogenannten adsorption gelöster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar 24:1–39 Lagergren S (1898) Zur theorie der sogenannten adsorption gelöster stoffe. Kungliga Svenska Vetenskapsakademiens. Handlingar 24:1–39
19.
Zurück zum Zitat Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34:451–465CrossRef
20.
Zurück zum Zitat Wang ZH, Comyn TP, Ghadiri M, Kale GM (2011) Maltose and pectin assisted sol–gel production of Ce0.8Gd0.2O1.9 solid electrolyte nanopowders for solid oxide fuel cells. J Mater Chem 21:16494–16499CrossRef Wang ZH, Comyn TP, Ghadiri M, Kale GM (2011) Maltose and pectin assisted sol–gel production of Ce0.8Gd0.2O1.9 solid electrolyte nanopowders for solid oxide fuel cells. J Mater Chem 21:16494–16499CrossRef
Metadaten
Titel
Ion-exchange kinetics and thermal decomposition characteristics of Fe2+-exchanged alginic acid membrane for the formation of iron oxide nanoparticles
verfasst von
Zihua Wang
Jia Liu
Girish M. Kale
Mojtaba Ghadiri
Publikationsdatum
01.10.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 20/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8423-9

Weitere Artikel der Ausgabe 20/2014

Journal of Materials Science 20/2014 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.