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2015 | Buch

Nanotechnology: Principles and Practices

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Über dieses Buch

Given the rapid advances in the field, this book offers an up-to-date introduction to nanomaterials and nanotechnology. Though condensed into a relatively small volume, it spans the whole range of multidisciplinary topics related to nanotechnology. Starting with the basic concepts of quantum mechanics and solid state physics, it presents both physical and chemical synthetic methods, as well as analytical techniques for studying nanostructures. The size-specific properties of nanomaterials, such as their thermal, mechanical, optical and magnetic characteristics, are discussed in detail. The book goes on to illustrate the various applications of nanomaterials in electronics, optoelectronics, cosmetics, energy, textiles and the medical field and discusses the environmental impact of these technologies. Many new areas, materials and effects are then introduced, including spintronics, soft lithography, metamaterials, the lotus effect, the Gecko effect and graphene. The book also explains the functional principles of essential techniques, such as scanning tunneling microscopy (STM), atomic force microscopy (AFM), scanning near field optical microscopy (SNOM), Raman spectroscopy and photoelectron microscopy. In closing, Chapter 14, ‘Practicals’, provides a helpful guide to setting up and conducting inexpensive nanotechnology experiments in teaching laboratories.

Inhaltsverzeichnis

Frontmatter
Chapter 1. Introduction to Quantum Mechanics
Abstract
In Nanotechnology we are concerned with natural and synthetic materials in the size range of ∼1–100 nm. At such a small size, very familiar classical, Newtonian mechanics or thermodynamics are not able to explain the observed properties of materials. We have to use quantum mechanics sometimes directly and sometimes through subjects like solid state physics or chemistry which use it to explain the properties and phenomenon of different materials. Those of you who are familiar with quantum mechanics and solid state physics can skip this and the next chapter and directly go to the third chapter. For those who would like to start new, let us discuss first the need of quantum mechanics and how it got developed so that it can be used to understand atoms, molecules, solids and nanomaterials. Box 1.1 gives some historical milestones, which have led to quantum mechanics.
Sulabha K. Kulkarni
Chapter 2. Structure and Bonding
Abstract
Matter is composed of atoms and molecules. Gases, liquids and solids are different states of matter (there can be some other states also under some extreme conditions of matter). However they can get converted into one another depending upon their stability at different pressure, temperature or variation of both. For example, as illustrated in Fig. 2.1, water molecule (H2O) can be in gaseous state (vapour), liquid state (water) or solid state (ice) depending on the temperature and pressure. Water vapour can be converted into liquid water or ice by cooling. Similarly ice can be turned into water and then vapour by heating. At the triple point, solid, liquid and gas co-exist. Critical point as shown in Fig. 2.1 is a point at which some critical values of temperature and pressure are reached. Beyond this point there is no distinction between gas and liquid phase.
Sulabha K. Kulkarni
Chapter 3. Synthesis of Nanomaterials—I (Physical Methods)
Abstract
There are a large number of techniques available to synthesize different types of nanomaterials in the form of colloids, clusters, powders, tubes, rods, wires, thin films etc. Some of the already existing conventional techniques to synthesize different types of materials are optimized to get novel nanomaterials and some new techniques are developed. Nanotechnology is an interdisciplinary subject. There are therefore various physical, chemical, biological and hybrid techniques available to synthesize nanomaterials. It can be seen from Box 3.1 that, for each type, there is a large number of possibilities. The list is not complete but gives some commonly used techniques; some of them will be described in this and in the next two chapters. The technique to be used depends upon the material of interest, type of nanomaterial viz. zero dimensional (0-D), one dimensional (1-D) or two dimensional (2-D), their sizes and quantity.
In this chapter we shall discuss some physical as well as related methods to obtain nanomaterials.
Sulabha K. Kulkarni
Chapter 4. Synthesis of Nanomaterials—II (Chemical Methods)
Abstract
In this chapter we shall discuss some of the wet chemical methods to synthesize nanomaterials. There are numerous advantages of using chemical methods which are summarized in Box 4.1. In some cases nanomaterials are obtained as colloidal particles in solutions, which can be filtered and dried to obtain powder. We can obtain thin films or nanoporous materials by electrodeposition and etching. Advantages of chemical synthesis are manifold. In many cases very well known chemical reaction route can be optimized to obtain nanoparticles. Particles of different shapes and sizes are possible depending upon the chemicals used and reaction conditions.
Sulabha K. Kulkarni
Chapter 5. Synthesis of Nanomaterials—III (Biological Methods)
Abstract
In his, very famous speech delivered in 1959, before the scientists of American Physical Society, Nobel Laureate Richard Feynman asked the scientists to derive the inspiration from Mother Nature to make the things smaller and see the advantages of making things smaller. Indeed the biological world, animal kingdom and plants make optimum use of materials and space. Nature indeed makes use of small spaces and corresponding confinement to synthesize inorganic materials or minerals abundantly found in earth’s crust. It uses insoluble, complex organic molecules as a reactor in which nucleation and growth of complex and hierarchical structures of inorganic materials takes place by reactions of organic soluble molecules. When we think of biological world, we normally think of delicate, temperature sensitive, carboneous or organic materials like leaves, roots, stems, cells, tissues and skin. Inorganic materials are also produced in biological systems. Bones, teeth, shells, nanomagnets inside the bodies of some bacteria and birds are some examples. Inorganic materials inside organic matter or organisms are known as biocomposites or biominerals. A variety of mechanically strong or weak, rigid or flexible, porous or nonporous, thick or thin materials either organic or inorganic in small or large quantities are abundantly produced in contact with live cells. These materials exhibit a wide variety in their functions like providing support to body, allow body movements and in general carry out various essential body functions.
Sulabha K. Kulkarni
Chapter 6. Self Assembly
Abstract
The term ‘Self Assembly’ itself indicates its meaning. It is a gathering or collection of certain entities without any external influence. Although the term ‘self assembly’ has received a scientific acceptance over the last 3–4 decades and such assemblies are recognized in biology, chemistry or physics, some philosophers like Kanad, Democritus and Descarates several centuries back had imagined that everything in the world, from small objects around us to solar system, galaxies and universe is a result of tiny, non-divisible units (or atoms). The word ảtomos (Greek: ἄτομος) was first used by Democritus to mean uncuttable. Out of a chaotic situation, the various forms of matter get ordered following some laws of nature. Today we know that atoms can be further smashed with very high energy into still tinier particles viz. electrons, protons and neutrons. Protons and neutrons also are composed of fundamental particles like quarks. Yet, the concept that matter is composed of tiny units like atoms or molecules is still very useful for understanding most of the phenomena around us.
Sulabha K. Kulkarni
Chapter 7. Analysis Techniques
Abstract
Nanomaterials, dispersed in the form of colloids in solutions, particles (dry powders) or thin films, are characterized by various techniques. Although the techniques to be used would depend upon the type of material and information one needs to know, usually one is interested in first knowing the size, crystalline type, composition, thermal, chemical state, and properties like optical or magnetic properties. A list of various commonly used techniques and their utility can be found in Box 7.1.
In this chapter, we shall briefly outline some of the techniques from those mentioned in Box 7.1.
Sulabha K. Kulkarni
Chapter 8. Types of Nanomaterials and Their Properties
Abstract
It is an interesting question as to, starting with a few atoms, how the bulk materials reach their structure and related properties. Do they undergo any structural changes or even their smallest unit cell is similar to that in bulk material? This question has been addressed by many. There are reasons to believe that the small clusters or nanoparticles are not just the fragments of bulk materials. There can be entirely different structures as well as bonds and bond strengths in clusters which can even differ from nanomaterials.
Sulabha K. Kulkarni
Chapter 9. Nanolithography
Abstract
We have seen in Chaps. 3, 4, and 5 a variety of methods to make nanoparticles (including spherical and other particle shapes) and thin films (or multilayers). These methods are popularly known as bottom up approach. In bottom up approach atoms and molecules are assembled so as to have nanomaterials of required size and shape by controlled deposition or reaction parameters. In the top down approach reverse is the case. Atoms and molecules are removed from a bulk material or sometimes thin films so as to obtain desired nanostructure.
Sulabha K. Kulkarni
Chapter 10. Nanoelectronics
Abstract
In Chap. 9 (also see Fig. 9.1), we saw that the sizes of the electronic devices like transistors are shrinking accompanied by the increase of their density per unit area. With increased device density, in general, the cost of the product not only goes down but the device performance also improves. The performance is limited by the increased heat generation which in turn would restrict the size of the device that should be made. Further, as we go on reducing the size the physics of low dimensional materials does not remain the same as for the bulk according to the discussions in the previous chapters. In fact this gives rise to new nanodevices which would be discussed in this chapter just to understand the basic principle behind their peculiar behaviour which is not seen in the microdevices. Although very interesting, we shall not discuss the nanodevices in which carbon nanotubes or graphene are being used to obtain more efficient devices. Here we are restricting only to certain phenomena rather than special nanomaterials in the devices.
Sulabha K. Kulkarni
Chapter 11. Some Special Nanomaterials
Abstract
We discussed in last few chapters synthesis, characterization and properties of nanomaterials in general. Few examples were given from time to time. In this chapter we shall discuss some nanomaterials like fullerenes, graphene, carbon nanotubes, porous silicon, aerogel, zeolites, self assembled materials and core-shell particles, which form a large section of nanomaterials due to their novel properties.
Sulabha K. Kulkarni
Chapter 12. Applications
Abstract
The ability of materials to dramatically change their properties at nanoscale has opened up the possibility of making new devices, instruments and consumer goods to function in a much better way than was possible earlier. We have seen in Chaps. 10 and 11 that nanomaterials have enabled us to design new products which were not possible using bulk materials. Rapid progress in the synthesis and understanding of nanomaterials in just a few years has led them to enter the world market in a big way. Figure 12.1 shows an overview of various fields in which nanomaterials have entered or are about to enter. In this chapter we shall briefly discuss some of these applications.
Sulabha K. Kulkarni
Chapter 13. Nanotechnology and Environment
Abstract
Whenever any new technology emerges there is rightfully a concern about its impact on social life, health and environment. This was seen when first trains were run. People were worried if there would be effect of travelling in a train. In the twentieth century many new technologies were developed and even a common man knows the benefits of new developments in science and technology. However, along with comforts achieved by adopting various technologies, mankind is now facing numerous problems. The problems are not limited to any small country or community, to rich or poor but by all. Major problems being faced are due to increased population in developing and underdeveloped countries, old and new diseases, depletion of natural resources like fossil fuel, oil and water, increased number of wars, terrorism and so on. Some of the problems are also related to global climatic changes, scarcity and quality of food and water as well as increased pollution in big cities. Therefore some often asked questions are: whether nanotechnology would help to solve or increase some of these problems? Do nanomaterials harm human bodies, animals or plants, may be by inhaling or by contact? Will nanomaterials pollute water, air and food?
Sulabha K. Kulkarni
Chapter 14. Practicals
Abstract
In this chapter we shall briefly discuss some easy ways to perform experiments which will enable the beginners to get some experience in the synthesis of nanomaterials and characterization. We shall mention the equipment required and outline the procedure along with some results. These experiments were actually performed in the author’s laboratory and are possible to perform in any moderately equipped laboratory without heavy investment.
Sulabha K. Kulkarni
Backmatter
Metadaten
Titel
Nanotechnology: Principles and Practices
verfasst von
Sulabha K. Kulkarni
Copyright-Jahr
2015
Electronic ISBN
978-3-319-09171-6
Print ISBN
978-3-319-09170-9
DOI
https://doi.org/10.1007/978-3-319-09171-6

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