Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
ATZ-Fachkongress

Chassis.tech plus 2024


4 Kongresse in einer Veranstaltung

Treffen Sie in München die Fachleute von Chassis, Lenkung, Bremsen sowie Reifen/Räder.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 4/2015

01.02.2015 | Original Paper

Role of different factors in the glass-forming ability of binary alloys

verfasst von: D. V. Louzguine-Luzgin, N. Chen, A. Yu. Churymov, L. V. Louzguina-Luzgina, V. I. Polkin, L. Battezzati, A. R. Yavari

Erschienen in: Journal of Materials Science | Ausgabe 4/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In the present work, we discuss the glass-forming ability of various binary alloys in which the glassy phase was not formed even by melt spinning technique with high cooling rate of the melt up to 1 MK/s (some consisted of partly glassy phase), though by commonly accepted guidelines, these alloys could be as good glass-formers as many other binary glasses. The alloys studied belong to binary systems with multiple eutectics; the constituent elements have a negative enthalpy of mixing, and a significant variability of atomic size differences is observed from system to system. The results indicate the necessity of taking into account simultaneously various factors influencing the glass-forming ability including melt fragility.
Vorheriger Artikel Mechanical properties of low-cost, earth-abundant chalcogenide thermoelectric materials, PbSe and PbS, with additions of 0–4 % CdS or ZnS
Nächster Artikel A study of the effect of precursors on physical and biological properties of mesoporous bioactive glass

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Inoue A (1995) High-strength bulk amorphous alloys with low critical cooling rates. Mater Trans JIM 36:866–875CrossRef
2.
3.
Inoue A (2000) Stabilization of metallic supercooled liquid and bulk amorphous alloys. Acta Mater 48:279–306CrossRef
4.
Johnson WL (1999) Bulk glass-forming metallic alloys: science and technology. MRS Bull 24:42–56CrossRef
5.
Louzguine-Luzgin DV, Inoue A (2013) Bulk metallic glasses. formation, structure, properties, and applications. In: Buschow KHJ (ed) Handbook of magnetic materials. Elsevier, New York, pp 131–171
6.
Louzguine-Luzgin DV, Louzguina-Luzgina LV, Ketov SV, Zadorozhnyy VYu, Greer AL (2014) Influence of cyclic loading on the onset of failure in a Zr-based bulk metallic glass. J Mater Sci 49:6716–6721. doi:10.​1007/​s10853-014-8276-2 CrossRef
7.
Louzguine-Luzgin DV, Xie G, Zhang Q, Suryanarayana C, Inoue A (2010) Formation, structure, and crystallization behavior of Cu-based bulk glass-forming alloys. Metall Mater Trans A 41:1664–1669CrossRef
8.
Louzguine-Luzgin DV, Miracle DB, Louzguina-Luzgina L, Inoue A (2010) Comparative analysis of glass-formation in binary, ternary, and multicomponent alloys. J Appl Phys 108:103511CrossRef
9.
Louzguine DV, Inoue A (2002) Comparison of the long-term thermal stability of various metallic glasses under continuous heating. Scripta Mater 47:887–891CrossRef
10.
Louzguine DV, Inoue A (2001) Electronegativity of the constituent rare-earth metals as a factor stabilizing the supercooled liquid region in Al-based metallic glasses. Appl Phys Lett 79:3410–3412CrossRef
11.
Egami T, Waseda Y (1984) Atomic size effect on the formability of metallic glasses. J Non-Cryst Solids 64:113–134CrossRef
12.
Egami T (1996) The atomic structure of aluminum based metallic glasses and universal criterion for glass-formation. J Non-Cryst Solids 205–207:575–582CrossRef
13.
Miracle DB, Senkov ON (2003) Topological criterion for metallic glass formation. Mater Sci Eng A 347:50–58CrossRef
14.
Miracle DB (2006) The efficient cluster packing model. An atomic structural model for metallic glasses. Acta Mater 54:4317–4336CrossRef
15.
Sheng HW, Luo WK, Alamgir FM, Bai JM, Ma E (2006) Atomic packing and short-to- medium-range order in metallic glasses. Nature 439:419–425CrossRef
16.
Tamura K, Endo H (1969) Ferromagnetic Properties of Amorphous Nickel. Phys Lett A 29:52–53CrossRef
17.
Davies HA (1983) Metallic glass formation. In: Luborsky FE (ed) Amorphous metallic alloys. Butterworths, London, pp 8–25CrossRef
18.
Louzguine-Luzgin DV, Belosludov R, Saito M, Kawazoe Y, Inoue A (2008) Glass-transition behavior of Ni: Calculation, prediction, and experiment. J Appl Phys 104:123529–1–123529-5CrossRef
19.
Kim YW, Lin HM, Kelly TF (1989) Amorphous solidification of pure metals in submicron spheres. Acta Metall 37:247–255CrossRef
20.
Egami T (1997) Universal criterion for metallic glass formation. Mater Sci Eng, A 226–228:261–267CrossRef
21.
Hobbs D, Hafner J, Spisak D (2003) Understanding the complex metallic element Mn. I. Crystalline and noncollinear magnetic structure of α-Mn. Phys Rev B 68:014407CrossRef
22.
Louzguine-Luzgin DV, Yavari AR, Vaughan G, Inoue A (2009) Clustered crystalline structures as glassy phase approximants. Intermetallics 17:477–480CrossRef
23.
Turnbull D, Cohen MH (1961) Free-volume model of the amorphous phase: glass transition. J Chem Phys 34:120–125CrossRef
24.
Lu ZP, Liu CT (2002) A new glass-forming ability criterion for bulk metallic glasses. Acta Mater 50:3501–3512CrossRef
25.
Suryanarayana C, Seki I, Inoue A (2009) A critical analysis of the glass-forming ability of alloys. J Non-Cryst Solids 355:355–360CrossRef
26.
Suryanarayana C, Inoue A (2010) Bulk Metallic Glasses. CRC Press, Boca RatonCrossRef
27.
Louzguine-Luzgin DV, Setyawan AD, Kato H, Inoue A (2007) Thermal conductivity of an alloy in relation to the observed cooling rate and glass-forming ability. Phil Mag 87:1845–1854CrossRef
28.
Park ES, Kim DH, Kim WT (2005) Parameter for glass forming ability of ternary alloy systems. Appl Phys Lett 86:061907CrossRef
29.
Senkov ON, Miracle DB, Mullens HM (2005) Topological criteria for amorphization based on a thermodynamic approach. J Appl Phys 97:103502CrossRef
30.
Louzguine-Luzgin DV, Miracle DB, Inoue A (2008) Intrinsic and Extrinsic Factors Influencing the Glass-Forming Ability of Alloys. Adv Eng Mater 10:1008–1015CrossRef
31.
Louzguine-Luzgin DV, Inoue A, Botta WJ (2006) Reduced electronegativity difference as a factor leading to the formation of Al-based glassy alloys with a large supercooled liquid region of 50 K. Appl Phys Lett 88:011911CrossRef
32.
Louzguine DV, Louzguina LV, Inoue A (2002) Factors influencing glass formation in rapidly solidified Si, Ge–Ni and Si, Ge–Ni–Nd alloys. Appl Phys Lett 80:1556–1558CrossRef
33.
Miracle DB, Louzguine-Luzgin DV, Louzguina-Luzgina LV, Inoue A (2010) An assessment of binary metallic glasses: correlations between structure, glass forming ability and stability. Int Mater Rev 55:218–256CrossRef
34.
Battezzati L, Baricco M (1988) An analysis of volume effects in metallic glass formation. J Less-Common Met 145:31–38CrossRef
35.
Yavari AR (1983) Small volume change on melting as a new criterion for easy formation of metallic glasses. Phys Lett A 95:165–168CrossRef
36.
Bsenko L (1976) The crystal structure of Hf3Cu8 and Zr3Cu8. Acta Cryst B 32:2220–2224CrossRef
37.
Fang T, Kennedy SJ, Quan L, Hicks TJ (1992) The structure and paramagnetism of Ni3Nb. J Phys-Condens Matter 4:2405–2409CrossRef
38.
Zhou DW, Liu JS, Peng P, Chen L, Hu Y (2008) A first-principles study on the structural stability of Al2Ca, Al4Ca and Mg2Ca phases. J Mater Lett 62:206–210CrossRef
39.
Glimois JL, Forey P, Feron J, Becle C (1981) Structural investigations of the pseudo-binary compounds Ni10−x Cu x Zr7. J Less-Common Met 78:45–50CrossRef
40.
Gabathuler JP, White P, Parthé E (1975) Zr14Cu51 and Hf14Cu51 with GdAg3.6 structure type. Acta Cryst B 31:608–610CrossRef
41.
Mattern N, Schops A, Kuhn U, Acker J, Khvostikova O, Eckert J (2008) Structural behavior of CuxZr100−x metallic glass (x = 35 − 70). J Non-Cryst Solids 354:1054–1060CrossRef
42.
Gebhardt E, von Erdberg M, Lüty U (1964) Silver-Yttrium binary alloy phase diagram (based on 1964 Gebhardt E.). IMD Spec Rep Ser 10:303–314
43.
Steeb S, Godel D, Löhr C (1968) On the structure of the compounds Ag3R.E. (R.E. = Y, La, Ce, Sm, Gd, Dy, Ho, Er). J Less-Common Met 15:137CrossRef
44.
McMasters OD, Gschneidner KA Jr, Venteicher RF (1970) Crystallography of the silver-rich rare-earth-silver intermetallic compounds. Acta Crystall B 26:1224–1229CrossRef
45.
Kadomatsu H, Kawanishi Y, Kurisu M, Tokunaga T, Fujiwara H (1988) Structural phase transitions in YCu 1−x M x (M = Ni, Ag and Ga). J Less Common Met 141:29–36CrossRef
46.
Gratz E, Rotter M, Lindbaum A (1993) The influence of the crystal field on the anisotropic thermal expansion in TmCu2. J Phys 5:7955–7958
47.
Buschow KHJ, van der Goot AS (1971) Composition and crystal structure of hexagonal Cu-rich rare earth-copper compounds. Acta Cryst. B 27:1085–1088CrossRef
48.
Miracle DB, Sanders WS, Senkov ON (2003) The influence of efficient atomic packing on the Constitution of metallic glasses. Philos Mag 83:2409–2428CrossRef
49.
Miracle DB (2004) A structural model for metallic glasses. Nat Mater 3:697–702CrossRef
50.
Xia L, Li WH, Fang SS, Wei BC, Dong YD (2006) Binary Ni–Nb bulk metallic glasses. J Appl Phys 99:026103–026103-3CrossRef
51.
Zhang Y, Zhou YJ, Lin JP (2008) Solid solution phase formation rules for multicomponent alloys. Adv Eng Mater 10:534–538CrossRef
52.
Fang SS, Xiao X, Lei X (2003) Relationship between the widths of supercooled liquid regions and bond parameters of Mg-based bulk metallic glasses. J Non-Cryst Solids 321:120–125CrossRef
53.
Takeuchi A, Inoue A (2005) Classification of bulk metallic glasses by atomic size difference, heat of mixing and period of constituent elements and its application to characterization of the main alloying element. Mater Trans 46:2817–2829CrossRef
54.
Guo S, Liu CT (2011) Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase. Mater Int 21:433–446
55.
56.
Gale WF, Totemeier TC (2004) (eds.), Smithells metals reference book. 8th edn. Elsevier Butterworth-Heinemann Ltd., Oxford, pp 11-28–11-29
57.
Ketov SV, Louzguina-Luzgina LV, Churyumov AYu, Solonin AN, Miracle DB, Louzguine-Luzgin DV, Inoue A (2012) Glass-formation and crystallization processes in Ag-Y-Cu alloys. J Non-Cryst Solids 358:1759–1763
58.
Satta M, Rizzi P, Baricco M (2009) Glass-formation and hardness of Cu–Y alloys. J Alloys Compd 483:50–53CrossRef
59.
60.
Burlington MA (2004) Smithells metals reference book. In: Gale WF, Totemeier TC (eds) ASM international metals reference book, 8th edn. Elsevier Butterworth-Heinemann Ltd., Oxford, pp 11-271–11-272
61.
Miracle DB, Lord EA, Ranganathan S (2006) Candidate atomic cluster configurations in metallic glass structures. Mater Trans 47:1737–1742CrossRef
62.
Goldschmidt V (1928) Uber atomabstande in metallen. Z Phys Chem 133:397–419
63.
Pauling L (1947) Atomic radii and interatomic distances in metals. J Am Chem Soc 69:542–553CrossRef
64.
Eiblert R, Redinger J, Neckel A (1987) Electronic structure, chemical bonding and spectral properties of the intermetallic compounds FeTi CoTi and NiTi. J Phys F 17:1533CrossRef
65.
Egami T (1996) Universal criterion for metallic glass formation. J Non-Cryst Solids 205–207:575–582CrossRef
66.
Egami T, Ojha M, Nicholson DM, Louzguine-Luzgin DV, Chen N, Inoue A (2012) Glass formability and the Al-Au system. Philos Mag 92:655–665CrossRef
67.
Nurgayanov PP, Chudinov VG (2000) Atomic mechanisms of glass formation in metallic alloys, tendency to glass formation, and structural models. J Glass Phys Chem 26:335–341
68.
Louzguine-Luzgin DV, Belosludov R, Yavari AR, Georgarakis K, Vaughan G, Kawazoe Y, Egami T, Inoue A (2011) Structural basis for supercooled liquid fragility established by synchrotron-radiation method and computer simulation. J Appl Phys 110:043519CrossRef
69.
Blatter A, von Allmen M (1985) Reversible amorphization in laser-quenched titanium alloys. Phys Rev Lett 54:2103CrossRef
70.
Yavari AR (2005) Solving the hume-rothery eutectic puzzle using miracle glasses. Nat Mater 4:1–2CrossRef
71.
Sudavtsova VS, Kotova NV (2009) Thermodynamic properties of binary Si–Y (transition metal) alloys powder metallurgy and metal ceramics, 48: 582-587. Translated from Poroshkovaya Metallurgiya 48:115–123
72.
Senkov ON, Miracle DB (2001) Effect of the atomic size distribution on glass forming ability of amorphous metallic alloys. Mater Res Bull 36:2183–2198CrossRef
73.
Burlington MA (2004) Smithells metals reference book. In: Gale WF, Totemeier TC (eds) ASM international metals reference book, 8th edn. Elsevier Butterworth-Heinemann Ltd., Oxford UK, pp 4–44
74.
Batsanov SS (1994) General and inorganic chemistry: metallic radii of nonmetals. Russ Chem Bull 43:199–201CrossRef
75.
Louzguine DV, Saito M, Waseda Y, Inoue A (1999) Structural study of amorphous Ge50Al40Cr10 alloy. J Phys Soc Jpn 68:2298–2303CrossRef
76.
Botta WJ, Pereira FS, Bolfarini C, Kiminami CS, de Oliveira MF (2008) Topological instability and electronegativity effects on the glass-forming ability of metallic alloys. Philos Mag Lett 88:785–791CrossRef
77.
Yao KF, Chen N (2008) Pd–Si binary bulk metallic glass. Sci China Ser G 51:414–420CrossRef
78.
Chen N, Yang HA, Caron A, Chen PC, Lin YC, Louzguine-Luzgin DV, Yao KF, Esashi M, Inoue A (2011) Glass-forming ability and thermoplastic formability of a Pd40Ni40Si4P16 glassy alloy. J Mater Sci 46:2091–2096. doi:10.​1007/​s10853-010-5043-x CrossRef
79.
Louzguine DV, Inoue A (1999) The influence of cooling rate on the formation of an amorphous phase in Si-based multicomponent alloys and its thermal stability. Mater Res Bull 34:1165–1172CrossRef
80.
Bergman C, Chastel R, Gilbert M, Castanet R, Mathieu JC (1980) Short-range order and thermodynamic behaviour of Pd-Si melts. J Phys Colloques 41:591–594CrossRef
81.
Guo FQ, Poon SJ, Shiflet GJ (2004) CaAl-based bulk metallic glasses with high thermal stability. Appl Phys Lett 84:37–39CrossRef
82.
Mendeleev D (1889) The periodic law of the chemical elements. J Chem Soc 55:634–656CrossRef
83.
Winter M (2008) WebElements: the periodic table on the WWW, vol 2007. The University of Sheffield and WebElements Ltd, Sheffield
84.
Nagel SR, Taue J (1975) Nearly-free-electron approach to the theory of metallic glass alloys. Phys Rev Lett 35:380CrossRef
85.
Hiiussler P (1983) Interrelations between electronic and ionic structure in metallic glasses. Z Phys B Cond Matt 53:15
86.
Louzguine DV, Inoue A (2002) Investigation of structure and properties of the Al–Y–Ni–Co–Cu metallic glasses. J Mater Res 17:1014–1018CrossRef
87.
Louzguine-Luzgin DV, Inoue A (2005) Structure and transformation behaviour of a rapidly solidified Al–Y–Ni–Co–Pd alloy. J Alloys Compd 399:78–85CrossRef
88.
Perepezko JH, Hildal K (2008) Metallic glass formation reactions and interfaces. Mater Sci and Eng B 148:171–178CrossRef
89.
Perepezko JH, Imhoff SD, Hebert RJ (2010) Nanostructure development during devitrification and deformation. J Alloys Compd 495:360–364CrossRef
90.
Huang Z, Li J, Rao Q, Zhou Y (2008) Thermal stability and primary phase of Al–Ni(Cu)–La amorphous alloys. J Alloys Compd 463:328CrossRef
91.
Tkatch VI, Rassolov SG, Popov VV, Maksimov VV, Maslov VV, Nosenko VK, Aronin AS, Abrosimova GE, Rybchenko OG (2011) Complex crystallization mode of amorphous/nanocrystalline composite Al86Ni2Co5.8Gd5.7Si0.5. J Non-Cryst Solids 357:163–1628CrossRef
92.
Wang H, Carter EA (1993) Metal-metal bonding in Engel-Brewer intermetallics: “anomalous” charge transfer in zirconium-platinum (ZrPt3). J Am Chem Soc 115:2357–2362CrossRef
93.
Louzguine-Luzgin DV (2014) Vitrification and devitrification processes in metallic glasses. J Alloy Compd 586:S2–S8CrossRef
94.
Ojovan MI (2013) Ordering and structural changes at the glass–liquid transition. J Non-Cryst Solids 382:79–86CrossRef
95.
Senkov ON (2007) Correlation between fragility and glass-forming ability of metallic alloys. Phys Rev B 76:104202CrossRef
96.
Uhlmann DR (1972) A kinetic treatment of glass formation. J Non-Cryst Solids 7:337–348CrossRef
Metadaten
Titel
Role of different factors in the glass-forming ability of binary alloys
verfasst von
D. V. Louzguine-Luzgin
N. Chen
A. Yu. Churymov
L. V. Louzguina-Luzgina
V. I. Polkin
L. Battezzati
A. R. Yavari
Publikationsdatum
01.02.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 4/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8741-y

Weitere Artikel der Ausgabe 4/2015

Journal of Materials Science 4/2015 Zur Ausgabe

Original Paper

Effect of external stress on nucleation of ellipsoidal ω precipitates in a Ti–20 wt% Mo alloy

Original Paper

Effect of Li3PO4 addition on the sintering temperature, phase, microstructure, and electrical properties of BaTiO3

Original Paper

Mechanical properties of low-cost, earth-abundant chalcogenide thermoelectric materials, PbSe and PbS, with additions of 0–4 % CdS or ZnS

Original Paper

Electronic and optical modeling of solar cell compound CuXY2 (X = In, Ga, Al; Y = S, Se, Te): first-principles study via Tran–Blaha-modified Becke–Johnson exchange potential approach

Review

Biomaterials for ocular reconstruction

Original Paper

The effect of reduction methods and stabilizer (PVP) on the properties of polyacrylonitrile (PAN) composite nanofibers in the presence of nanosilver

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise