Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
ATZ-Fachkongress

Chassis.tech plus 2024


4 Kongresse in einer Veranstaltung

Treffen Sie in München die Fachleute von Chassis, Lenkung, Bremsen sowie Reifen/Räder.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2015

01.07.2015

Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions

verfasst von: Zhiyun Li, Sili Ren

Erschienen in: Journal of Materials Science | Ausgabe 13/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Nitrogen-functionalized mesoporous carbon (NMC) materials with high nitrogen content were synthesized through a hard template method using ionic liquid of 1-cyanomethyl-3-methylimidazolium bromide as the precursor and LUDOX HS-40 colloidal silica as the template. The obtained NMCs were characterized by X-ray diffraction, transmission electron microscopy, N2 adsorption and desorption analysis, X-ray photoelectron spectroscopy, and elemental analysis. It was shown that the carbonization temperature played a critical role in determining the physiochemical properties and the nitrogen content of the carbon materials. The obtained nitrogen-functionalized mesoporous carbon carbonized at 800 °C possessed disordered mesoporous structure with very high specific surface area of 1028 m2 g−1, large pore volume of 0.94 cm3 g−1, and high nitrogen content of 21.0 wt%. The adsorption performance of the prepared NMCs was investigated by removing Cu2+ from aqueous solutions and the adsorption capacity could attain 117.1 mg g−1 at an optimal condition. The kinetic and isothermal analysis revealed that the removal of Cu2+ by the NMCs belongs to chemical monolayer adsorption, suggesting the strong interaction between Cu2+ and the adsorbent. The XPS spectra of N1s before and after adsorption of Cu2+ suggested that the pyridinic-type nitrogen was the dominant groups of the adsorbent in the adsorption process. Furthermore, the material was separated from solution by filtration and displayed a superior reusability in the recycling test.
Vorheriger Artikel Effect of double aluminium doping on the structure, stability and electronic properties of small gold clusters
Nächster Artikel Modeling grain growth kinetics of binary substitutional alloys by the thermodynamic extremal principle

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Hill MK (2010) Understanding environmental pollution. Cambridge University Press, CambridgeCrossRef
2.
Matlock MM, Howerton BS, Atwood DA (2002) Chemical precipitation of lead from lead battery recycling plant wastewater. Ind Eng Chem Res 41(6):1579–1582CrossRef
3.
Matlock MM, Howerton BS, Atwood DA (2002) Chemical precipitation of heavy metals from acid mine drainage. Water Res 36(19):4757–4764CrossRef
4.
Verbych S, Hilal N, Sorokin G, Leaper M (2005) Ion exchange extraction of heavy metal ions from wastewater. Separ Sci Technol 39(9):2031–2040CrossRef
5.
Dabrowski A, Hubicki Z, Podkościelny P, Robens E (2004) Selective removal of the heavy metal ions from waters and industrial wastewaters by ion-exchange method. Chemosphere 56(2):91–106CrossRef
6.
Zeng G-M, Xu K, Huang J-H, Li X, Fang Y-Y, Qu Y-H (2008) Micellar enhanced ultrafiltration of phenol in synthetic wastewater using polysulfone spiral membrane. J Membr Sci 310(1):149–160CrossRef
7.
Borbély G, Nagy E (2009) Removal of zinc and nickel ions by complexation–membrane filtration process from industrial wastewater. Desalination 240(1):218–226CrossRef
8.
Ngah W, Fatinathan S (2010) Adsorption characterization of Pb(II) and Cu (II) ions onto chitosan-tripolyphosphate beads: kinetic, equilibrium and thermodynamic studies. J Environ Manage 91(4):958–969CrossRef
9.
Wen Y, Ma J, Chen J, Shen C, Li H, Liu W (2015) Carbonaceous sulfur-containing chitosan–Fe(III): a novel adsorbent for efficient removal of copper (II) from water. Chem Eng J 259:372–380CrossRef
10.
Tian H, Feng Q, Chen Y, Yang H, Li X, Lu P (2015) Synthesis of amino-functionalized mesoporous materials with environmentally friendly surfactants by evaporation-induced self-assembly and their application to the adsorption of lead(II) ions. J Mater Sci 50(7):2768–2778. doi:10.​1007/​s10853-015-8832-4
11.
Awual MR, Hasan MM (2015) Colorimetric detection and removal of copper(II) ions from wastewater samples using tailor-made composite adsorbent. Sens Actuat B 206:692–700CrossRef
12.
Rajurkar NS, Gokarn AN, Dimya K (2011) Adsorption of chromium (III), nickel (II), and copper (II) from aqueous solution by activated alumina. CLEAN–Soil, Air Water 39(8):767–773CrossRef
13.
Wu Z, Li W, Webley PA, Zhao D (2012) General and controllable synthesis of novel mesoporous magnetic iron oxide@carbon encapsulates for efficient arsenic removal. Adv Mater 24(4):485–491CrossRef
14.
Wang X, Pei Y, Lu M, Lu X, Du X (2015) Highly efficient adsorption of heavy metals from wastewaters by graphene oxide-ordered mesoporous silica materials. J Mater Sci 50(5):2113–2121. doi:10.​1007/​s10853-014-8773-3 CrossRef
15.
Wu Z, Zhao D (2011) Ordered mesoporous materials as adsorbents. Chem Commun 47(12):3332–3338CrossRef
16.
Awual MR, Yaita T, El-Safty SA, Shiwaku H, Suzuki S, Okamoto Y (2013) Copper(II) ions capturing from water using ligand modified a new type mesoporous adsorbent. Chem Eng J 221:322–330CrossRef
17.
Li Z, Liu J, Xia C, Li F (2013) Nitrogen-functionalized ordered mesoporous carbons as multifunctional supports of ultrasmall pd nanoparticles for hydrogenation of phenol. ACS Catalysis 3(11):2440–2448CrossRef
18.
Goettmann F, Fischer A, Antonietti M, Thomas A (2006) Chemical synthesis of mesoporous carbon nitrides using hard templates and their use as a metal-free catalyst for friedel-crafts reaction of benzene. Angew Chem Int Ed 45(27):4467–4471CrossRef
19.
Awual MR (2015) A novel facial composite adsorbent for enhanced copper(II) detection and removal from wastewater. Chem Eng J 266:368–375CrossRef
20.
Awual MR, Yaita T, Okamoto Y (2014) A novel ligand based dual conjugate adsorbent for cobalt(II) and copper(II) ions capturing from water. Sens Actuat B 203:71–80CrossRef
21.
Awual MR, Ismael M, Yaita T, El-Safty SA, Shiwaku H, Okamoto Y, Suzuki S (2013) Trace copper(II) ions detection and removal from water using novel ligand modified composite adsorbent. Chem Eng J 222:67–76CrossRef
22.
Wang J, Xin HL, Wang D (2014) Recent progress on mesoporous carbon materials for advanced energy conversion and storage. Part Part Syst Char 31(5):515–539CrossRef
23.
Li Q, Jiang R, Dou Y, Wu Z, Huang T, Feng D, Yang J, Yu A, Zhao D (2011) Synthesis of mesoporous carbon spheres with a hierarchical pore structure for the electrochemical double-layer capacitor. Carbon 49(4):1248–1257CrossRef
24.
Lu A, Kiefer A, Schmidt W, Schüth F (2004) Synthesis of polyacrylonitrile-based ordered mesoporous carbon with tunable pore structures. Chem Mater 16(1):100–103CrossRef
25.
Fuertes AB, Centeno TA (2005) Mesoporous carbons with graphitic structures fabricated by using porous silica materials as templates and iron-impregnated polypyrrole as precursor. J Mater Chem 15(10):1079–1083CrossRef
26.
Vinu A, Anandan S, Anand C, Srinivasu P, Ariga K, Mori T (2008) Fabrication of partially graphitic three-dimensional nitrogen-doped mesoporous carbon using polyaniline nanocomposite through nanotemplating method. Micropor Mesopor Mat 109(1–3):398–404CrossRef
27.
Park I-S, Choi M, Kim T-W, Ryoo R (2006) Synthesis of magnetically separable ordered mesoporous carbons using furfuryl alcohol and cobalt nitrate in a silica template. J Mater Chem 16(33):3409–3416CrossRef
28.
Chen H, Sun F, Wang J, Li W, Qiao W, Ling L, Long D (2013) Nitrogen Doping Effects on the Physical and Chemical Properties of Mesoporous Carbons. J Phys Chem C 117(16):8318–8328CrossRef
29.
Zhang S, Dokko K, Watanabe M (2014) Direct synthesis of nitrogen-doped carbon materials from protic ionic liquids and protic salts: structural and physicochemical correlations between precursor and carbon. Chem Mater 26(9):2915–2926CrossRef
30.
Lee JS, Wang X, Luo H, Baker GA, Dai S (2009) Facile ionothermal synthesis of microporous and mesoporous carbons from task specific ionic liquids. J Am Chem Soc 131(13):4596–4597CrossRef
31.
Yuan J, Giordano C, Antonietti M (2010) Ionic liquid monomers and polymers as precursors of highly conductive, mesoporous, graphitic carbon nanostructures. Chem Mater 22(17):5003–5012CrossRef
32.
Fulvio PF, Lee JS, Mayes RT, Wang X, Mahurin SM, Dai S (2011) Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties. Phys Chem Chem Phys 13(30):13486–13491CrossRef
33.
Chen A, Yu Y, Zhang Y, Xing T, Wang Y, Zhang Y, Zhang J (2014) Solid–solid grinding/templating route to magnetically separable nitrogen-doped mesoporous carbon for the removal of Cu2+ ions. J Hazard Mater 279:280–288CrossRef
34.
Kruk M, Jaroniec M (2001) Gas adsorption characterization of ordered organic-inorganic nanocomposite materials. Chem Mater 13(10):3169–3183CrossRef
35.
Paraknowitsch JP, Zhang J, Su D, Thomas A, Antonietti M (2010) Ionic liquids as precursors for nitrogen-doped graphitic carbon. Adv Mater 22(1):87–92CrossRef
36.
Biniak S, Szymański G, Siedlewski J, Światkowski A (1997) The characterization of activated carbons with oxygen and nitrogen surface groups. Carbon 35(12):1799–1810CrossRef
37.
Madhava Rao M, Ramesh A, Purna Chandra Rao G, Seshaiah K (2006) Removal of copper and cadmium from the aqueous solutions by activated carbon derived from Ceiba pentandra hulls. J Hazard Mater 129(1–3):123–129CrossRef
38.
Deng S, Bai R, Chen JP (2003) Behaviors and mechanisms of copper adsorption on hydrolyzed polyacrylonitrile fibers. J Colloid Interf Sci 260(2):265–272CrossRef
39.
Ho YS, McKay G (1999) Pseudo-second order model for sorption processes. Process Biochem 34(5):451–465CrossRef
40.
Huang Y, Li S, Chen J, Zhang X, Chen Y (2014) Adsorption of Pb(II) on mesoporous activated carbons fabricated from water hyacinth using H3PO4 activation: adsorption capacity, kinetic and isotherm studies. Appl Surf Sci 293:160–168CrossRef
41.
Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40(9):1361–1403CrossRef
42.
Freundlich H (1906) Über die adsorption in lösungen. Zeitschrift für Physikalische
43.
Günay A, Arslankaya E, Tosun İ (2007) Lead removal from aqueous solution by natural and pretreated clinoptilolite: adsorption equilibrium and kinetics. J Hazard Mater 146(1–2):362–371CrossRef
44.
Veli S, Alyüz B (2007) Adsorption of copper and zinc from aqueous solutions by using natural clay. J Hazard Mater 149(1):226–233CrossRef
45.
Mohan D, Pittman CU Jr, Steele PH (2006) Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on Kraft lignin—a biosorbent. J Colloid Interf Sci 297(2):489–504CrossRef
46.
Liu C, Bai R, San Ly Q (2008) Selective removal of copper and lead ions by diethylenetriamine-functionalized adsorbent: behaviors and mechanisms. Water Res 42(6–7):1511–1522CrossRef
47.
Xue X, Li F (2008) Removal of Cu(II) from aqueous solution by adsorption onto functionalized SBA-16 mesoporous silica. Micropor Mesopor Mat 116(1–3):116–122CrossRef
48.
Kula I, Uğurlu M, Karaoğlu H, Çelik A (2008) Adsorption of Cd(II) ions from aqueous solutions using activated carbon prepared from olive stone by ZnCl2 activation. Bioresource Technol 99(3):492–501CrossRef
49.
Chen H, Yan T, Jiang F (2014) Adsorption of Cr(VI) from aqueous solution on mesoporous carbon nitride. J Taiwan Inst Chem E 45(4):1842–1849CrossRef
Metadaten
Titel
Preparation of nitrogen-functionalized mesoporous carbon and its application for removal of copper ions
verfasst von
Zhiyun Li
Sili Ren
Publikationsdatum
01.07.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2015
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9009-x

Weitere Artikel der Ausgabe 13/2015

Journal of Materials Science 13/2015 Zur Ausgabe

Original Paper

Synthesis and characterization of magnetic (Cr0.5Mn0.5)2GaC thin films

Original Paper

Effects of sonication energy on the dispersion of carbon nanotubes in a vinyl ester matrix and associated thermo-mechanical properties

Original Paper

Characterization and biocompatibility of a calcium-containing AZ31B alloy as a biodegradable material

Original Paper

Excitation wavelength dependent luminescence properties for Eu3+-activated Ba2Gd2Si4O13 phosphor

Review

Cold spray as an emerging technology for biocompatible and antibacterial coatings: state of art

Original Paper

Functional group changes of polyacrylonitrile fibres during their oxidative, carbonization and electrochemical treatment

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise