Skip to main content
Erschienen in: Journal of Materials Science 13/2016

01.04.2016 | Original Paper

Facile synthesis of nitrogen-doped graphene on Ni foam for high-performance supercapacitors

verfasst von: Haifu Huang, Chenglong Lei, Guangsheng Luo, Zhenzhi Cheng, Guangxu Li, Shaolong Tang, Youwei Du

Erschienen in: Journal of Materials Science | Ausgabe 13/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Nitrogen-doped graphene deposited on nickel foam was prepared via a simple hydrothermal process using urea as the reducing agent and nitrogen source and was directly applied as a binder-free supercapacitor electrode. The N content was 5.01 at. %. The electrochemical test of the prepared N-doped graphene showed ideal and reversible capacitive behaviour and excellent electrochemical performance, with a high specific capacitance of 223 F g−1 at 0.29 A g−1, a high-rate capability with the specific capacitances maintained at 184 F g−1 at a high rate of 35.7 A g−1, and good cycling stability with the specific capacitance of the N-doped graphene increased to 206 F g−1 after 3000 cycles. The results suggest its promising application as an electrode material for supercapacitor.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Scherson DA, Palencsár A (2006) Batteries and electrochemical capacitors. Electrochem Soc Interfac 15:17–22 Scherson DA, Palencsár A (2006) Batteries and electrochemical capacitors. Electrochem Soc Interfac 15:17–22
2.
Zurück zum Zitat Miller JR, Burke AF (2008) Electrochemical capacitors: challenges and opportunities for real-world applications. Electrochem Soc Interfac 17:53–57 Miller JR, Burke AF (2008) Electrochemical capacitors: challenges and opportunities for real-world applications. Electrochem Soc Interfac 17:53–57
3.
Zurück zum Zitat Miller JR, Simon P (2008) Electrochemical capacitors for energy management. Science 321:651–652CrossRef Miller JR, Simon P (2008) Electrochemical capacitors for energy management. Science 321:651–652CrossRef
4.
Zurück zum Zitat Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7:845–854CrossRef Simon P, Gogotsi Y (2008) Materials for electrochemical capacitors. Nat Mater 7:845–854CrossRef
5.
Zurück zum Zitat Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828CrossRef Wang G, Zhang L, Zhang J (2012) A review of electrode materials for electrochemical supercapacitors. Chem Soc Rev 41:797–828CrossRef
6.
Zurück zum Zitat Liu C, Yu Z, Neff D, Zhamu A, Jang BZ (2010) Graphene-based supercapacitor with an ultrahigh energy density. Nano Lett 10:4863–4868CrossRef Liu C, Yu Z, Neff D, Zhamu A, Jang BZ (2010) Graphene-based supercapacitor with an ultrahigh energy density. Nano Lett 10:4863–4868CrossRef
7.
Zurück zum Zitat Gogotsi Y, Simon P (2011) True performance metrics in electrochemical energy storage. Science 334:917–918CrossRef Gogotsi Y, Simon P (2011) True performance metrics in electrochemical energy storage. Science 334:917–918CrossRef
8.
Zurück zum Zitat Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502CrossRef Stoller MD, Park S, Zhu Y, An J, Ruoff RS (2008) Graphene-based ultracapacitors. Nano Lett 8:3498–3502CrossRef
9.
Zurück zum Zitat Weiss NO, Zhou H, Liao L, Liu Y, Jiang S, Huang Y, Duan X (2012) Graphene: an emerging electronic material. Adv Mater 24:5782–5825CrossRef Weiss NO, Zhou H, Liao L, Liu Y, Jiang S, Huang Y, Duan X (2012) Graphene: an emerging electronic material. Adv Mater 24:5782–5825CrossRef
10.
Zurück zum Zitat Huang Y, Liang J, Chen Y (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8:1805–1834CrossRef Huang Y, Liang J, Chen Y (2012) An overview of the applications of graphene-based materials in supercapacitors. Small 8:1805–1834CrossRef
11.
Zurück zum Zitat Yang X, Cheng C, Wang Y, Qiu L, Li D (2013) Liquid-mediated dense integration of graphene materials for compact capacitive energy storage. Science 341:534–537CrossRef Yang X, Cheng C, Wang Y, Qiu L, Li D (2013) Liquid-mediated dense integration of graphene materials for compact capacitive energy storage. Science 341:534–537CrossRef
12.
Zurück zum Zitat Mahmood N, Zhang C, Yin H, Hou Y (2014) Graphene-based nanocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells. J Mater Chem A 2:15–32CrossRef Mahmood N, Zhang C, Yin H, Hou Y (2014) Graphene-based nanocomposites for energy storage and conversion in lithium batteries, supercapacitors and fuel cells. J Mater Chem A 2:15–32CrossRef
13.
Zurück zum Zitat Wen Z, Wang X, Mao S, Bo Z, Kim H, Cui S, Lu G, Feng X, Chen J (2012) Crumpled nitrogen-doped graphene nanosheets with ultrahigh pore volume for high-performance supercapacitor. Adv Mater 24:5610–5616CrossRef Wen Z, Wang X, Mao S, Bo Z, Kim H, Cui S, Lu G, Feng X, Chen J (2012) Crumpled nitrogen-doped graphene nanosheets with ultrahigh pore volume for high-performance supercapacitor. Adv Mater 24:5610–5616CrossRef
14.
Zurück zum Zitat Hulicova-Jurcakova D, Kodama M, Shiraishi S, Hatori H, Zhu ZH, Lu GQ (2009) Nitrogen-enriched nonporous carbon electrodes with extraordinary supercapacitance. Adv Funct Mater 19:1800–1809CrossRef Hulicova-Jurcakova D, Kodama M, Shiraishi S, Hatori H, Zhu ZH, Lu GQ (2009) Nitrogen-enriched nonporous carbon electrodes with extraordinary supercapacitance. Adv Funct Mater 19:1800–1809CrossRef
15.
Zurück zum Zitat Zhao Y, Hu C, Hu Y, Cheng H, Shi G, Qu L (2012) A versatile, ultralight, nitrogen-doped graphene framework. Angew Chem Int Ed 124:11533–11537CrossRef Zhao Y, Hu C, Hu Y, Cheng H, Shi G, Qu L (2012) A versatile, ultralight, nitrogen-doped graphene framework. Angew Chem Int Ed 124:11533–11537CrossRef
16.
Zurück zum Zitat Wei D, Liu Y, Wang Y, Zhang H, Huang L, Yu G (2009) Synthesis of N-Doped graphene by chemical vapor deposition and its electrical properties. Nano Lett 9:1752–1758CrossRef Wei D, Liu Y, Wang Y, Zhang H, Huang L, Yu G (2009) Synthesis of N-Doped graphene by chemical vapor deposition and its electrical properties. Nano Lett 9:1752–1758CrossRef
17.
Zurück zum Zitat Lin YC, Lin CY, Chiu PW (2010) Controllable graphene N-doping with ammonia plasma. Appl Phys Lett 96:133110CrossRef Lin YC, Lin CY, Chiu PW (2010) Controllable graphene N-doping with ammonia plasma. Appl Phys Lett 96:133110CrossRef
18.
Zurück zum Zitat Jafri RI, Rajalakshmi N, Ramaprabhu S (2010) Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell. J Mater Chem 20:7114–7117CrossRef Jafri RI, Rajalakshmi N, Ramaprabhu S (2010) Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell. J Mater Chem 20:7114–7117CrossRef
19.
Zurück zum Zitat Chen CM, Zhang Q, Zhao XC, Zhang B, Kong QQ, Yang MG, Yang QH, Wang MZ, Yang YG, Schlögl R, Su DS (2012) Hierarchically aminated graphene honeycombs for electrochemical capacitive energy storage. J Mater Chem 22:14076CrossRef Chen CM, Zhang Q, Zhao XC, Zhang B, Kong QQ, Yang MG, Yang QH, Wang MZ, Yang YG, Schlögl R, Su DS (2012) Hierarchically aminated graphene honeycombs for electrochemical capacitive energy storage. J Mater Chem 22:14076CrossRef
20.
Zurück zum Zitat Li M, Tang N, Ren W, Cheng H, Wu W, Zhong W, Du Y (2012) Quenching of fluorescence of reduced graphene oxide by nitrogen-doping. Appl Phys Lett 100:233112CrossRef Li M, Tang N, Ren W, Cheng H, Wu W, Zhong W, Du Y (2012) Quenching of fluorescence of reduced graphene oxide by nitrogen-doping. Appl Phys Lett 100:233112CrossRef
21.
Zurück zum Zitat Li N, Wang Z, Zhao K, Shi Z, Gu Z, Xu S (2010) Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method. Carbon 48:255–259CrossRef Li N, Wang Z, Zhao K, Shi Z, Gu Z, Xu S (2010) Large scale synthesis of N-doped multi-layered graphene sheets by simple arc-discharge method. Carbon 48:255–259CrossRef
22.
Zurück zum Zitat Gopalakrishnan K, Govindaraj A, Rao CNR (2013) Extraordinary supercapacitor performance of heavily nitrogenated graphene oxide obtained by microwave synthesis. J Mater Chem A 1:7563–7565CrossRef Gopalakrishnan K, Govindaraj A, Rao CNR (2013) Extraordinary supercapacitor performance of heavily nitrogenated graphene oxide obtained by microwave synthesis. J Mater Chem A 1:7563–7565CrossRef
23.
Zurück zum Zitat Hassan FM, Chabot V, Li J, Kim BK, Ricardez-Sandoval L, Yu A (2013) Pyrrolic-structure enriched nitrogen doped graphene for highly efficient next generation supercapacitors. J Mater Chem A 1:2904–2912CrossRef Hassan FM, Chabot V, Li J, Kim BK, Ricardez-Sandoval L, Yu A (2013) Pyrrolic-structure enriched nitrogen doped graphene for highly efficient next generation supercapacitors. J Mater Chem A 1:2904–2912CrossRef
24.
Zurück zum Zitat Lin Z, Waller GH, Liu Y, Liu M, Wong CP (2013) Simple preparation of nanoporous few-layer nitrogen-doped graphene for use as an efficient electrocatalyst for oxygen reduction and oxygen evolution reactions. Carbon 53:130–136CrossRef Lin Z, Waller GH, Liu Y, Liu M, Wong CP (2013) Simple preparation of nanoporous few-layer nitrogen-doped graphene for use as an efficient electrocatalyst for oxygen reduction and oxygen evolution reactions. Carbon 53:130–136CrossRef
25.
Zurück zum Zitat Lin Z, Waller G, Liu Y, Liu M, Wong CP (2012) Facile synthesis of nitrogen-doped graphene via pyrolysis of graphene oxide and urea, and its electrocatalytic activity toward the oxygen-reduction reaction. Adv Energy Mater 2:884–888CrossRef Lin Z, Waller G, Liu Y, Liu M, Wong CP (2012) Facile synthesis of nitrogen-doped graphene via pyrolysis of graphene oxide and urea, and its electrocatalytic activity toward the oxygen-reduction reaction. Adv Energy Mater 2:884–888CrossRef
26.
Zurück zum Zitat Sheng ZH, Shao L, Chen JJ, Bao WJ, Wang FB, Xia XH (2011) Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis. ACS Nano 5:4350–4358CrossRef Sheng ZH, Shao L, Chen JJ, Bao WJ, Wang FB, Xia XH (2011) Catalyst-free synthesis of nitrogen-doped graphene via thermal annealing graphite oxide with melamine and its excellent electrocatalysis. ACS Nano 5:4350–4358CrossRef
27.
Zurück zum Zitat Lin Z, Song MK, Ding Y, Liu Y, Liu M, Wong CP (2012) Facile preparation of nitrogen-doped graphene as a metal-free catalyst for oxygen reduction reaction. Phys Chem Chem Phys 14:3381–3387CrossRef Lin Z, Song MK, Ding Y, Liu Y, Liu M, Wong CP (2012) Facile preparation of nitrogen-doped graphene as a metal-free catalyst for oxygen reduction reaction. Phys Chem Chem Phys 14:3381–3387CrossRef
28.
Zurück zum Zitat Huang H, Tang Y, Xu L, Tang S, Du Y (2014) Direct formation of reduced graphene oxide and 3D lightweight nickel network composite foam by hydrohalic acids and its application for high-performance supercapacitors. ACS Appl Mater Interfac 6:10248–10257CrossRef Huang H, Tang Y, Xu L, Tang S, Du Y (2014) Direct formation of reduced graphene oxide and 3D lightweight nickel network composite foam by hydrohalic acids and its application for high-performance supercapacitors. ACS Appl Mater Interfac 6:10248–10257CrossRef
29.
Zurück zum Zitat Wang K, Li L, Zhang T, Liu Z (2014) Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability. Energy 70:612–617CrossRef Wang K, Li L, Zhang T, Liu Z (2014) Nitrogen-doped graphene for supercapacitor with long-term electrochemical stability. Energy 70:612–617CrossRef
30.
Zurück zum Zitat Sui ZY, Meng YZ, Xiao PW, Zhao ZQ, Wei ZX, Han BH (2015) Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents. Appl Mater Interfac 7:1431–1438CrossRef Sui ZY, Meng YZ, Xiao PW, Zhao ZQ, Wei ZX, Han BH (2015) Nitrogen-doped graphene aerogels as efficient supercapacitor electrodes and gas adsorbents. Appl Mater Interfac 7:1431–1438CrossRef
31.
Zurück zum Zitat Xie B, Chen Y, Yu M, Shen X, Lei H, Xie T, Zhang Y, Wu Y (2015) Carboxyl-assisted synthesis of nitrogen-doped graphene sheets for supercapacitor applications. Nanoscale Res Lett 10:1–11CrossRef Xie B, Chen Y, Yu M, Shen X, Lei H, Xie T, Zhang Y, Wu Y (2015) Carboxyl-assisted synthesis of nitrogen-doped graphene sheets for supercapacitor applications. Nanoscale Res Lett 10:1–11CrossRef
32.
Zurück zum Zitat Kota M, Yu X, Yeon SH, Cheong HW, Park HS (2016) Ice-templated three dimensional nitrogen doped graphene for enhanced supercapacitor performance. J Power Sources 303:372–378CrossRef Kota M, Yu X, Yeon SH, Cheong HW, Park HS (2016) Ice-templated three dimensional nitrogen doped graphene for enhanced supercapacitor performance. J Power Sources 303:372–378CrossRef
33.
Zurück zum Zitat Du X, Zhou C, Liu HY, Mai YW, Wang G (2013) Facile chemical synthesis of nitrogen-doped graphene sheets and their electrochemical capacitance. J Power Sources 241:460–466CrossRef Du X, Zhou C, Liu HY, Mai YW, Wang G (2013) Facile chemical synthesis of nitrogen-doped graphene sheets and their electrochemical capacitance. J Power Sources 241:460–466CrossRef
34.
Zurück zum Zitat Chen J, Sheng K, Luo P, Li C, Shi G (2012) Graphene hydrogels deposited in Nickel foams for high-rate electrochemical capacitors. Adv Mater 24:4569–4573CrossRef Chen J, Sheng K, Luo P, Li C, Shi G (2012) Graphene hydrogels deposited in Nickel foams for high-rate electrochemical capacitors. Adv Mater 24:4569–4573CrossRef
35.
Zurück zum Zitat Chen W, Fan Z, Zeng G, Lai Z (2013) Layer-dependent supercapacitance of graphene films grown by chemical vapor deposition on nickel foam. J Power Sourc 225:251–256CrossRef Chen W, Fan Z, Zeng G, Lai Z (2013) Layer-dependent supercapacitance of graphene films grown by chemical vapor deposition on nickel foam. J Power Sourc 225:251–256CrossRef
36.
Zurück zum Zitat Zhang LL, Zhao X, Stoller MD, Zhu Y, Ji H, Murali S, Wu Y, Perales S, Clevenger B, Ruoff RS (2012) Highly conductive and porous activated reduced graphene oxide films for high-power supercapacitors. Nano Lett 12:1806–1812CrossRef Zhang LL, Zhao X, Stoller MD, Zhu Y, Ji H, Murali S, Wu Y, Perales S, Clevenger B, Ruoff RS (2012) Highly conductive and porous activated reduced graphene oxide films for high-power supercapacitors. Nano Lett 12:1806–1812CrossRef
37.
Zurück zum Zitat Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin LC (2011) Graphene and carbon nanotube composite electrodes for supercapacitors with ultra-high energy density. Phys Chem Chem Phys 13:17615–17624CrossRef Cheng Q, Tang J, Ma J, Zhang H, Shinya N, Qin LC (2011) Graphene and carbon nanotube composite electrodes for supercapacitors with ultra-high energy density. Phys Chem Chem Phys 13:17615–17624CrossRef
38.
Zurück zum Zitat Beidaghi M, Wang C (2012) Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv Funct Mater 22:4501–4510CrossRef Beidaghi M, Wang C (2012) Micro-supercapacitors based on interdigital electrodes of reduced graphene oxide and carbon nanotube composites with ultrahigh power handling performance. Adv Funct Mater 22:4501–4510CrossRef
39.
Zurück zum Zitat Cao X, Shi Y, Shi W, Lu G, Huang X, Yan Q, Zhang Q, Zhang H (2011) Preparation of novel 3D graphene networks for supercapacitor applications. Small 7:3163–3168CrossRef Cao X, Shi Y, Shi W, Lu G, Huang X, Yan Q, Zhang Q, Zhang H (2011) Preparation of novel 3D graphene networks for supercapacitor applications. Small 7:3163–3168CrossRef
Metadaten
Titel
Facile synthesis of nitrogen-doped graphene on Ni foam for high-performance supercapacitors
verfasst von
Haifu Huang
Chenglong Lei
Guangsheng Luo
Zhenzhi Cheng
Guangxu Li
Shaolong Tang
Youwei Du
Publikationsdatum
01.04.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9931-6

Weitere Artikel der Ausgabe 13/2016

Journal of Materials Science 13/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.