nach oben

Journal of Materials Science

Erschienen in:

31.07.2017 | Chemical routes to materials

Facile synthesis and excellent electromagnetic wave absorption properties of flower-like porous RGO/PANI/Cu₂O nanocomposites

verfasst von: Ping Yan, Jie Miao, Juan Cao, Hui Zhang, Cuiping Wang, Anjian Xie, Yuhua Shen

Erschienen in: Journal of Materials Science | Ausgabe 22/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Novel porous ternary nanocomposite systems containing reduced graphene oxide (RGO)/polyaniline (PANI)/cuprous oxide (Cu₂O) were prepared via one-step in situ redox method. The RGO/PANI/Cu₂O nanocomposites present a flower-like structure with an average size of 2.0 μm in diameter. The morphologies and properties of the products can be controlled by adjusting the molar ratios of aniline to Cu²⁺. When the molar ratio of aniline to Cu²⁺ is 1:1, the product exhibits excellent microwave absorption property in the frequency range of 2–18 GHz. It can be seen that the maximum reflection loss (RL) of the ternary composite is up to −52.8 dB at 2.7 GHz with a thickness of only 2 mm, and the absorption bandwidth corresponding to −10 dB (90% of EM wave absorption) is 13.2 GHz. The microwave absorption property of ternary RGO/PANI/Cu₂O composite is significantly improved due to its special flower-like porous structure, dielectric loss property and well impedance matching characteristics, which is 8.12 times than that of pure RGO and 5.28 times than that of pure PANI. Therefore, our study paves a new way to prepare the promising lightweight and high-performance composite materials combined with the characteristics of three components for electromagnetic absorption.

Vorheriger Artikel A bifunctional electrocatalyst of PtNi nanoparticles immobilized on three-dimensional carbon nanofiber mats for efficient and stable water splitting in both acid and basic media

Nächster Artikel Preparation of 2D graphitic carbon nitride nanosheets by a green exfoliation approach and the enhanced photocatalytic performance

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Eun SW, Choi WH, Jang HK, Shin JH, Kim JB, Kim CG (2015) Effect of delamination on the electromagnetic wave absorbing performance of radar absorbing structures. Compos Sci Technol 116:18–25CrossRef

Micheli D, Vricella A, Pastore R, Marchetti M (2014) Synthesis and electromagnetic characterization of frequency selective radar absorbing materials using carbon nanopowders. Carbon 77:756–774CrossRef

Qu B, Zhu CL, Li CY, Zhang XT, Chen YJ (2016) Coupling hollow Fe₃O₄–Fe nanoparticles with graphene sheets for high-performance electromagnetic wave absorbing material. ACS Appl Mater Interfaces 8:3730–3735CrossRef

Cordova D, Toledo P, Klimach H, Bampi S, Fabris E (2016) EMI resisting MOSFET-only voltage reference based on ZTC condition. Analog Integr Circuits Process 89:45–59CrossRef

Meshram M, Agrawal NK, Sinha B, Misra P (2004) Characterization of M-type barium hexagonal ferrite-based wide band microwave absorber. J Magn Magn Mater 271:207–214CrossRef

Feng Y, Qiu T, Shen C (2007) Absorbing properties and structural design of microwave absorbers based on carbonyl iron and barium ferrite. J Magn Magn Mater 318:8–13CrossRef

Ali K, Iqbal J, Jan T, Ahmad I, Wan D, Bahadur A et al (2017) Synthesis of CuFe₂O₄–ZnO nanocomposites with enhanced electromagnetic wave absorption properties. J Alloys Compd 705:559–565CrossRef

Zhang H, Hong M, Chen P, Xie A, Shen Y (2016) 3D and ternary rGO/MCNTs/Fe₃O₄ composite hydrogels: synthesis, characterization and their electromagnetic wave absorption properties. J Alloys Compd 665:381–387CrossRef

Han M, Yin X, Kong L, Li M, Duan W, Zhang L et al (2014) Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties. J Mater Chem A 2:16403–16409CrossRef

10.

Wang M, Huang J, Tong Z, Li W, Chen J (2013) Reduced graphene oxide–cuprous oxide composite via facial deposition for photocatalytic dye-degradation. J Alloys Compd 568:26–35CrossRef

11.

Nguyen TT, Shim J-J (2015) Rapid one-step synthesis and electrochemical properties of graphene/carbon nanotubes/MnO₂ composites. Synth Metals 199:276–279CrossRef

12.

Liu P, Huang Y, Wang L, Zong M, Zhang W (2013) Hydrothermal synthesis of reduced graphene oxide–Co₃O₄ composites and the excellent microwave electromagnetic properties. Mater Lett 107:166–169CrossRef

13.

Wang T, Li Y, Wang L, Liu C, Geng S, Jia X et al (2015) Synthesis of graphene/α-Fe₂O₃ composites with excellent electromagnetic wave absorption properties. RSC Adv 5:60114–60120CrossRef

14.

Choi J, Jung HT (2015) A new triple-layered composite for high-performance broadband microwave absorption. Compos Struct 122:166–171CrossRef

15.

Ciric-Marjanovic G (2013) Recent advances in polyaniline composites with metals, metalloids and nonmetals. Synth Metals 170:31–56CrossRef

16.

Marins JA, Soares BG, Fraga M, Muller D, Barra GMO (2014) Self-supported bacterial cellulose polyaniline conducting membrane as electromagnetic interference shielding material: effect of the oxidizing agent. Cellulose 21:1409–1418CrossRef

17.

Al-Ghamdi AA, Al-Hartomy OA, Al-Solamy F, Al-Hazmi F, Al-Ghamdi AA, El-Mossalamy EH et al (2014) On the prospects of conducting polyaniline/natural rubber composites for electromagnetic shielding effectiveness applications. J Thermoplast Compos Mater 27:765–782CrossRef

18.

Jazirehpour M, Ebrahimi SAS (2015) Effect of aspect ratio on dielectric, magnetic, percolative and microwave absorption properties of magnetite nanoparticles. J Alloys Compd 638:188–196CrossRef

19.

Tian CH, Du YC, Xu P, Qiang R, Wang Y, Ding D et al (2015) Constructing uniform core-shell PPy@PANI composites with tunable shell thickness toward enhancement in microwave absorption. ACS Appl Mater Interfaces 7:20090–20099CrossRef

20.

Yu HL, Wang TS, Wen B, Lu MM, Xu Z, Zhu CL et al (2012) Graphene/polyaniline nanorod arrays: synthesis and excellent electromagnetic absorption properties. J Mater Chem 22:21679–21685CrossRef

21.

Wang L, Huang Y, Huang HJ (2014) N-doped graphene@polyaniline nanorod arrays hierarchical structures: synthesis and enhanced electromagnetic absorption properties. Mater Lett 124:89–92CrossRef

22.

Susman MD, Feldman Y, Vaskevich A, Rubinstein I (2014) Chemical deposition of Cu₂O nanocrystals with precise morphology control. ACS Nano 8:162–174CrossRef

23.

Kuang M, Li TT, Chen H, Zhang SM, Zhang LL, Zhang YX (2015) Hierarchical Cu₂O/CuO/Co₃O₄ core-shell nanowires: synthesis and electrochemical properties. Nanotechnology 26:304002–304010CrossRef

24.

Chakravarty A, Bhowmik K, Mukherjee A, De G (2015) Cu₂O nanoparticles anchored on amine-functionalized graphite nanosheet: a potential reusable catalyst. Langmuir 31:5210–5219CrossRef

25.

Lee S, Oh J, Kim D, Piao Y (2016) A sensitive electrochemical sensor using an iron oxide/graphene composite for the simultaneous detection of heavy metal ions. Talanta 160:528–536CrossRef

26.

Kim AY, Kim MK, Cho K, Woo JY, Lee Y, Han SH et al (2016) One-step catalytic synthesis of CuO/Cu₂O in a graphitized porous C matrix derived from the Cu-based metal organic framework for Li- and Na-ion batteries. ACS Appl Mater Interfaces 8:19514–19523CrossRef

27.

Huo HH, Guo CY, Li GL, Han X, Xu CL (2014) Reticular-vein-like Cu@Cu₂O/reduced graphene oxide nanocomposites for a non-enzymatic glucose sensor. RSC Adv 4:20459–20465CrossRef

28.

Ro D-K, Paradise EM, Ouellet M, Fisher KJ, Newman KL, Ndungu JM et al (2006) Production of the antimalarial drug precursor artemisinic acid in engineered yeast. Nature 440:940–943CrossRef

29.

Fan ZJ, Luo GH, Zhang ZF, Zhou L, Wei F (2006) Electromagnetic and microwave absorbing properties of multi-walled carbon nanotubes/polymer composites. Mater Sci Eng B Solid State Mater Adv Technol 132:85–89CrossRef

30.

Zhang YH, Zhang N, Tang ZR, Xu YJ (2012) Graphene transforms wide band gap ZnS to a visible light photocatalyst. The new role of graphene as a macromolecular photosensitizer. ACS Nano 6:9777–9789CrossRef

31.

Wang K, Dong X, Zhao C, Qian X, Xu Y (2015) Facile synthesis of Cu₂O/CuO/RGO nanocomposite and its superior cyclability in supercapacitor. Electrochim Acta 152:433–442CrossRef

32.

Xi X, Liu R, Huang T, Xu Y, Wu D (2016) Strongly coupled polyaniline/graphene hybrids with much enhanced capacitance performance. J Colloid Interface Sci 483:34–40CrossRef

33.

Wu Q, Chen M, Wang S, Zhang X, Huan L, Diao G (2016) Preparation of sandwich-like ternary hierarchical nanosheets manganese dioxide/polyaniline/reduced graphene oxide as electrode material for supercapacitor. Chem Eng J 304:29–38CrossRef

34.

Miao J, Xie A, Li S, Huang F, Cao J, Shen Y (2016) A novel reducing graphene/polyaniline/cuprous oxide composite hydrogel with unexpected photocatalytic activity for the degradation of Congo red. Appl Surf Sci 360:594–600CrossRef

35.

Wang G, Zhuo S, Xing W (2012) Graphene/polyaniline nanocomposite as counter electrode of dye-sensitized solar cells. Mater Lett 69:27–29CrossRef

36.

Niu H, Zhang S, Ma Q, Qin S, Wan L, Xu J et al (2013) Dye-sensitized solar cells based on flower-shaped α-Fe₂O₃ as a photoanode and reduced graphene oxide–polyaniline composite as a counter electrode. RSC Adv 3:17228–17235CrossRef

37.

Li Y, Yang N, Du TT, Wang XZ, Chen W (2016) Transformation of graphene oxide by chlorination and chloramination: implications for environmental transport and fate. Water Res 103:416–423CrossRef

38.

Frost RL, Cejka J, Ayoko G (2008) Raman spectroscopic study of the uranyl phosphate minerals phosphuranylite and yingjiangite. J Raman Spectrosc 39:495–502CrossRef

39.

Ding B, Kimura E, Sato T, Fujita S, Shiratori S (2004) Fabrication of blend biodegradable nanofibrous nonwoven mats via multi-jet electrospinning. Polymer 45:1895–1902CrossRef

40.

Yec CC, Zeng HC (2012) Synthetic architecture of multiple core-shell and yolk-shell structures of (Cu₂O@)(n)Cu₂O (n = 1-4) with centricity and eccentricity. Chem Mater 24:1917–1929CrossRef

41.

Qiu W, Kang YL, Lei ZK, Qin QH, Li Q, Wang QA (2010) Experimental study of the Raman strain rosette based on the carbon nanotube strain sensor. J Raman Spectrosc 41:1216–1220CrossRef

42.

Yamamoto M, Wang ST, Ni MY, Lin YF, Li SL, Aikawa S et al (2014) Strong enhancement of raman scattering from a bulk-inactive vibrational mode in few-layer MoTe₂. ACS Nano 8:3895–3903CrossRef

43.

Ghanbari K, Moloudi M (2016) Flower-like ZnO decorated polyaniline/reduced graphene oxide nanocomposites for simultaneous determination of dopamine and uric acid. Anal Biochem 512:91–102CrossRef

44.

Liu P, Huang JY, Sanchez DVP, Schwartzman D, Lee SH, Yun M (2016) High yield two-dimensional (2-D) polyaniline layer and its application in detection of B-type natriuretic peptide in human serum. Sens Actuator B Chem 230:184–190CrossRef

45.

Cao J, Li JC, Liu L, Xie AJ, Li SK, Qiu LG et al (2014) One-pot synthesis of novel Fe₃O₄/Cu₂O/PANI nanocomposites as absorbents in water treatment. J Mater Chem A 2:7953–7959CrossRef

46.

Mishra M, Singh AP, Gupta V, Chandra A, Dhawan SK (2016) Tunable EMI shielding effectiveness using new exotic carbon: polymer composites. J Alloys Compd 688:399–403CrossRef

47.

Wang L, Xing H, Gao S, Ji X, Shen Z (2017) Porous flower-like NiO@ graphene composites with superior microwave absorption properties. J Mater Chem C 5:2005–2014CrossRef

48.

Cao MS, Song WL, Hou ZL, Wen B, Yuan J (2010) The effects of temperature and frequency on the dielectric properties, electromagnetic interference shielding and microwave-absorption of short carbon fiber/silica composites. Carbon 48:788–796CrossRef

49.

Huang YH, Huang XY, Schadler LS, He JL, Jiang PK (2016) Core@double-shell structured nanocomposites: a route to high dielectric constant and low loss material. ACS Appl Mater Interfaces 8:25496–25507CrossRef

50.

Fang MS, Shi FH, Chen YH (2016) Unidirectional all-optical absorption switch based on optical Tamm state in nonlinear plasmonic waveguide. Plasmonics 11:197–203CrossRef

51.

Liu PB, Huang Y, Zhang X (2014) Superparamagnetic Fe₃O₄ nanoparticles on graphene-polyaniline: synthesis, characterization and their excellent electromagnetic absorption properties. J Alloys Compd 596:25–31CrossRef

52.

Han MK, Yin XW, Kong L, Li M, Duan WY, Zhang LT et al (2014) Graphene-wrapped ZnO hollow spheres with enhanced electromagnetic wave absorption properties. J Mater Chem A 2:16403–16409CrossRef

53.

Feng W, Wang YM, Chen JC, Wang L, Guo LX, Ouyang JH et al (2016) Reduced graphene oxide decorated with in situ growing ZnO nanocrystals: facile synthesis and enhanced microwave absorption properties. Carbon 108:52–60CrossRef

54.

Duong PHH, Nunes SP, Chung TS (2016) Dual-skinned polyamide/poly(vinylidene fluoride)/cellulose acetate membranes with embedded woven. J Membr Sci 520:840–849CrossRef

55.

Chen TT, Deng F, Zhu J, Chen CF, Sun GB, Ma SL et al (2012) Hexagonal and cubic Ni nanocrystals grown on graphene: phase-controlled synthesis, characterization and their enhanced microwave absorption properties. J Mater Chem 22:15190–15197CrossRef

56.

Kong L, Yin X, Zhang Y, Yuan X, Li Q, Ye F et al (2013) Electromagnetic wave absorption properties of reduced graphene oxide modified by maghemite colloidal nanoparticle clusters. J Phys Chem C 117:19701–19711CrossRef

57.

Hosseini SH, Mohseni SH, Asadnia A, Kerdari H (2011) Synthesis and microwave absorbing properties of polyaniline/MnFe₂O₄ nanocomposite. J Alloys Compd 509:4682–4687CrossRef

58.

Liu XY, Lv YL, Zhuang QX, Li YM, Zhang SD, Lan FX (2016) Polybenzobisoxazoles-based nanocomposites with high microwave absorption performance and excellent thermal stability. Polymer 99:605–613CrossRef

59.

Luo JH, Shen P, Yao W, Jiang CF, Xu JG (2016) Synthesis, characterization, and microwave absorption properties of reduced graphene oxide/strontium ferrite/polyaniline nanocomposites. Nanoscale Res Lett 11:141–154CrossRef

60.

He Z, Qi SH, Zhong XL, Ma H, Wang P, Qiu H (2015) Preparation and microwave-absorbing properties of silver-coated strontium ferrite with polyaniline via in situ polymerization. J Alloys Compd 621:194–200CrossRef

61.

Micheli D, Apollo C, Pastore R, Marchetti M (2010) X-Band microwave characterization of carbon-based nanocomposite material, absorption capability comparison and RAS design simulation. Compos Sci Technol 70:400–409CrossRef

62.

Wu F, Xie A, Sun M, Wang Y, Wang M (2015) Reduced graphene oxide (RGO) modified spongelike polypyrrole (PPy) aerogel for excellent electromagnetic absorption. J Mater Chem A 3:14358–14369CrossRef

63.

Guo J, Wang X, Miao P, Liao X, Zhang W, Shi B (2012) One-step seeding growth of controllable Ag@Ni core-shell nanoparticles on skin collagen fiber with introduction of plant tannin and their application in high-performance microwave absorption. J Mater Chem 22:11933–11942CrossRef

64.

Liu P, Yao Z, Zhou J, Yang Z, Kong LB (2016) Small magnetic Co-doped NiZn ferrite/graphene nanocomposites and their dual-region microwave absorption performance. J Mater Chem C 4:9738–9749CrossRef

Titel: Facile synthesis and excellent electromagnetic wave absorption properties of flower-like porous RGO/PANI/Cu2O nanocomposites
verfasst von: Ping Yan
Jie Miao
Juan Cao
Hui Zhang
Cuiping Wang
Anjian Xie
Yuhua Shen
Publikationsdatum: 31.07.2017
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 22/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-017-1418-6

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 22/2017

Precipitation behaviors of 14H LPSO lamellae in Mg96Gd3Zn0.5Ni0.5 alloys during severe plastic deformation

Preparation of graphene oxide–cellulose acetate nanocomposite membrane for high-flux desalination

Prospect of 9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide-based oligosiloxane in the preparation of high damping methyl phenyl vinyl silicone rubbers with broad temperature range

Large enhanced conversion efficiency of perovskite solar cells by CsBr doping

Curved nanotwinned structure in Ni induced by dynamic compression

Morphological studies of small-molecule solar cells: nanostructural engineering via solvent vapor annealing treatments

Premium Partner

Marktübersichten