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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2013

01.09.2013 | Original Paper

Facile elaboration of polymethylmethacrylate / polyurethane interpenetrating networks using Diels-Alder reactions

verfasst von: Nathalie Mignard, Nidhal Okhay, Corinne Jegat, Mohamed Taha

Erschienen in: Journal of Polymer Research | Ausgabe 9/2013

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Abstract

Thermo-reversible PMMA/PU interpenetrating polymer networks were successfully prepared by Diels-Alder (DA) reaction using a furan-functionalized polymethyl methacrylate, furan-functionalized polyurethane and a maleimide-based coupling agent. First, homo-networks were synthesized and characterized in order to predict the characteristics of the corresponding interpenetrating network. Polyurethane networks were confirmed to be reversible with a temperature of retro-Diels-Alder varying from 135 °C to 144 °C depending on the cross-linking density. PMMA/PU blends are completely immiscible as shown by the presence of two Tgs corresponding to the two phases in DSC results. Due to the presence of supramolecular interactions, no phase separation was observed in the simultaneously cross-linked PMMA/PU networks. Thermal behavior and de-cross-linking of the IPNs were studied by DSC, solubility tests and rheology. Swelling tests allowed the evaluation of the networks density.
Vorheriger Artikel Nanofiber-based poly(aryl ether sulfone) containing guanidinium groups as novel anion-exchange membranes
Nächster Artikel Functionalized lignin for halogen-free flame retardant rigid polyurethane foam: preparation, thermal stability, fire performance and mechanical properties

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Metadaten
Titel
Facile elaboration of polymethylmethacrylate / polyurethane interpenetrating networks using Diels-Alder reactions
verfasst von
Nathalie Mignard
Nidhal Okhay
Corinne Jegat
Mohamed Taha
Publikationsdatum
01.09.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2013
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0233-2

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