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01.11.2014 | Original Paper

Functionalized graphene oxide/polyimide nanocomposites as highly CO₂-selective membranes

verfasst von: Hadis Koolivand, Alireza Sharif, Mehdi Razzaghi Kashani, Mohammad Karimi, Mahdi Koolivand Salooki, Mohammad Ali Semsarzadeh

Erschienen in: Journal of Polymer Research | Ausgabe 11/2014

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Abstract

The design of highly CO₂-selective membranes by incorporating low amounts (0.25–0.75 wt%) of functionalized graphene oxide (F-GO) nanosheets (polyethylene glycol functionalized and aminated GOs) into an Ultem® 1000 polyetherimide (PEI) is presented. Structural and morphological analysis of the membranes by infrared spectroscopy, X-ray diffraction, differential scanning calorimetry and scanning electron microscopy revealed strong interfacial interactions between the F-GO nanosheets and PEI. The CO₂/CH₄ separation performance of the membranes was discussed in terms of filler-polymer interfacial interactions and free volume characteristics. The origins of free volume are proposed to be different for GO/PEI and F-GO/PEI membranes: free volume is mainly located at the GO-PEI interface of the GO/PEI membranes while distributed within interphase regions formed around the F-GO nanosheets in the F-GO/PEI ones. These different free volume localizations resulted in distinct gas separation properties of the membranes. The membranes containing aminated-GO showed outstanding CO₂/CH₄ selectivities up to 142, due to the activation of multi-permselectivity mechanism in the PEI membrane by addition of the aminated nanosheets. The promising potential of F-GOs in CO₂ removal is highlighted by comparing the CO₂/CH₄ separation performance of the F-GO/PEI membranes with that of other nanocomposites of PEI.

Vorheriger Artikel Influence of annealing on stress–strain behaviors and performances of β nucleated polypropylene stretched membranes

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Titel: Functionalized graphene oxide/polyimide nanocomposites as highly CO2-selective membranes
verfasst von: Hadis Koolivand
Alireza Sharif
Mehdi Razzaghi Kashani
Mohammad Karimi
Mahdi Koolivand Salooki
Mohammad Ali Semsarzadeh
Publikationsdatum: 01.11.2014
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 11/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-014-0599-9

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