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Journal of Polymer Research

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01.12.2020 | ORIGINAL PAPER

Excellent memory performance of poly (1,6-hexanediol adipate) based shape memory polyurethane filament over a range of thermo-mechanical parameters

verfasst von: Priyanka Gupta, Hema Garg, Jayashree Mohanty, Bipin Kumar

Erschienen in: Journal of Polymer Research | Ausgabe 12/2020

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Abstract

Shape memory filaments have significant implications in smart wearable textiles, biomedical sutures, and additive manufacturing. However, the deterioration of shape memory performance over a range of temperature and strain limits their use in many high-end applications. This investigation reports the shape memory properties of segmented polyurethane filament and its detailed chemical and thermo-mechanical characterization. Shape memory polyurethane (SMPU) based on poly(1,6-hexanediol adipate) (PHA), 4,4′-diphenylmethane diisocyanate (MDI), and 1,4-butanediol (BDO) shows the transition temperature near body temperature. Hard segment and soft segment content in SMPU is 28.5% and 71.5% by weight. SMPU filament exhibited excellent shape recovery (~ 98%) and higher shape fixity (~ 80%) at a strain of 20%, 40%, and 60% and temperature of 30 ℃ and 50 ℃. Results have been supported by thermal and X-ray analysis. The cause of high fixity has been discussed in detail. Experimental results indicated higher crystallization and melting enthalpy. The cyclic test of SMPU filament showed almost complete shape recovery with no change in shape fixity under different thermo-mechanical conditions.

Vorheriger Artikel Electrospinning of antibacterial cellulose acetate/polyethylene glycol fiber with in situ reduced silver particles

Nächster Artikel Investigation of the influence of impurities on the ring-opening polymerisation of L-Lactide from biogenous feedstock

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Titel: Excellent memory performance of poly (1,6-hexanediol adipate) based shape memory polyurethane filament over a range of thermo-mechanical parameters
verfasst von: Priyanka Gupta
Hema Garg
Jayashree Mohanty
Bipin Kumar
Publikationsdatum: 01.12.2020
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 12/2020
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-020-02345-5

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