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Journal of Polymer Research

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01.07.2021 | ORIGINAL PAPER

Emulsion polymerization using three types of RAFT prepared well-defined polymeric stabilizers based on 2-dimethylaminoethyl methacrylate (DMAEMA) under CO₂ atmosphere: a comparative study

verfasst von: Maede Ramezanpour, Abbas Rezaee Shirin-Abadi

Erschienen in: Journal of Polymer Research | Ausgabe 7/2021

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Abstract

CO₂-responsive latexes have attracted increasing attention because of their applications in various fields such as gels, surfaces, latex particles, membranes, worm-like micelles (WLMs). Herein, poly(2-dimethylaminoethyl methacrylate) (PDMAEMA), poly(2-dimethylaminoethyl methacrylate)-block-poly(methyl methacrylate) (PDMAEMA-b-PMMA), and PDMAEMA-co-PMMA were synthesized through reversible addition fragmentation chain transfer (RAFT) solution polymerization, and applied as well-defined cationic stabilizers in emulsion (co)polymerization of styrene (St) and methyl methacrylate (MMA). Conducting reactions under CO₂ atmosphere was attempted to produce polymer latexes which were susceptible to be triggered by CO₂. The final latexes could be coagulated by N₂ bubbling, and subsequently redispersed by CO₂ bubbling. Restoration of original size, and zeta-potential as confirmed by DLS resulted in successful redispersion of the polymer latex. The results showed that acid dissociation constant (pK_a) has an effect on final conversion, and higher pK_a leads to higher conversion and increase in rate of polymerization. Random distributions of MMA units in PDMAEMA-co-PMMA resulted in an increase in the pK_a values causing facile protonation mainly due to the larger distance between nitrogen atoms.

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Titel: Emulsion polymerization using three types of RAFT prepared well-defined polymeric stabilizers based on 2-dimethylaminoethyl methacrylate (DMAEMA) under CO2 atmosphere: a comparative study
verfasst von: Maede Ramezanpour
Abbas Rezaee Shirin-Abadi
Publikationsdatum: 01.07.2021
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 7/2021
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-021-02619-6

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