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01.03.2023 | Original Paper

Thermal and mechanical properties of biodegradable nanocomposites prepared by poly(lactic acid)/acetyl tributyl citrate reinforced with attapulgite

verfasst von: Ya-Li Sun, Lian-Jie Tu, Chi-Hui Tsou, Shang-Ming Lin, Li Lin, Manuel Reyes De Guzman, Rui Zeng, Yiqing Xia

Erschienen in: Journal of Polymer Research | Ausgabe 3/2023

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Abstract

Attapulgite (ATT) is a multi-purpose nanomaterial, which can be used as a reinforcing filler for polylactic acid (PLA) and improve its barrier performance. However, due to the high content of ATT, it is easy to cause agglomeration. In this study, acetyl tributyl citrate (ATBC) was used to improve the toughness of PLA, and the plasticizer could reduce the polymer viscosity and improve the processability, which may contribute to the dispersion of ATT in PLA. The results show that a small amount of ATBC can improve the fracture elongation, crystallinity, water absorption, hydrolysis, and biodegradability of PLA. On the other hand, when ATT is added to PLA/ATBC sample by 10%, the tensile strength, and thermal degradation temperature can be greatly improved and reach the maximum value. Compared with pure PLA, the tensile strength is significantly increased by 33.4% (60.3 MPa), the elongation at break increased by 177.56%, and the thermal degradation temperature increased significantly by about 20.1 ℃. According to the scanning electron microscope and energy dispersive spectrometer, when ATT ≤ 10%, the nanofiller has excellent dispersion in the matrix, but when ATT > 10%, the nanofiller appears serious agglomeration and interfacial phase separation, which is caused by the incompatibility between PLA and ATT, so the performance of the nano composite is greatly reduced. From the results of soil burial and hydrolysis tests, the weight loss rate of PLA/ATBC samples increased with the increase of ATT nanofiller content. The influence of the internal and external tightness of the sample structure on the biodegradability was explained from the analysis results of water absorption and contact angle. The synergy of ATT and ATBC improves the comprehensive performance of PLA and increases its feasibility as a packaging material.

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Jašo V, Glenn G, Klamczynski A, Petrović ZS (2015) Biodegradability study of polylactic acid/thermoplastic polyurethane blends. Polym Test 47:1–3. https://doi.org/10.1016/j.polymertesting.2015.07.011CrossRef

Zhou Y, Hu P, Jiang J (2017) Metabolite characterization of a novel sedative drug, remimazolam in human plasma and urine using ultra high-performance liquid chromatography coupled with synapt high-definition mass spectrometry. J Pharm Biomed Anal 137:78–83. https://doi.org/10.1016/j.jpba.2017.01.016CrossRefPubMed

Kakroodi AR, Kazemi Y, Nofar M (2017) Tailoring poly (lactic acid) for packaging applications via the production of fully bio-based in situ microfibrillar composite films. Chem Eng J 308:772–782. https://doi.org/10.1016/j.cej.2016.09.130CrossRef

Yn Wang, Weng YX, Wang L (2014) Characterization of interfacial compatibility of polylactic acid and bamboo flour (PLA/BF) in biocomposites. Polym Test 36:119–125. https://doi.org/10.1016/j.polymertesting.2014.04.001CrossRef

Athanasiou KA, Niederauer GG, Agrawal CM (1996) Sterilization, toxicity, biocompatibility and clinical applications of polylactic acid/polyglycolic acid copolymers. Biomaterials 17:93–102. https://doi.org/10.1016/0142-9612(96)85754-1CrossRefPubMed

Armentano I, Bitinis N, Fortunati E, Mattioli S, Rescignano N, Verdejo R (2013) Multifunctional nanostructured PLA materials for packaging and tissue engineering. Prog Polym Sci 38:1720–1747. https://doi.org/10.1016/j.progpolymsci.2013.05.010CrossRef

Jin FL, Hu RR, Park SJ (2019) Improvement of thermal behaviors of biodegradable poly (lactic acid) polymer: a review. Compos B Eng 164:287–296CrossRef

Granda L, Espinach F, Tarrés Q, Méndez J, Delgado, Aguilar M, Mutjé P (2016) Towards a good interphase between bleached kraft softwood fibers and poly (lactic) acid. Compos B Eng 99:514–520. https://doi.org/10.1016/j.compositesb.2016.05.008CrossRef

Scaffaro R, Lopresti F, Botta L (2018) PLA based biocomposites reinforced with Posidonia oceanica leaves. Compos B Eng 139:1–11. https://doi.org/10.1016/j.compositesb.2017.11.048CrossRef

10.

Rasa RM, Janorkar AV, Hirt DE (2010) Poly (lactic acid) modifications. Prog Polym Sci 35:338–356. https://doi.org/10.1016/j.progpolymsci.2009.12.003CrossRef

11.

Daniel J, da Silva Derval S, Rosa (2022) Antimicrobial Performance of Bioinspired PLA Fabricated via One-Step Plasma Etching with Silver and Copper. ACS Appl Polym Mater 4(10):7162–7172. https://doi.org/10.1021/acsapm.2c01043

12.

Leal Filho W, Saari U, Fedoruk M, Iital A, Moora H, Klöga M (2019) An overview of the problems posed by plastic products and the role of extended producer responsibility in Europe. J Clean Prod 214:550–558. https://doi.org/10.1016/j.jclepro.2018.12.256CrossRef

13.

Nassar SF, Guinault A, Delpouve N, Divry V, Ducruet V, Sollogoub C (2017) Multi-scale analysis of the impact of polylactide morphology on gas barrier properties. Polymer 108:163–172. https://doi.org/10.1016/j.polymer.2016.11.047CrossRef

14.

Bai H, Huang C, Xiu H, Zhang Q, Fu Q (2014) Enhancing mechanical performance of polylactide by tailoring crystal morphology and lamellae orientation with the aid of nucleating agent. Polymer 55:6924–6934. https://doi.org/10.1016/j.polymer.2014.10.059CrossRef

15.

Becker JM, Pounder RJ, Dove AP (2010) Synthesis of poly (lactide) s with modified thermal and mechanical properties. Macromol Rapid Commun 31:1923–1937. https://doi.org/10.1002/marc.201000088CrossRefPubMed

16.

Zhang L, Zhao G, Wang G (2019) Investigation of the influence of pressurized CO 2 on the crystal growth of poly (l-lactic acid) by using an in situ high-pressure optical system. Soft Matter 15:5714–5727. https://doi.org/10.1039/C9SM00737GCrossRefPubMed

17.

Guinault A, Sollogoub C, Ducruet V, Domenek S (2012) Impact of crystallinity of poly (lactide) on helium and oxygen barrier properties. Eur Poly J 48:779–788. https://doi.org/10.1016/j.eurpolymj.2012.01.014CrossRef

18.

Kumar S, Bhatnagar N, Ghosh AK (2016) Effect of enantiomeric monomeric unit ratio on thermal and mechanical properties of poly (lactide). Poly Bull 73:2087–2104. https://doi.org/10.1007/s00289-015-1595-xCrossRef

19.

Gruber P, Drumright R, Henton D (2000) Polylactic acid technology. Adv Mater 12:1841–1846CrossRef

20.

D’amico DA, Montes MI, Manfredi LB, Cyras VP (2016) Fully bio-based and biodegradable polylactic acid/poly (3-hydroxybutirate) blends: Use of a common plasticizer as performance improvement strategy. Polym Test 49:22–28. https://doi.org/10.1016/j.polymertesting.2015.11.004CrossRef

21.

Signori F, Coltelli MB, Bronco S (2009) Thermal degradation of poly (lactic acid)(PLA) and poly (butylene adipate-co-terephthalate)(PBAT) and their blends upon melt processing. Polym Degrad Stab 94:74–82. https://doi.org/10.1016/j.polymdegradstab.2008.10.004CrossRef

22.

Graupner N, Poonsawat T, Narkpiban K, Jörg M (2023) Potential of Thai Bast Fibers for Injection Molded PLA Composites. J Renew Mater 11(5):2279–2300. https://doi.org/10.32604/jrm.2023.025529

23.

Chen P, Liang X, Xu Y, Zhou Y, Nie W (2018) Enhanced thermal and mechanical properties of PLA/MoS2 nanocomposites synthesized via the in-situ ring-opening polymerization. Appl Surf Sci 440:1143–1149. https://doi.org/10.1016/j.apsusc.2018.01.260CrossRef

24.

Sun N, Zhang Y, Ma L, Yu S, Li J (2017) Preparation and characterization of chitosan/purified attapulgite composite for sharp adsorption of humic acid from aqueous solution at low temperature. J Taiwan Inst Chem Eng 78:96–103. https://doi.org/10.1016/j.jtice.2017.03.017CrossRef

25.

Kaynak C, Sarı B (2016) Accelerated weathering performance of polylactide and its montmorillonite nanocomposite. App Clay Sci 121:86–94. https://doi.org/10.1016/j.clay.2015.12.025CrossRef

26.

Gazzotti S, Rampazzo R, Hakkarainen M, Bussini D, Ortenzi MA, Farina H et al (2019) Cellulose nanofibrils as reinforcing agents for PLA-based nanocomposites: an in situ approach. Compos Sci Technol 171:94–102. https://doi.org/10.1016/j.compscitech.2018.12.015CrossRef

27.

Wang Y, Mei Y, Wang Q, Wei W, Huang F, Li Y (2019) Improved fracture toughness and ductility of PLA composites by incorporating a small amount of surface-modified helical carbon nanotubes. Compos B Eng 162:54–61. https://doi.org/10.1016/j.compositesb.2018.10.060CrossRef

28.

Scaffaro R, Botta L, Maio A, Gallo G (2017) PLA graphene nanoplatelets nanocomposites: physical properties and release kinetics of an antimicrobial agent. Compos B Eng 109:138–146. https://doi.org/10.1016/j.compositesb.2016.10.058CrossRef

29.

Picard E, Espuche E, Fulchiron R (2011) Effect of an organo-modified montmorillonite on PLA crystallization and gas barrier properties. Appl Clay Sci 53:58–65. https://doi.org/10.1016/j.clay.2011.04.023CrossRef

30.

Nerantzaki M, Prokopiou L, Bikiaris DN, Patsiaoura D, Chrissafis K, Klonos P (2018) In situ prepared poly (DL-lactic acid)/silica nanocomposites: study of molecular composition, thermal stability, glass transition and molecular dynamics. Thermo Acta 669:16–29. https://doi.org/10.1016/j.tca.2018.08.025CrossRef

31.

Tsou CH, Yao WH, Lu YC, Tsou CY, Wu CS, Chen J, Wang RY, Su C, Hung WS, De GM, Suen MC (2017) Antibacterial property and cytotoxicity of a poly (lactic acid)/nanosilver-doped multiwall carbon nanotube nanocomposite. Polymers 9:100. https://doi.org/10.3390/polym9030100CundefinedaundefinedoundefinedCrossRefPubMedPubMedCentral

32.

Zheng L, Geng Z, Zhen W (2019) Preparation, characterization, and reaction kinetics of poly (lactic acid)/amidated graphene oxide nanocomposites based on reactive extrusion process. J Polym Res 26:1–13. https://doi.org/10.1007/s10965-019-1722-8CrossRef

33.

Kumar SR (2022) Effect of wood flour and nano-SiO2 on stimulus response, mechanical, and thermal behavior of 3D printed polylactic acid composites. Polym Adv Tech 33:4197–4205. https://doi.org/10.1002/pat.5851CrossRef

34.

Bajwa DS, Shojaeiarani J, Liaw JD, Bajwa SG (2021) Role of hybrid nano-zinc oxide and cellulose nanocrystals on the mechanical, thermal, and flammability properties of poly (lactic acid) polymer. J Compos Sci 543. https://doi.org/10.3390/jcs5020043

35.

Ng HM, Bee ST, Sin LT (2020) Interaction effect of scomberomorus guttatus-derived hydroxyapatite and montmorillonite on the characteristics of polylactic acid blends for biomedical application. J Polym Res 27:215. https://doi.org/10.1007/s10965-020-02138-wCrossRef

36.

Liu X, Wu Q (2001) PP/clay nanocomposites prepared by grafting-melt intercalation. Polymer 42:10013–10019. https://doi.org/10.1016/S0032-3861(01)00561-4CrossRef

37.

Ju Y, Wang T, Huang Y, Zhou L, Yang Y, Liao F (2016) The flame-retardance polylactide nanocomposites with nano attapulgite coated by resorcinol bis (diphenyl phosphate). J Vinyl Addit Technol 22:506–513. https://doi.org/10.1002/vnl.21469CrossRef

38.

Zhou Y, Lei L, Yang B, Li J, Ren J (2017) Preparation of PLA-based nanocomposites modified by nano-attapulgite with good toughness-strength balance. Polym Test 60:78–83. https://doi.org/10.1016/j.polymertesting.2017.03.007CrossRef

39.

Tsou CH, Guo J, Lei JA, De Guzman MR, Suen MC (2020) Characterizing attapulgite-reinforced nanocomposites of poly (lactic acid). Polym Sci Ser A 62:732–743. https://doi.org/10.1134/S0965545X20330068CrossRef

40.

Pla O, Guinea F, Louis E, Ghaisas S, Sander L (1998) Viscous effects in brittle fracture. Phys Rev B 57:R13981. https://doi.org/10.1103/PhysRevB.57.R13981CrossRef

41.

Shih YF, Huang CC (2011) Polylactic acid (PLA)/banana fiber (BF) biodegradable green composites. J Polym Res 18:2335–2340. https://doi.org/10.1007/s10965-011-9646-yCrossRef

42.

Su SK, Gu JH, Lee HT, Wu CL, Tsou CH, Suen MC (2016) Preparation and characterization of biodegradable polyurethanes composites containing thermally treated attapulgite nanorods. Polym Bull 73:3119–3141. https://doi.org/10.1007/s00289-016-1645-zCrossRef

43.

Zhang N, Yu X, Duan J, Yang JH, Huang T, Qi XD (2018) Comparison study of hydrolytic degradation behaviors between α′-and α-poly (l-lactide). Polym Degrad Stab 148:1–9. https://doi.org/10.1016/j.polymdegradstab.2017.12.014CrossRef

44.

Galli P, Danesi S, Simonazzi T (1984) Polypropylene based polymer blends: fields of application and new trends. Polym Eng Sci 24:544–554. https://doi.org/10.1002/pen.760240807CrossRef

45.

Yeh JT, Tsou CH, Li YM et al. (2012) The compatible and mechanical properties of biodegradable poly(Lactic Acid)/ethylene glycidyl methacrylate copolymer blends. J Polym Res 19(2) 9766. https://doi.org/10.1007/s10965-011-9766-4

46.

Tsou CH, Suen MC, Yao WH, Yeh JT, Wu CS, Tsou CY (2014) Preparation and characterization of bioplastic-based green renewable composites from tapioca with acetyl tributyl citrate as a plasticizer. Materials 7:5617–5632. https://doi.org/10.3390/ma7085617CrossRefPubMedPubMedCentral

47.

Chen ZJ, Tsou CH, Tsai ML, Guo J, De, Guzman MR, Yang T (2021) Barrier properties and hydrophobicity of biodegradable poly (lactic acid) composites reinforced with recycled chinese spirits distiller’s grains. Polymers 13:2861. https://doi.org/10.3390/polym13172861CrossRefPubMedPubMedCentral

48.

Guo J, Tsou CH, De Guzman MR, Wu CS, Zhang X, Chen Z (2021) Preparation and characterization of bio-based green renewable composites from poly (lactic acid) reinforced with corn stover. J Polym Res 28:1–15. https://doi.org/10.1007/s10965-021-02710-yCrossRef

49.

Vickers NJ (2017) Animal communication: when i’m calling you, will you answer too? Curr Biol 27:R713–R5. https://doi.org/10.1016/j.cub.2017.05.064CrossRef

50.

Wen YH, Tsou CH, De, Guzman MR, Wu WS, Liao B, Du J (2021) Preparation of antibacterial nanocomposites of zinc oxide-doped graphene reinforced polypropylene with high comprehensive properties. NANO 16:2150026. https://doi.org/10.1142/S1793292021500260CrossRef

51.

Ge FF, Tsou CH, Yuan S, De, Guzman MR, Zeng CY, Li J (2021) Barrier performance and biodegradability of antibacterial poly (butylene adipate-co-terephthalate) nanocomposites reinforced with a new MWCNT-ZnO nanomaterial. Nanotech 32:485706. https://doi.org/10.1088/1361-6528/ac1b52CrossRef

52.

Tsou CH, Zhao L, Gao C, Duan H, Lin X, Wen Y (2020) Characterization of network bonding created by intercalated functionalized graphene and polyvinyl alcohol in nanocomposite films for reinforced mechanical properties and barrier performance. Nanotechnology 31:385703. https://doi.org/10.1088/1361-6528/ab9786CrossRefPubMed

53.

Gálvez J, Correa Aguirre JP, Hidalgo Salazar MA, Vera Mondragón B, Wagner E, Caicedo C (2020) Effect of extrusion screw speed and plasticizer proportions on the rheological, thermal, mechanical, morphological and superficial properties of PLA. Polymers 12:2111. https://doi.org/10.3390/polym12092111CrossRefPubMedPubMedCentral

54.

Maiza M, Benaniba MT, Quintard G, Massardier, Nageotte V (2015) Biobased additive plasticizing polylactic acid (PLA). Polimeros 25:581–590. https://doi.org/10.1590/0104-1428.1986CrossRef

55.

Celebi H, Gunes E (2018) Combined effect of a plasticizer and carvacrol and thymol on the mechanical, thermal, morphological properties of poly (lactic acid). J Appl Polym Sci 135:45895. https://doi.org/10.1002/app.45895CrossRef

56.

Tsou CH, Ma ZL, De Guzman MR, Zhao L, Du J, Emori W (2022) High-performance antibacterial nanocomposite films with a 3D network structure prepared from carboxylated graphene and modified polyvinyl alcohol. Prog Org Coat 166:106805. https://doi.org/10.1016/j.porgcoat.2022.106805CrossRef

57.

Tsou CH, Wu CS, Hung WS, De, Guzman MR, Gao C, Wang RY (2019) Rendering polypropylene biocomposites antibacterial through modification with oyster shell powder. Polymer 160:265–271. https://doi.org/10.1016/j.polymer.2018.11.048CrossRef

58.

Tsou CH, Gao C, Guzman MD, Wu DY, Hung WS, Yuan L, Suen MC, Yeh JT (2018) Preparation and characterization of poly (lactic acid) with adipate ester added as a plasticizer. Poly Com 26:446–453. https://doi.org/10.1177/0967391118809210CrossRef

59.

Stoehr N et al (2014) Properties and weldability of plasticized polylactic acid films. J Appl Polym Sci 131:12

60.

Wu CS, Tsou CH (2019) Fabrication, characterization, and application of biocomposites from poly (lactic acid) with renewable rice husk as reinforcement. J Polym Res 26:1–9. https://doi.org/10.1007/s10965-019-1710-zCrossRef

61.

Tsou CH, Zeng R et al. (2023) Biological oyster shell waste enhances polyphenylene sulfide composites and endows them with antibacterial properties. Chin J Chem Eng. In Press https://doi.org/10.1016/j.cjche.2022.08.022

62.

Guo J, Tsou CH et al (2021) Conductivity and mechanical properties of carbon black-reinforced poly(lactic acid) (PLA/CB) composites. Iran Polym J 30(12)1251–1262. https://doi.org/10.1007/s13726-021-00973-2

63.

Promsorn J, Harnkarnsujarit N (2022) Pyrogallol loaded thermoplastic cassava starch based films as bio-based oxygen scavengers. Ind Crops Prod 186:115226. https://doi.org/10.1016/j.indcrop.2022.115226

64.

Ge FF, Wan N, Tsou CH (2022) Thermal properties and hydrophilicity of antibacterial poly(phenylene sulfide) nanocomposites reinforced with zinc oxide-doped multiwall carbon nanotubes. J Polym Res 29:83. https://doi.org/10.1007/s10965-022-02931-9CrossRef

65.

Tsou CH, Zeng R, Tsou CY, Mechanical (2022) Hydrophobic, and barrier properties of nanocomposites of modified polypropylene reinforced with low-content attapulgite. Polymers 14:3696. https://doi.org/10.3390/polym14173696CrossRefPubMedPubMedCentral

66.

Tsou CH, Yao WH, Wu CS, Tsou CY, Hung WS, Chen JC (2019) Preparation and characterization of renewable composites from Polylactide and Rice husk for 3D printing applications. J Polym Res 26:1–10. https://doi.org/10.1007/s10965-019-1882-6CrossRef

67.

Ma ZL, Tsou CH, Cui X, Wu J, Lin L, Wen H (2022) Barrier properties of nanocomposites from high-density polyethylene reinforced with natural attapulgite. Cu Res Gr Sus Chem 5:100314. https://doi.org/10.1016/j.crgsc.2022.100314CrossRef

68.

Phothisarattana D, Wongphan P, Promhuad K, Promsorn J, Harnkarnsujarit N (2021) Biodegradable poly (Butylene Adipate-Co-Terephthalate) and thermoplastic starch-blended TiO2 nanocomposite blown films as functional active packaging of fresh fruit. Polymers 13:4192. https://doi.org/10.3390/polym13234192CrossRefPubMedPubMedCentral

69.

Karst D, Yang Y (2006) Molecular modeling study of the resistance of PLA to hydrolysis based on the blending of PLLA and PDLA. Polymer 47:4845–4850. https://doi.org/10.1016/j.polymer.2006.05.002CrossRef

70.

Siparsky GL, Voorhees KJ, Miao F (1998) Hydrolysis of polylactic acid (PLA) and polycaprolactone (PCL) in aqueous acetonitrile solutions: autocatalysis. J Polym Environ 6:31–41. https://doi.org/10.1023/A:1022826528673CrossRef

71.

Karst D, Yang Y (2006) Molecular modeling study of the resistance of PLA to hydrolysis based on the blending of PLLA and PDLA. Polymer 47(13):4845–4850CrossRef

72.

Wongphan P, Khowthong M, Supatrawiporn T (2022) Novel edible starch films incorporating papain for meat tenderization. Food 31:100787. https://doi.org/10.1016/j.fpsl.2021.100787CrossRef

73.

Katekhong W, Wongphan P, Klinmalai P (2022) Thermoplastic starch blown films functionalized by plasticized nitrite blended with PBAT for superior oxygen barrier and active biodegradable meat packaging. Food Chem 374:131709. https://doi.org/10.1016/j.foodchem.2021.131709CrossRefPubMed

74.

Tsou CH, Ge FF et al (2023) Barrier and Biodegradable Properties of Poly(butylene adipate-co-terephthalate) Reinforced with ZnO-Decorated Graphene Rendering it Antibacterial. ACS Appl Polym Mater. In press https://doi.org/10.1021/acsapm.2c01507

75.

Wongphan P, Panrong T, Harnkarnsujarit N (2022) Effect of different modified starches on physical, morphological, thermomechanical, barrier and biodegradation properties of cassava starch and polybutylene adipate terephthalate blend film. Food Pack Shelf Life 32:100844. https://doi.org/10.1016/j.fpsl.2022.100844CrossRef

Titel: Thermal and mechanical properties of biodegradable nanocomposites prepared by poly(lactic acid)/acetyl tributyl citrate reinforced with attapulgite
verfasst von: Ya-Li Sun
Lian-Jie Tu
Chi-Hui Tsou
Shang-Ming Lin
Li Lin
Manuel Reyes De Guzman
Rui Zeng
Yiqing Xia
Publikationsdatum: 01.03.2023
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 3/2023
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-023-03483-2

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