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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2023

01.05.2023 | Original Paper

Role of gamma irradiation on ion diffusion of PEO-NH4I based solid polymer electrolytes

verfasst von: Mou Saha, Tapas Kumar Ballabh, Ruma Ray

Erschienen in: Journal of Polymer Research | Ausgabe 5/2023

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Abstract

This article proposes using a suitable proportion of high-energy radiation for property enhancement in solid polymer electrolytes (SPEs). Here, the effect of gamma irradiation has been investigated in proton-conducting SPEs prepared from host polymer Poly(ethylene)Oxide and the salt NH4I. Gamma radiation, combined with variation in salt concentration, modifies the structural, thermal and electrical properties of the SPE. High energy radiation produces scission and/or cross-linking of polymer molecules and changes the effective crystalline /amorphous proportion of the system. The microstructural analysis and variation in physicochemical properties within the specified range of irradiation dose (1 – 49 kGy) have been studied systematically in this article. Before irradiation, only varying salt concentration, maximum DC ionic conductivity (2.31 × 10–6 S/cm) of this two-phase (PEO–NH4I) SPE system is achieved at 12wt% NH4I at room temperature. Application of gamma irradiation enhances the conductivity almost by two orders of magnitude (2.06 × 10–4 S/cm) at 37 kGy at room temperature. Associated dielectric properties and underlying relaxation phenomena show corresponding variations. The ion transport mechanism is analysed in terms of energy-induced ion dissociation, modified carrier ions (n) and ease of mobility (μ) of the carrier ions through a more amorphous polymer substrate. This competing effect between n and μ nicely explains the contribution to the enhancement of ionic conductivity due to gamma radiation in SPEs.
Vorheriger Artikel The catalytic mechanism and limiting factor of polyamide hydrolysis for chemical recycling: the classic hydrolysis of polyamide 4

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Metadaten
Titel
Role of gamma irradiation on ion diffusion of PEO-NH4I based solid polymer electrolytes
verfasst von
Mou Saha
Tapas Kumar Ballabh
Ruma Ray
Publikationsdatum
01.05.2023
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2023
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-023-03561-5

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