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Journal of Sol-Gel Science and Technology

Erschienen in:

14.12.2019 | Original Paper: Sol–gel and hybrid materials with surface modification for applications

Synthesis of pyridyl Schiff base functionalized SBA-15 mesoporous silica for the removal of Cu(II) and Pb(II) from aqueous solution

verfasst von: Yuanyuan Zhang, Xiang Cao, Jiyuan Sun, Guohao Wu, Jie Wang, Dongen Zhang

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2020

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Abstract

SBA-15 mesoporous materials functionalized with N-propyl-2-pyridylimine and ethylenediaminepropyl-2-pyridylimine denoted as SBA-PA and SBA-NPA were prepared and used as adsorbents for decontamination of aqueous solutions from Cu(II) and Pb(II) ions. Batch tests were carried out and pH value of 5.0 was selected for the adsorption process. The experimental data were well represented by pseudo-second-order kinetic model and Langmuir isotherm model, indicating the adsorption was promoted by chemical process and occurred on monolayer. The theoretical maximum values of sorption capacities of SBA-PA and SBA-NPA for Cu(II) were 35.87 and 48.26 mg/g, and for Pb(II) were 82.05 and 106.62 mg/g, respectively. The adsorption of Cu(II) and Pb(II) was enhanced with the increase of temperature and the thermodynamics parameters were also studied. In addition, the two adsorbents could be easily regenerated over four times without significant loss of adsorption efficiency. Therefore, these nanocomposites prepared here could be promising for heavy metal ions removal in aqueous solution.

Vorheriger Artikel Impact of zinc doping on structural, optical, and electrical properties of CdO films prepared by sol–gel screen printing mechanism

Nächster Artikel Characterization and corrosion protection of nano-titanium dioxide doped BTSE-GPTMS sol–gel coating on cast Al–Si alloy

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O’Connell DW, Birkinshaw C, O’Dwyer TF (2008) Heavy metal adsorbents prepared from the modification of cellulose: a review. Bioresour Technol 99:6709–6724CrossRef

Zhao G, Huang X, Tang Z, Huang Q, Niu F, Wang X (2018) Polymer−based nanocomposites for heavy metal ions removal from aqueous solution: a review. Polym Chem 9:3562–3582CrossRef

Radi S, Tighadouini S, Bacquet M, Degoutin S, Janus L, Mabkhot YN (2016) Fabrication and covalent modification of highly chelated hybrid material based on silica-bipyridine framework for efficient adsorption of heavy metals: isotherms, kinetics and thermodynamics studies. RSC Adv 6:82505–82514CrossRef

Farooq R, Wang Y, Lin F, Shaukat SF, Donaldson J, Chouhdary AJ (2002) Effect of ultrasound on the removal of copper from the model solutions for copper electrolysis process. Water Res 36:3165–3169CrossRef

Da̧browski A, Hubicki Z, Podkościelny P, Robens E (2004) Selective removal of the heavy metal ions from waters and industrial wastewaters by ion−exchange method. Chemosphere 56:91–106CrossRef

Meunier N, Drogui P, Montané C, Hausler R, Mercier G, Blais J-F (2006) Comparison between electrocoagulation and chemical precipitation for metals removal from acidic soil leachate. J Hazard Mater 137:581–590CrossRef

Ndiaye PI, Moulin P, Dominguez L, Millet JC, Charbit F (2005) Removal of fluoride from electronic industrial effluentby RO membrane separation. Desalination 173:25–32CrossRef

Azimi A, Azari A, Rezakazemi M, Ansarpour M (2017) Removal of heavy metals from industrial wastewaters: a review. ChemBioEng Rev 4:37–59CrossRef

Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: A review. J Environ Manag 92:407–418CrossRef

10.

Hernández Rodiguez M, Yperman J, Carleer R, Maggen J, Dadi D, Gryglewicz G, Van der Bruggen B, Falcón Hernández J, Otero Calvis A (2018) Adsorption of Ni(II) on spent coffee and coffee husk based activated carbon. J Environ Chem Eng 6:1161–1170CrossRef

11.

Cegłowski M, Schroeder G (2015) Preparation of porous resin with Schiff base chelating groups for removal of heavy metal ions from aqueous solutions. Chem Eng J 263:402–411CrossRef

12.

Georgescu A-M, Nardou F, Zichil V, Nistor ID (2018) Adsorption of lead(II) ions from aqueous solutions onto Cr-pillared clays. Appl Clay Sci 152:44–50CrossRef

13.

Li H, Niu Y, Xue Z, Mu Q, Wang K, Qu R, Chen H, Bai L, Yang H, Wei D (2019) Adsorption property and mechanism of PAMAM dendrimer/silica gel hybrids for Fe(III) and Ag(I) from N,N-dimethylformamide. J Mol Liq 273:305–313CrossRef

14.

Da’na E (2017) Adsorption of heavy metals on functionalized-mesoporous silica: A review. Microporous Mesoporous Mater 247:145–157CrossRef

15.

Diagboya PNE, Dikio ED (2018) Silica-based mesoporous materials; emerging designer adsorbents for aqueous pollutants removal and water treatment. Microporous Mesoporous Mater 266:252–267CrossRef

16.

Cashin VB, Eldridge DS, Yu A, Zhao D (2018) Surface functionalization and manipulation of mesoporous silica adsorbents for improved removal of pollutants: a review. Environ Sci-Wat Res Technol 4:110–128CrossRef

17.

Mureseanu M, Reiss A, Stefanescu I, David E, Parvulescu V, Renard G, Hulea V (2008) Modified SBA-15 mesoporous silica for heavy metal ions remediation. Chemosphere 73:1499–1504CrossRef

18.

Gupta KC, Sutar AK (2008) Catalytic activities of Schiff base transition metal complexes. Coord Chem Rev 252:1420–1450CrossRef

19.

Chen X, Yamaguchi A, Namekawa M, Kamijo T, Teramae N, Tong A (2011) Functionalization of mesoporous silica membrane with a Schiff base fluorophore for Cu(II) ion sensing. Anal Chim Acta 696:94–100CrossRef

20.

Shiri−Yekta Z, Yaftian MR, Nilchi A (2013) Silica nanoparticles modified with a Schiff base ligand: An efficient adsorbent for Th(IV), U(VI) and Eu(III) ions. Korean J Chem Eng 30:1644–1651CrossRef

21.

Niu Y, Qu R, Chen H, Mu L, Liu X, Wang T, Zhang Y, Sun C (2014) Synthesis of silica gel supported salicylaldehyde modified PAMAM dendrimers for the effective removal of Hg(II) from aqueous solution. J Hazard Mater 278:267–278CrossRef

22.

Zhao J, Niu Y, Ren B, Chen H, Zhang S, Jin J, Zhang Y (2018) Synthesis of Schiff base functionalized superparamagnetic Fe3O4 composites for effective removal of Pb(II) and Cd(II) from aqueous solution. Chem Eng J 347:574–584CrossRef

23.

Wang Q, Gao W, Liu Y, Yuan J, Xu Z, Zeng Q, Li Y, Schröder M (2014) Simultaneous adsorption of Cu(II) and SO42− ions by a novel silica gel functionalized with a ditopic zwitterionic Schiff base ligand. Chem Eng J 250:55–65CrossRef

24.

Hami Dindar M, Yaftian MR, Pilehvari M, Rostamnia S (2015) SBA-15 mesoporous materials decorated with organic ligands: use as adsorbents for heavy metal ions. J Iran Chem Soc 12:561–572CrossRef

25.

Dindar MH, Yaftian MR, Rostamnia S (2015) Potential of functionalized SBA-15 mesoporous materials for decontamination of water solutions from Cr(VI), As(V) and Hg(II) ions. J Environ Chem Eng 3:986–995CrossRef

26.

Dolatyari L, Yaftian MR, Rostamnia S (2016) Removal of uranium(VI) ions from aqueous solutions using Schiff base functionalized SBA-15 mesoporous silica materials. J Environ Manag 169:8–17CrossRef

27.

Dolatyari L, Yaftian MR, Rostamnia S (2016) Adsorption characteristics of Eu(III) and Th(IV) ions onto modified mesoporous silica SBA-15 materials. J Taiwan Inst Chem Eng 60:174–184CrossRef

28.

Dindar MH, Yaftian MR, Hajihasani M, Rostamnia S (2016) Refinement of contaminated water by Cr(VI), As(V) and Hg(II) using N-donor ligands arranged on SBA-15 platform; batch and fixed-bed column methods. J Taiwan Inst Chem Eng 67:325–337CrossRef

29.

Enache DF, Vasile E, Simonescu CM, Culita D, Vasile E, Oprea O, Pandele AM, Razvan A, Dumitru F, Nechifor G (2018) Schiff base-functionalized mesoporous silicas (MCM-41, HMS) as Pb(II) adsorbents. RSC Adv 8:176–189CrossRef

30.

Parambadath S, Mathew A, Barnabas MJ, Kim SY, Ha C-S (2016) Concentration-dependant selective removal of Cr(III), Pb(II) and Zn(II) from aqueous mixtures using 5-methyl-2-thiophenecarboxaldehyde Schiff base-immobilised SBA-15. J Sol–Gel Sci Technol 79:426–439CrossRef

31.

Wu H, Xiao Y, Guo Y, Miao S, Chen Q, Chen Z (2020) Functionalization of SBA-15 mesoporous materials with 2-acetylthiophene for adsorption of Cr(III) ions. Microporous Mesoporous Mater 292:109754CrossRef

32.

Behbahani M, Najafi F, Amini MM, Sadeghi O, Bagheri A, Hassanlou PG (2014) Solid phase extraction using nanoporous MCM-41 modified with 3,4-dihydroxybenzaldehyde for simultaneous preconcentration and removal of gold(III), palladium(II), copper(II) and silver(I). J Ind Eng Chem 20:2248–2255CrossRef

33.

Saad EM, Hassan HMA, Soltan MS, Butler IS, Mostafa SI (2018) Removal of copper(II) ions from aqueous media by chemically modified MCM-41 with N-(3-(trimethoxysilyl)propyl)ethylenediamine and its 4-hydroxysalicylidene schiff-base. Environ Prog Sustain Energy 37:746–760CrossRef

34.

Zhang L, Hu X, Yu C, Crawford R, Yu A (2013) Preparation of sinapinaldehyde modified mesoporous silica materials and their application in selective extraction of trace Pb(II). Int J Environ Anal Chem 93:1274–1285CrossRef

35.

Arshadi M, Ghiaci M, Gil A (2011) Schiff base ligands immobilized on a nanosized SiO₂–Al₂O₃ mixed oxide as adsorbents for heavy metals. Ind Eng Chem Res 50:13628–13635CrossRef

36.

Boroumand Jazi M, Arshadi M, Amiri MJ, Gil A (2014) Kinetic and thermodynamic investigations of Pb(II) and Cd(II) adsorption on nanoscale organo-functionalized SiO₂Al₂O₃. J Colloid Interface Sci 422:16–24CrossRef

37.

Di Bernardo P, Zanonato PL, Tamburini S, Vigato PA (2007) Functionalisation of silica gel with cyclic and acyclic Schiff bases and related d- and/or f-metal complexes. Inorg Chim Acta 360:1083–1094CrossRef

38.

Sayari A, Han B-H, Yang Y (2004) Simple synthesis route to monodispersed SBA-15 Silica Rods. J Am Chem Soc 126:14348–14349CrossRef

39.

Rafatullah M, Sulaiman O, Hashim R, Ahmad A (2009) Adsorption of copper (II), chromium (III), nickel (II) and lead (II) ions from aqueous solutions by meranti sawdust. J Hazard Mater 170:969–977CrossRef

40.

Iftikhar AR, Bhatti HN, Hanif MA, Nadeem R (2009) Kinetic and thermodynamic aspects of Cu(II) and Cr(III) removal from aqueous solutions using rose waste biomass. J Hazard Mater 161:941–947CrossRef

41.

Wang T, Liu W, Xiong L, Xu N, Ni J (2013) Influence of pH, ionic strength and humic acid on competitive adsorption of Pb(II), Cd(II) and Cr(III) onto titanate nanotubes. Chem Eng J 215−216:366–374CrossRef

42.

Ge S, Geng W, He X, Zhao J, Zhou B, Duan L, Wu Y, Zhang Q (2018) Effect of framework structure, pore size and surface modification on the adsorption performance of methylene blue and Cu²⁺ in mesoporous silica. Colloids Surf A 539:154–162CrossRef

43.

Huang Q, Liu M, Deng F, Wang K, Huang H, Xu D, Zeng G, Zhang X, Wei Y (2016) Mussel inspired preparation of amine-functionalized Kaolin for effective removal of heavy metal ions. Mater Chem Phys 181:116–125CrossRef

44.

Niu L, Deng S, Yu G, Huang J (2010) Efficient removal of Cu(II), Pb(II), Cr(VI) and As(V) from aqueous solution using an aminated resin prepared by surface-initiated atom transfer radical polymerization. Chem Eng J 165:751–757CrossRef

45.

Shahbazi A, Younesi H, Badiei A (2011) Functionalized SBA-15 mesoporous silica by melamine-based dendrimer amines for adsorptive characteristics of Pb(II), Cu(II) and Cd(II) heavy metal ions in batch and fixed bed column. Chem Eng J 168:505–518CrossRef

46.

Wu Q, You R, Lv Q, Xu Y, You W, Yu Y (2015) Efficient simultaneous removal of Cu(II) and Cr₂O₇²⁻ from aqueous solution by a renewable amphoteric functionalized mesoporous silica. Chem Eng J 281:491–501CrossRef

Titel: Synthesis of pyridyl Schiff base functionalized SBA-15 mesoporous silica for the removal of Cu(II) and Pb(II) from aqueous solution
verfasst von: Yuanyuan Zhang
Xiang Cao
Jiyuan Sun
Guohao Wu
Jie Wang
Dongen Zhang
Publikationsdatum: 14.12.2019
Verlag: Springer US
Erschienen in: Journal of Sol-Gel Science and Technology / Ausgabe 3/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-019-05205-x

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