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Erschienen in: Journal of Nanoparticle Research 1/2013

01.01.2013 | Research Paper

Enhanced electromagnetic interference shielding effectiveness of polyaniline functionalized carbon nanotubes filled polystyrene composites

verfasst von: Parveen Saini, Veena Choudhary

Erschienen in: Journal of Nanoparticle Research | Ausgabe 1/2013

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Abstract

Multiwall carbon nanotubes (MWCNTs)/polystyrene composites were fabricated by solution processing route using non-covalently functionalized (polyaniline coated) MWCNTs. These composites exhibit an extremely low percolation threshold (0.12 vol.% MWCNT) along with micro porosity and are found to have potential applications in the areas of electromagnetic interference (EMI) shielding and electrostatic dissipation (ESD) with an ESD time of 0.78 s and shielding effectiveness of −23.3 dB (>99 % attenuation). The EMI shielding was found to be dominated by absorption (−18.7 dB) with a nominal contribution from reflection (−4.6 dB) that can explained in terms of multiple internal reflection phenomenon driven by high conductivity and the porous structure.

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Literatur
Zurück zum Zitat Ajayan PM, Schadler LS, Giannaris C, Rubio A (2000) Single-walled carbon nanotube-polymer composites: strength and weakness. Adv Mater 12:750–753CrossRef Ajayan PM, Schadler LS, Giannaris C, Rubio A (2000) Single-walled carbon nanotube-polymer composites: strength and weakness. Adv Mater 12:750–753CrossRef
Zurück zum Zitat Baughman RH, Zakhidov AA, de Heer A (2002) Carbon nanotubes—the route toward applications. Science 297:787–792CrossRef Baughman RH, Zakhidov AA, de Heer A (2002) Carbon nanotubes—the route toward applications. Science 297:787–792CrossRef
Zurück zum Zitat Blanchet GB, Fincher CR, Gao F (2003) Polyaniline nanotube composites: a high-resolution printable conductor. Appl Phys Lett 82:1290–1292CrossRef Blanchet GB, Fincher CR, Gao F (2003) Polyaniline nanotube composites: a high-resolution printable conductor. Appl Phys Lett 82:1290–1292CrossRef
Zurück zum Zitat Che RC, Peng LM, Duan XF, Chen XF, Liang XL (2004) Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Adv Mater 16:401–405CrossRef Che RC, Peng LM, Duan XF, Chen XF, Liang XL (2004) Microwave absorption enhancement and complex permittivity and permeability of Fe encapsulated within carbon nanotubes. Adv Mater 16:401–405CrossRef
Zurück zum Zitat Chung DDL (2001) Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39:279–285CrossRef Chung DDL (2001) Electromagnetic interference shielding effectiveness of carbon materials. Carbon 39:279–285CrossRef
Zurück zum Zitat Colaneri NF, Shacklette LW (1992) EMI shielding measurements of conductive polymer blends. IEEE Trans Instrum Meas 41:291–297CrossRef Colaneri NF, Shacklette LW (1992) EMI shielding measurements of conductive polymer blends. IEEE Trans Instrum Meas 41:291–297CrossRef
Zurück zum Zitat Eswaraiah V, Sankaranarayanan V, Ramaprabhu S (2011) Inorganic nanotubes reinforced polyvinylidene fluoride composites as low-cost electromagnetic interference shielding materials. Nanoscale Res Lett 6:137. doi:10.1186/1556-276X-6-137 CrossRef Eswaraiah V, Sankaranarayanan V, Ramaprabhu S (2011) Inorganic nanotubes reinforced polyvinylidene fluoride composites as low-cost electromagnetic interference shielding materials. Nanoscale Res Lett 6:137. doi:10.​1186/​1556-276X-6-137 CrossRef
Zurück zum Zitat Heeger AJ (2001) Semiconducting and metallic polymers: the fourth generation of polymeric materials. Angew Chem Int Ed 40:2591–2611CrossRef Heeger AJ (2001) Semiconducting and metallic polymers: the fourth generation of polymeric materials. Angew Chem Int Ed 40:2591–2611CrossRef
Zurück zum Zitat Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef
Zurück zum Zitat Joo J, Epstein AJ (1994) Electromagnetic radiation shielding by intrinsically conducting polymers. Appl Phys Lett 65:2278–2280CrossRef Joo J, Epstein AJ (1994) Electromagnetic radiation shielding by intrinsically conducting polymers. Appl Phys Lett 65:2278–2280CrossRef
Zurück zum Zitat Kim HM, Kim K, Lee CY, Joo J, Cho SJ, Yoon HS, Pejaković DA, Yoo JW, Epstein AJ (2004) Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst. Appl Phys Lett 84:589–591CrossRef Kim HM, Kim K, Lee CY, Joo J, Cho SJ, Yoon HS, Pejaković DA, Yoo JW, Epstein AJ (2004) Electrical conductivity and electromagnetic interference shielding of multiwalled carbon nanotube composites containing Fe catalyst. Appl Phys Lett 84:589–591CrossRef
Zurück zum Zitat Li N, Huang Y, Du V, He X, Lin X, Gao H, Ma Y, Li F, Chen Y, Eklund PC (2006) Electromagnetic interference (EMI) shielding of single-walled carbon nanotube epoxy composites. Nano Lett 6:1141–1145CrossRef Li N, Huang Y, Du V, He X, Lin X, Gao H, Ma Y, Li F, Chen Y, Eklund PC (2006) Electromagnetic interference (EMI) shielding of single-walled carbon nanotube epoxy composites. Nano Lett 6:1141–1145CrossRef
Zurück zum Zitat Li Y, Chen C, Li J-T, Zhang S, Ni Y, Cai S, Huang J (2010) Enhanced dielectric constant for efficient electromagnetic shielding based on carbon-nanotube-added styrene acrylic emulsion based composite. Nanoscale Res Lett 5:1170–1176CrossRef Li Y, Chen C, Li J-T, Zhang S, Ni Y, Cai S, Huang J (2010) Enhanced dielectric constant for efficient electromagnetic shielding based on carbon-nanotube-added styrene acrylic emulsion based composite. Nanoscale Res Lett 5:1170–1176CrossRef
Zurück zum Zitat MacDiarmid AG (2001) Synthetic metals: a novel role for organic polymers. Angew Chem Int Ed 40:2581–2590CrossRef MacDiarmid AG (2001) Synthetic metals: a novel role for organic polymers. Angew Chem Int Ed 40:2581–2590CrossRef
Zurück zum Zitat Park C, Ounaies Z, Watson KA, Crooks RE, Smith J, Lowther SE, Connell JW, Siochi EJ, Harrison JS, Clair TLS (2002) Dispersion of single wall carbon nanotubes by in situ polymerization under sonication. Chem Phys Lett 364:303–308CrossRef Park C, Ounaies Z, Watson KA, Crooks RE, Smith J, Lowther SE, Connell JW, Siochi EJ, Harrison JS, Clair TLS (2002) Dispersion of single wall carbon nanotubes by in situ polymerization under sonication. Chem Phys Lett 364:303–308CrossRef
Zurück zum Zitat Ramasubramaniam R, Chen J, Liu H (2003) Homogeneous carbon nanotube/polymer composites for electrical applications. Appl Phys Lett 83:2928–2930CrossRef Ramasubramaniam R, Chen J, Liu H (2003) Homogeneous carbon nanotube/polymer composites for electrical applications. Appl Phys Lett 83:2928–2930CrossRef
Zurück zum Zitat Saini P, Jalan R, Dhawan SK (2008) Synthesis and characterization of processable polyaniline doped with novel dopant NaSIPA. J Appl Polym Sci 108:1437–1446CrossRef Saini P, Jalan R, Dhawan SK (2008) Synthesis and characterization of processable polyaniline doped with novel dopant NaSIPA. J Appl Polym Sci 108:1437–1446CrossRef
Zurück zum Zitat Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK (2009) Polyaniline/MWCNT composites for microwave absorption and EMI shielding. Mater Chem Phys 113:919–926CrossRef Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK (2009) Polyaniline/MWCNT composites for microwave absorption and EMI shielding. Mater Chem Phys 113:919–926CrossRef
Zurück zum Zitat Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK (2011) Enhanced microwave absorption behavior of polyaniline-CNT/polystyrene blend in 12.4–18.0 GHz range. Synth Met 161:1522–1526CrossRef Saini P, Choudhary V, Singh BP, Mathur RB, Dhawan SK (2011) Enhanced microwave absorption behavior of polyaniline-CNT/polystyrene blend in 12.4–18.0 GHz range. Synth Met 161:1522–1526CrossRef
Zurück zum Zitat Saini P, Choudhary V, Dhawan SK (2012a) Improved microwave absorption and electrostatic charge dissipation efficiencies of conducting polymer grafted fabrics prepared via in situ polymerization. Polym Adv Technol 23:343–349CrossRef Saini P, Choudhary V, Dhawan SK (2012a) Improved microwave absorption and electrostatic charge dissipation efficiencies of conducting polymer grafted fabrics prepared via in situ polymerization. Polym Adv Technol 23:343–349CrossRef
Zurück zum Zitat Saini P, Choudhary V, Vijayan N, Kotnala RK (2012b) improved electromagnetic interference shielding response of poly (aniline)-coated fabrics containing dielectric and magnetic nanoparticles. J Phys Chem C 116:13403–13412CrossRef Saini P, Choudhary V, Vijayan N, Kotnala RK (2012b) improved electromagnetic interference shielding response of poly (aniline)-coated fabrics containing dielectric and magnetic nanoparticles. J Phys Chem C 116:13403–13412CrossRef
Zurück zum Zitat Sandler JKW, Kirk JE, Kinloch IA, Shaffer MSP, Windle AH (2003) Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer 44:5893–5899CrossRef Sandler JKW, Kirk JE, Kinloch IA, Shaffer MSP, Windle AH (2003) Ultra-low electrical percolation threshold in carbon-nanotube-epoxy composites. Polymer 44:5893–5899CrossRef
Zurück zum Zitat Sangermano M, Pegel S, Pötschke P, Voit B (2008) Antistatic epoxy coatings with carbon nanotubes obtained by cationic photopolymerization. Macromol Rapid Commun 29:396–400CrossRef Sangermano M, Pegel S, Pötschke P, Voit B (2008) Antistatic epoxy coatings with carbon nanotubes obtained by cationic photopolymerization. Macromol Rapid Commun 29:396–400CrossRef
Zurück zum Zitat Schulz RB, Plantz VC, Brush DR (1988) Shielding theory and practice. IEEE Trans 30:187–201 Schulz RB, Plantz VC, Brush DR (1988) Shielding theory and practice. IEEE Trans 30:187–201
Zurück zum Zitat Shirakawa H (2001) The discovery of polyacetylene film: the dawning of an era of conducting polymers. Angew Chem Int Ed 40:2574–2580CrossRef Shirakawa H (2001) The discovery of polyacetylene film: the dawning of an era of conducting polymers. Angew Chem Int Ed 40:2574–2580CrossRef
Zurück zum Zitat Singh BP, Prabha, Saini P, Gupta T, Garg P, Kumar G, Pandey I, Pandey S, Seth RK, Dhawan SK, Mathur RB (2011) Designing of multiwalled carbon nanotubes reinforced low density polyethylene nanocomposites for suppression of electromagnetic radiation. J Nanopart Res 13:7065–7074CrossRef Singh BP, Prabha, Saini P, Gupta T, Garg P, Kumar G, Pandey I, Pandey S, Seth RK, Dhawan SK, Mathur RB (2011) Designing of multiwalled carbon nanotubes reinforced low density polyethylene nanocomposites for suppression of electromagnetic radiation. J Nanopart Res 13:7065–7074CrossRef
Zurück zum Zitat Stafstrom S, Bredas JL, Epstein AJ, Woo HS, Tanner DB, Huang WS, MacDiarmid AG (1987) Polaron lattice in highly conducting polyaniline: theoretical and optical studies. Phys Rev Lett 59:1464–1467CrossRef Stafstrom S, Bredas JL, Epstein AJ, Woo HS, Tanner DB, Huang WS, MacDiarmid AG (1987) Polaron lattice in highly conducting polyaniline: theoretical and optical studies. Phys Rev Lett 59:1464–1467CrossRef
Zurück zum Zitat Ting TH, Jau YN, Yu RP (2012) Microwave absorbing properties of polyaniline/multi-walled carbon nanotube composites with various polyaniline contents. Appl Surf Sci 258:3184–3190CrossRef Ting TH, Jau YN, Yu RP (2012) Microwave absorbing properties of polyaniline/multi-walled carbon nanotube composites with various polyaniline contents. Appl Surf Sci 258:3184–3190CrossRef
Zurück zum Zitat Yang Y, Gupta MC, Dudley KL, Lawrence RW (2005) Novel carbon nanotube—polystyrene foam composites for electromagnetic interference shielding. Nano Lett 5:2131–2134CrossRef Yang Y, Gupta MC, Dudley KL, Lawrence RW (2005) Novel carbon nanotube—polystyrene foam composites for electromagnetic interference shielding. Nano Lett 5:2131–2134CrossRef
Metadaten
Titel
Enhanced electromagnetic interference shielding effectiveness of polyaniline functionalized carbon nanotubes filled polystyrene composites
verfasst von
Parveen Saini
Veena Choudhary
Publikationsdatum
01.01.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 1/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-012-1415-2

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