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Journal of Nanoparticle Research

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01.02.2018 | Research Paper

Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions

verfasst von: E. V. Abkhalimov, A. A. Timofeev, B. G. Ershov

Erschienen in: Journal of Nanoparticle Research | Ausgabe 2/2018

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Abstract

The transformation process of 20–50 nm silver nanoprisms in the presence of Cl-, Br-, and I- ions was studied. The threshold concentrations of halide ions that initiate the transformation do not depend on the size of nanoprisms. It was shown that the structure change is caused by the formation of poorly soluble silver complexes on nanoprisms and occurs by an electrochemical mechanism. The induction period preceding the onset of shape transformation is related to the formation of silver halide nanoelectrodes. The electrochemical reactions involving silver and silver halide nanoelectrodes induce restructuring of silver particles the efficiency of which is determined by electrode potentials.

Vorheriger Artikel An investigation on the preparation of nanocrystalline hydrous zirconia from zirconium tungstate

Nächster Artikel Hydrothermal preparation of blue molybdenum bronze nanoribbons: structural changes in mother crystals, related to solid-state conversion and crystallite splitting to nanomorphology

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Titel: Electrochemical mechanism of silver nanoprisms transformation in aqueous solutions containing the halide ions
verfasst von: E. V. Abkhalimov
A. A. Timofeev
B. G. Ershov
Publikationsdatum: 01.02.2018
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 2/2018
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-018-4133-6

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