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Erschienen in: Journal of Coatings Technology and Research 6/2012

01.11.2012

Preparation of hyperbranched polyester polyol-based urethane acrylates and applications on UV-curable wood coatings

verfasst von: Sümeyye Şabani, Ayşen H. Önen, Atilla Güngör

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 6/2012

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Abstract

In the present study, hyperbranched urethane acrylates (UA/HB-PEs) were synthesized by modifying the hydroxyl groups of hyperbranched polyester polyols (HB-PEs). The structure of oligomers were characterized by FTIR and 1H NMR spectroscopic techniques. Formulations containing UA/HB-PEs, reactive diluents, and photoinitiator were applied onto wood substrates and successfully polymerized under UV-irradiation. The coating performances and thermal properties of UV-cured films were evaluated. The studies on film characteristics reveal that the incorporation of UA/HB-PE afforded coatings with good adhesion and high gloss properties. It is observed that UV-cured coatings originated from [2,2-bis(4-β-hydroxyethoxy) phenyl propane] (HB-HEPA)- and [2,2-bis(4-β-hydroxyethoxy) phenyl 6F propane] (HB-HEPFA)-based oligomers possessed better surface and mechanical properties.

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Literatur
1.
Zurück zum Zitat Allen, NS, (ed.) Photopolymerisation and Photoimaging Science and Technology. Elsevier, London, 1989 Allen, NS, (ed.) Photopolymerisation and Photoimaging Science and Technology. Elsevier, London, 1989
2.
Zurück zum Zitat Pappas, SP, UV Curing: Science and Technology, Technology Marketing Corporation. Technology Marketing Corporation, Stanford, 1978 Pappas, SP, UV Curing: Science and Technology, Technology Marketing Corporation. Technology Marketing Corporation, Stanford, 1978
3.
Zurück zum Zitat Sacks, M, UV Curing of Coatings, Printing Inks and Adhesives, p. 152. Process Economics Program, Report, Menlo Park, CA, 1982 Sacks, M, UV Curing of Coatings, Printing Inks and Adhesives, p. 152. Process Economics Program, Report, Menlo Park, CA, 1982
4.
Zurück zum Zitat Hua, FJ, Hu, CP, “Morphology and Mechanical Properties of Urethane Acrylate Resin Networks.” J. Appl. Polym. Sci., 77 1532 (2000)CrossRef Hua, FJ, Hu, CP, “Morphology and Mechanical Properties of Urethane Acrylate Resin Networks.” J. Appl. Polym. Sci., 77 1532 (2000)CrossRef
5.
Zurück zum Zitat Chiang, WY, Chan, SC, “Preparation and Properties of UV-Autocurable BTDA-Based Polyester Multiacrylates. I. Effects of Acrylic Functionality and Polyol Molecular Weight.” J. Appl. Polym. Sci., 41 2971 (1990)CrossRef Chiang, WY, Chan, SC, “Preparation and Properties of UV-Autocurable BTDA-Based Polyester Multiacrylates. I. Effects of Acrylic Functionality and Polyol Molecular Weight.” J. Appl. Polym. Sci., 41 2971 (1990)CrossRef
6.
Zurück zum Zitat Shama, SA, Tortorello, AJ, “Effect of Structure on the Thermal Stability of Photocurable Urethane Acrylate Formulations.” J. Appl. Polym. Sci., 43 699 (1991)CrossRef Shama, SA, Tortorello, AJ, “Effect of Structure on the Thermal Stability of Photocurable Urethane Acrylate Formulations.” J. Appl. Polym. Sci., 43 699 (1991)CrossRef
7.
Zurück zum Zitat Kayaman-Apohan, N, Amanoela, A, Arsu, N, Güngör, A, “Synthesis and Characterization of UV-Curable Vinyl Ether Functionalized Urethane Oligomers.” Prog. Org. Coat., 49 23 (2004)CrossRef Kayaman-Apohan, N, Amanoela, A, Arsu, N, Güngör, A, “Synthesis and Characterization of UV-Curable Vinyl Ether Functionalized Urethane Oligomers.” Prog. Org. Coat., 49 23 (2004)CrossRef
8.
Zurück zum Zitat Oprea, S, “Synthesis and Characterization of Polyurethane Urea Acrylates: Effects of the Hard Segments Structure.” J. Appl. Polym. Sci., 105 2509 (2007)CrossRef Oprea, S, “Synthesis and Characterization of Polyurethane Urea Acrylates: Effects of the Hard Segments Structure.” J. Appl. Polym. Sci., 105 2509 (2007)CrossRef
9.
Zurück zum Zitat Miao, H, Huang, Z, Cheng, L, Shi, W, “Synthesis and Properties of Fluorinated Phosphate Acrylates Used for UV-Curing Coatings.” Prog. Org. Coat., 64 365 (2009)CrossRef Miao, H, Huang, Z, Cheng, L, Shi, W, “Synthesis and Properties of Fluorinated Phosphate Acrylates Used for UV-Curing Coatings.” Prog. Org. Coat., 64 365 (2009)CrossRef
10.
Zurück zum Zitat Yılmaz-Inan, T, Ekinci, E, Yıldız, E, Kuyulu, A, Güngör, A, “Preparation and Characterization of Novel UV-Curable Urethane Methacrylate Difunctional Monomers and Their Structure–Property Relationships.” Macromol. Chem. Phys., 202 532 (2001)CrossRef Yılmaz-Inan, T, Ekinci, E, Yıldız, E, Kuyulu, A, Güngör, A, “Preparation and Characterization of Novel UV-Curable Urethane Methacrylate Difunctional Monomers and Their Structure–Property Relationships.” Macromol. Chem. Phys., 202 532 (2001)CrossRef
11.
Zurück zum Zitat Hult, A, Johansson, M, Malmström, E, “Hyperbranched Polymers.” Adv. Polym. Sci., 143 1 (1999)CrossRef Hult, A, Johansson, M, Malmström, E, “Hyperbranched Polymers.” Adv. Polym. Sci., 143 1 (1999)CrossRef
12.
Zurück zum Zitat Kim, YH, “Hyperbranched Polymers 10 years After.” J. Polym. Sci.: A Polym. Chem., 36 1685 (1998)CrossRef Kim, YH, “Hyperbranched Polymers 10 years After.” J. Polym. Sci.: A Polym. Chem., 36 1685 (1998)CrossRef
13.
Zurück zum Zitat Malmström, E, Hult, A, “Kinetics of Formation of Hyperbranched Polyesters Based on 2,2-Bis(methylol)propionic Acid.” Macromolecules, 29 1222 (1996)CrossRef Malmström, E, Hult, A, “Kinetics of Formation of Hyperbranched Polyesters Based on 2,2-Bis(methylol)propionic Acid.” Macromolecules, 29 1222 (1996)CrossRef
14.
Zurück zum Zitat Asif, A, Shi, W, “Synthesis and Properties of UV Curable Waterborne Hyperbranched Aliphatic Polyester.” Eur. Polym. J., 39 933 (2003)CrossRef Asif, A, Shi, W, “Synthesis and Properties of UV Curable Waterborne Hyperbranched Aliphatic Polyester.” Eur. Polym. J., 39 933 (2003)CrossRef
15.
Zurück zum Zitat Zagar, E, Zigon, M, Podzimek, S, “Characterization of Commercial Aliphatic Hyperbranched Polyesters.” Polymer, 47 166 (2006)CrossRef Zagar, E, Zigon, M, Podzimek, S, “Characterization of Commercial Aliphatic Hyperbranched Polyesters.” Polymer, 47 166 (2006)CrossRef
16.
Zurück zum Zitat Fogelström, L, Antoni, P, Malmström, E, Hult, A, “UV-Curable Hyperbranched Nanocomposite Coatings.” Prog. Org. Coat., 55 284 (2006)CrossRef Fogelström, L, Antoni, P, Malmström, E, Hult, A, “UV-Curable Hyperbranched Nanocomposite Coatings.” Prog. Org. Coat., 55 284 (2006)CrossRef
17.
Zurück zum Zitat Tasic, S, Bozic, B, Dunjic, B, “Synthesis of New Hyperbranched Urethane-Acrylates and Their Evaluation in UV-Curable Coatings.” Prog. Org. Coat., 51 320 (2004)CrossRef Tasic, S, Bozic, B, Dunjic, B, “Synthesis of New Hyperbranched Urethane-Acrylates and Their Evaluation in UV-Curable Coatings.” Prog. Org. Coat., 51 320 (2004)CrossRef
18.
Zurück zum Zitat Xu, G, Shi, W, “Synthesis and Characterization of Hyperbranched Polyurethane Acrylates Used as UV Curable Oligomers for Coatings.” Prog. Org. Coat., 52 110 (2005)CrossRef Xu, G, Shi, W, “Synthesis and Characterization of Hyperbranched Polyurethane Acrylates Used as UV Curable Oligomers for Coatings.” Prog. Org. Coat., 52 110 (2005)CrossRef
19.
Zurück zum Zitat Malmström, E, Johansson, M, Hult, A, “Hyperbranched Aliphatic Polyesters.” Macromolecules, 28 1698 (1995)CrossRef Malmström, E, Johansson, M, Hult, A, “Hyperbranched Aliphatic Polyesters.” Macromolecules, 28 1698 (1995)CrossRef
20.
Zurück zum Zitat Kayaman-Apohan, N, Demirci, R, Cakir, M, Güngör, A, “UV-Curable Interpenetrating Polymer Networks Based on Acrylate/Vinyl Ether Functionalized Urethane Oligomers.” Radiat. Phys. Chem., 73 254 (2005)CrossRef Kayaman-Apohan, N, Demirci, R, Cakir, M, Güngör, A, “UV-Curable Interpenetrating Polymer Networks Based on Acrylate/Vinyl Ether Functionalized Urethane Oligomers.” Radiat. Phys. Chem., 73 254 (2005)CrossRef
21.
Zurück zum Zitat Awasthi, S, Agarwal, D, “The Effect of Difunctional Acids on the Performance Properties of Polyurethane Coatings.” J. Coat. Technol. Res., 6 329 (2009)CrossRef Awasthi, S, Agarwal, D, “The Effect of Difunctional Acids on the Performance Properties of Polyurethane Coatings.” J. Coat. Technol. Res., 6 329 (2009)CrossRef
22.
Zurück zum Zitat Yan, D, Zhou, Z, Müller, AHE, “Molecular Weight Distribution of Hyperbranched Polymers Generated by Self-Condensing Vinyl Polymerization in Presence of a Multifunctional Initiator.” Macromolecules, 32 245 (1999)CrossRef Yan, D, Zhou, Z, Müller, AHE, “Molecular Weight Distribution of Hyperbranched Polymers Generated by Self-Condensing Vinyl Polymerization in Presence of a Multifunctional Initiator.” Macromolecules, 32 245 (1999)CrossRef
23.
Zurück zum Zitat Hanselmann, R, Hölter, D, Frey, H, “Hyperbranched Polymers Prepared Via the Core-Dilution/Slow Addition Technique: Computer Simulation of Molecular Weight Distribution and Degree of Branching.” Macromolecules, 31 3790 (1998)CrossRef Hanselmann, R, Hölter, D, Frey, H, “Hyperbranched Polymers Prepared Via the Core-Dilution/Slow Addition Technique: Computer Simulation of Molecular Weight Distribution and Degree of Branching.” Macromolecules, 31 3790 (1998)CrossRef
24.
Zurück zum Zitat Chikh, L, Tessier, M, Fradet, A, “Polydispersity of Hyperbranched Polyesters Based on 2,2-Bis(hydroxymethyl)propanoic Acid: SEC/MALDI–TOF MS and 13C NMR/Kinetic-Recursive Probability Analysis.” Macromolecules, 41 9044 (2008)CrossRef Chikh, L, Tessier, M, Fradet, A, “Polydispersity of Hyperbranched Polyesters Based on 2,2-Bis(hydroxymethyl)propanoic Acid: SEC/MALDI–TOF MS and 13C NMR/Kinetic-Recursive Probability Analysis.” Macromolecules, 41 9044 (2008)CrossRef
25.
Zurück zum Zitat Vukovic, J, Steinmeier, D, Lechner, MD, Jovanovic, S, Bozic, B, “Thermal Degradation of Aliphatic Hyperbranched Polyesters and Their Derivatives.” Polym. Degrad. Stab., 91 1903 (2006)CrossRef Vukovic, J, Steinmeier, D, Lechner, MD, Jovanovic, S, Bozic, B, “Thermal Degradation of Aliphatic Hyperbranched Polyesters and Their Derivatives.” Polym. Degrad. Stab., 91 1903 (2006)CrossRef
26.
Zurück zum Zitat Magnusson, H, Malmström, E, Hult, A, “Structure Buildup in Hyperbranched Polymers from 2,2-Bis(hydroxymethyl)propionic Acid.” Macromolecules, 33 3099 (2000)CrossRef Magnusson, H, Malmström, E, Hult, A, “Structure Buildup in Hyperbranched Polymers from 2,2-Bis(hydroxymethyl)propionic Acid.” Macromolecules, 33 3099 (2000)CrossRef
27.
Zurück zum Zitat Chikh, L, Tessier, M, Fradet, A, “NMR and MALDI-TOF MS Study of Side Reactions in Hyperbranched Polyesters Based on 2,2-Bis(hydroxymethyl)propanoic Acid.” Polymer, 48 1884 (2007)CrossRef Chikh, L, Tessier, M, Fradet, A, “NMR and MALDI-TOF MS Study of Side Reactions in Hyperbranched Polyesters Based on 2,2-Bis(hydroxymethyl)propanoic Acid.” Polymer, 48 1884 (2007)CrossRef
28.
Zurück zum Zitat Hölter, D, Frey, H, “Degree of Branching in Hyperbranched Polymers.” Acta Polym., 48 298 (1997)CrossRef Hölter, D, Frey, H, “Degree of Branching in Hyperbranched Polymers.” Acta Polym., 48 298 (1997)CrossRef
29.
Zurück zum Zitat Dzunuzovic, E, Tasic, S, Bozic, B, Babic, D, Dunjic, B, “UV-Curable Hyperbranched Urethane Acrylate Oligomers Containing Soybean Fatty Acids.” Prog. Org. Coat., 52 136 (2005)CrossRef Dzunuzovic, E, Tasic, S, Bozic, B, Babic, D, Dunjic, B, “UV-Curable Hyperbranched Urethane Acrylate Oligomers Containing Soybean Fatty Acids.” Prog. Org. Coat., 52 136 (2005)CrossRef
30.
Zurück zum Zitat Bayramoglu, G, Kahraman, MV, Kayman-Apohan, N, Güngör, A, “The Coating Performance of Adipic Acid Modified and Methacrylated Bisphenol-A Based Epoxy Oligomers.” Polym. Adv. Technol., 18 173 (2007)CrossRef Bayramoglu, G, Kahraman, MV, Kayman-Apohan, N, Güngör, A, “The Coating Performance of Adipic Acid Modified and Methacrylated Bisphenol-A Based Epoxy Oligomers.” Polym. Adv. Technol., 18 173 (2007)CrossRef
Metadaten
Titel
Preparation of hyperbranched polyester polyol-based urethane acrylates and applications on UV-curable wood coatings
verfasst von
Sümeyye Şabani
Ayşen H. Önen
Atilla Güngör
Publikationsdatum
01.11.2012
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 6/2012
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-012-9418-6

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