Skip to main content
Erschienen in: Journal of Coatings Technology and Research 5/2013

01.09.2013

Comparison of corrosion performance of various conversion coatings on magnesium alloy using electrochemical techniques

verfasst von: R. Uma Rani, V. Maria Shalini, Hari Krishna Thota, A. K. Sharma

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 5/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Comparative studies on some of the important chemical conversion coatings, namely, phosphate–permanganate, galvanic black anodizing, dichromate treatment, and micro arc oxidized and modified acid fluoride anodizing on magnesium alloy AZ31B have been conducted. The surface morphology and composition of the coatings were examined through SEM and EDX techniques. Corrosion resistances of these coatings were compared using electrochemical impedance spectroscopy (EIS) and linear polarization studies. The corrosion resistances of the coatings investigated were found to be according to the order as follows: modified acid fluoride > micro arc oxidized phosphate > micro arc oxidized silicate > dichromate > galvanic black anodizing > phosphate-permanganate > bare magnesium.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Ambat, R, Zhou, W, “Electroless Nickel-Plating on AZ91D Magnesium Alloy: Effect of Substrate Microstructure and Plating Parameters.” Surf. Coat. Technol., 179 124–134 (2004)CrossRef Ambat, R, Zhou, W, “Electroless Nickel-Plating on AZ91D Magnesium Alloy: Effect of Substrate Microstructure and Plating Parameters.” Surf. Coat. Technol., 179 124–134 (2004)CrossRef
2.
Zurück zum Zitat Mordike, BL, Ebert, T, “Magnesium: Properties—Applications—Potential.” Mater. Sci. Eng. A., 302 37–45 (2001)CrossRef Mordike, BL, Ebert, T, “Magnesium: Properties—Applications—Potential.” Mater. Sci. Eng. A., 302 37–45 (2001)CrossRef
3.
Zurück zum Zitat Friedrich, H, Schumann, SJ, “Research for a “New Age of Magnesium” in the Automotive Industry.” Mater. Process. Technol., 117 276–281 (2001)CrossRef Friedrich, H, Schumann, SJ, “Research for a “New Age of Magnesium” in the Automotive Industry.” Mater. Process. Technol., 117 276–281 (2001)CrossRef
4.
Zurück zum Zitat Aghion, E, Bronfin, B, Eliezer, D, “The Role of the Magnesium Industry in Protecting the Environment.” J. Mater. Process. Technol., 117 381–385 (2001)CrossRef Aghion, E, Bronfin, B, Eliezer, D, “The Role of the Magnesium Industry in Protecting the Environment.” J. Mater. Process. Technol., 117 381–385 (2001)CrossRef
5.
Zurück zum Zitat Agnew, SR, Nie, JF, “Preface to the Viewpoint Set on: The Current State of Magnesium Alloy Science and Technology.” Scr. Mater., 63 671–673 (2010)CrossRef Agnew, SR, Nie, JF, “Preface to the Viewpoint Set on: The Current State of Magnesium Alloy Science and Technology.” Scr. Mater., 63 671–673 (2010)CrossRef
6.
Zurück zum Zitat Chen, X, Li, G, Lian, J, Jiang, Q, “An Organic Chromium-Free Conversion Coating on AZ91D Magnesium Alloy.” Appl. Surf. Sci., 255 2322–2328 (2008)CrossRef Chen, X, Li, G, Lian, J, Jiang, Q, “An Organic Chromium-Free Conversion Coating on AZ91D Magnesium Alloy.” Appl. Surf. Sci., 255 2322–2328 (2008)CrossRef
7.
Zurück zum Zitat Li, L, Cheng, Y, Wang, H, Zhang, Z, “Anodization of AZ91 Magnesium Alloy in Alkaline Solution Containing Silicate and Corrosion Properties of Anodized Films.” Trans. Nonferrous Met. Soc. China, 18 722–727 (2008)CrossRef Li, L, Cheng, Y, Wang, H, Zhang, Z, “Anodization of AZ91 Magnesium Alloy in Alkaline Solution Containing Silicate and Corrosion Properties of Anodized Films.” Trans. Nonferrous Met. Soc. China, 18 722–727 (2008)CrossRef
8.
Zurück zum Zitat Ghali, E, Corrosion Resistance of Aluminum and Magnesium Alloys-Understanding, Performance and Testing, 1st ed. Wiley, Hoboken, NJ (2010)CrossRef Ghali, E, Corrosion Resistance of Aluminum and Magnesium Alloys-Understanding, Performance and Testing, 1st ed. Wiley, Hoboken, NJ (2010)CrossRef
9.
Zurück zum Zitat Inoue, H, Sugahara, K, Yamamoto, A, Tsubakino, H, “Corrosion Rate of Magnesium and Its Alloys in Buffered Chloride Solutions.” Corros. Sci., 44 603–610 (2002)CrossRef Inoue, H, Sugahara, K, Yamamoto, A, Tsubakino, H, “Corrosion Rate of Magnesium and Its Alloys in Buffered Chloride Solutions.” Corros. Sci., 44 603–610 (2002)CrossRef
10.
Zurück zum Zitat Song, GL, Atrens, A, “Corrosion Mechanisms of Magnesium Alloys.” Adv. Eng. Mater., 1 11–33 (1999)CrossRef Song, GL, Atrens, A, “Corrosion Mechanisms of Magnesium Alloys.” Adv. Eng. Mater., 1 11–33 (1999)CrossRef
11.
Zurück zum Zitat Sharma, AK, Suresh, MR, Bhojraj, H, Narayanamurthy, H, Sahu, RP, “Electroless Nickel Plating on Magnesium Alloy.” Met. Finish., 96 (3) 10–18 (1998)CrossRef Sharma, AK, Suresh, MR, Bhojraj, H, Narayanamurthy, H, Sahu, RP, “Electroless Nickel Plating on Magnesium Alloy.” Met. Finish., 96 (3) 10–18 (1998)CrossRef
12.
Zurück zum Zitat Parthiban, GT, Muralidharan, S, Palaniswamy, N, Chittukala, K, Chanthraleka, D, Shamitha Begum, A, “Studies on Surface Treatment of Magnesium Alloy for Corrosion Protection.” J. Electrochem. Soc. India, 54 129–134 (2005) Parthiban, GT, Muralidharan, S, Palaniswamy, N, Chittukala, K, Chanthraleka, D, Shamitha Begum, A, “Studies on Surface Treatment of Magnesium Alloy for Corrosion Protection.” J. Electrochem. Soc. India, 54 129–134 (2005)
13.
Zurück zum Zitat Sharma, AK, Uma Rani, R, Giri, K, “Studies on Anodization of Magnesium Alloy for Thermal Control Applications.” Met. Finish., 95 (3) 43–51 (1997)CrossRef Sharma, AK, Uma Rani, R, Giri, K, “Studies on Anodization of Magnesium Alloy for Thermal Control Applications.” Met. Finish., 95 (3) 43–51 (1997)CrossRef
14.
Zurück zum Zitat Sharma, AK, Uma Rani, R, Mayanna, SM, “Thermal Studies on Electrodeposited Black Oxide Coating on Magnesium Alloys.” Thermochim. Acta, 376 67–75 (2001)CrossRef Sharma, AK, Uma Rani, R, Mayanna, SM, “Thermal Studies on Electrodeposited Black Oxide Coating on Magnesium Alloys.” Thermochim. Acta, 376 67–75 (2001)CrossRef
15.
Zurück zum Zitat Sharma, AK, “Role of Chemical Coatings in Space Applications—Recent Trends in Finishing of Light Metal Alloys.” Trans. SAEST, 30 (12) 1–13 (1995) Sharma, AK, “Role of Chemical Coatings in Space Applications—Recent Trends in Finishing of Light Metal Alloys.” Trans. SAEST, 30 (12) 1–13 (1995)
16.
Zurück zum Zitat Gray, JE, Luan, BJ, “Protective Coatings on Magnesium and Its Alloys—A Critical Review.” J. Alloys Compd., 336 88–113 (2002)CrossRef Gray, JE, Luan, BJ, “Protective Coatings on Magnesium and Its Alloys—A Critical Review.” J. Alloys Compd., 336 88–113 (2002)CrossRef
17.
Zurück zum Zitat Sharma, AK, “Galvanic Black Anodizing on Magnesium Alloy ZK 60A for Thermal Control Applications.” J. Spacecr. Technol., 7 (1) 49–57 (1997) Sharma, AK, “Galvanic Black Anodizing on Magnesium Alloy ZK 60A for Thermal Control Applications.” J. Spacecr. Technol., 7 (1) 49–57 (1997)
18.
Zurück zum Zitat Sharma, AK, Uma Rani, R, Bhojaraj, H, Narayanamurthy, H, “Galvanic Black Anodizing on Mg–Li Alloys.” J. Appl. Electrochem., 23 500–507 (1993) Sharma, AK, Uma Rani, R, Bhojaraj, H, Narayanamurthy, H, “Galvanic Black Anodizing on Mg–Li Alloys.” J. Appl. Electrochem., 23 500–507 (1993)
19.
Zurück zum Zitat Sharma, AK, Uma Rani, R, Afzar Malek, Acharya, KSN, Muddu, M, Sumeet Kumar, “Black Anodizing of a Magnesium–Lithium Alloy.” Met. Finish., 94 16–25 (1996)CrossRef Sharma, AK, Uma Rani, R, Afzar Malek, Acharya, KSN, Muddu, M, Sumeet Kumar, “Black Anodizing of a Magnesium–Lithium Alloy.” Met. Finish., 94 16–25 (1996)CrossRef
20.
Zurück zum Zitat Guo, HF, An, MZ, “Growth of Ceramic Coatings on AZ91D Magnesium Alloys by Micro-Arc Oxidation in Aluminate–Fluoride Solutions and Evaluation of Corrosion Resistance.” Appl. Surf. Sci., 246 229–238 (2005)CrossRef Guo, HF, An, MZ, “Growth of Ceramic Coatings on AZ91D Magnesium Alloys by Micro-Arc Oxidation in Aluminate–Fluoride Solutions and Evaluation of Corrosion Resistance.” Appl. Surf. Sci., 246 229–238 (2005)CrossRef
21.
Zurück zum Zitat Blawert, C, Dietzel, W, Ghali, E, Song, G, “Anodizing Treatments for Magnesium Alloys and Their Effect on Corrosion Resistance in Various Environments.” Adv. Eng. Mater., 8 511–533 (2006)CrossRef Blawert, C, Dietzel, W, Ghali, E, Song, G, “Anodizing Treatments for Magnesium Alloys and Their Effect on Corrosion Resistance in Various Environments.” Adv. Eng. Mater., 8 511–533 (2006)CrossRef
22.
Zurück zum Zitat Luo, H, Cai, Q, Wei, B, Yu, B, Li, D, He, J, Liu, Z, “Effect of (NaPO3)6 Concentrations on Corrosion Resistance of Plasma Electrolytic Oxidation Coatings Formed on AZ91D Magnesium Alloy.” J. Alloys Compd., 464 537–543 (2008)CrossRef Luo, H, Cai, Q, Wei, B, Yu, B, Li, D, He, J, Liu, Z, “Effect of (NaPO3)6 Concentrations on Corrosion Resistance of Plasma Electrolytic Oxidation Coatings Formed on AZ91D Magnesium Alloy.” J. Alloys Compd., 464 537–543 (2008)CrossRef
23.
Zurück zum Zitat Zuleta, AA, Correa, E, Villada, C, Sepulveda, MJ, Castano, JG, Echeverria, F, “Comparative Study of Different Environmentally Friendly (Chromium-Free) Methods for Surface Modification of Pure Magnesium.” Surf. Coat. Technol., 205 5254–5259 (2011)CrossRef Zuleta, AA, Correa, E, Villada, C, Sepulveda, MJ, Castano, JG, Echeverria, F, “Comparative Study of Different Environmentally Friendly (Chromium-Free) Methods for Surface Modification of Pure Magnesium.” Surf. Coat. Technol., 205 5254–5259 (2011)CrossRef
24.
Zurück zum Zitat Shashikala, AR, Uma Rani, R, Mayanna, SM, Sharma, AK, “Chemical Conversion Coatings on Magnesium Alloys—A Comparative Study.” Int. J. Electrochem. Sci., 3 993–1004 (2008) Shashikala, AR, Uma Rani, R, Mayanna, SM, Sharma, AK, “Chemical Conversion Coatings on Magnesium Alloys—A Comparative Study.” Int. J. Electrochem. Sci., 3 993–1004 (2008)
25.
Zurück zum Zitat Zhang, H, Yao, G, Wang, S, Liu, Y, Luo, H, “A Chrome-Free Conversion Coating for Magnesium–Lithium Alloy by a Phosphate–Permanganate Solution.” Surf. Coat. Technol., 202 1825–1830 (2008)CrossRef Zhang, H, Yao, G, Wang, S, Liu, Y, Luo, H, “A Chrome-Free Conversion Coating for Magnesium–Lithium Alloy by a Phosphate–Permanganate Solution.” Surf. Coat. Technol., 202 1825–1830 (2008)CrossRef
26.
Zurück zum Zitat Sharma, AK, Met. Finish., 91 57–63 (1993) Sharma, AK, Met. Finish., 91 57–63 (1993)
27.
Zurück zum Zitat Durney, LJ (ed.), Electroplating Engineering Hand Book. Van Nostrand Reinhold, New York (1987), pp 414, reprinted 2000 Durney, LJ (ed.), Electroplating Engineering Hand Book. Van Nostrand Reinhold, New York (1987), pp 414, reprinted 2000
28.
Zurück zum Zitat Zhao, H, Liu, Z, Han, Z, “A Comparison on Ceramic Coating Formed on AM50 Alloy by Micro-arc Oxidation in Two Electrolytes.” Mater. Sci. Forum, 546–549 575–578 (2007)CrossRef Zhao, H, Liu, Z, Han, Z, “A Comparison on Ceramic Coating Formed on AM50 Alloy by Micro-arc Oxidation in Two Electrolytes.” Mater. Sci. Forum, 546–549 575–578 (2007)CrossRef
29.
Zurück zum Zitat Hamdy, AS, Becccaria, AM, Spiniello, R, “The Effect of Cerium Pretreatment on the Corrosion Behaviour of Aluminium Composites.” Corros. Prev. Control, 48 101–109 (2001) Hamdy, AS, Becccaria, AM, Spiniello, R, “The Effect of Cerium Pretreatment on the Corrosion Behaviour of Aluminium Composites.” Corros. Prev. Control, 48 101–109 (2001)
30.
Zurück zum Zitat Lamakaa, SV, Knörnschildb, G, Snihirovaa, DV, Tarybaa, MG, Zheludkevichc, ML, Ferreiraa, MGS, “Complex Anticorrosion Coating for ZK30 Magnesium Alloy.” Electrochim. Acta, 55 131–141 (2009)CrossRef Lamakaa, SV, Knörnschildb, G, Snihirovaa, DV, Tarybaa, MG, Zheludkevichc, ML, Ferreiraa, MGS, “Complex Anticorrosion Coating for ZK30 Magnesium Alloy.” Electrochim. Acta, 55 131–141 (2009)CrossRef
31.
Zurück zum Zitat Cao, CN, Principle of Corrosion Electrochemistry. Chemistry Industry Press, Beijing (2004) Cao, CN, Principle of Corrosion Electrochemistry. Chemistry Industry Press, Beijing (2004)
32.
Zurück zum Zitat Stern, M, Geary, AL, “Electrochemical Polarization: I. A Theoretical Analysis of the Shape of Polarization Curves.” J. Electrochem. Soc., 104 56–63 (1957)CrossRef Stern, M, Geary, AL, “Electrochemical Polarization: I. A Theoretical Analysis of the Shape of Polarization Curves.” J. Electrochem. Soc., 104 56–63 (1957)CrossRef
Metadaten
Titel
Comparison of corrosion performance of various conversion coatings on magnesium alloy using electrochemical techniques
verfasst von
R. Uma Rani
V. Maria Shalini
Hari Krishna Thota
A. K. Sharma
Publikationsdatum
01.09.2013
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 5/2013
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-012-9466-y

Weitere Artikel der Ausgabe 5/2013

Journal of Coatings Technology and Research 5/2013 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.