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Journal of Coatings Technology and Research
Erschienen in: Journal of Coatings Technology and Research 4/2013

01.07.2013

Thermally curable benzoxazine-modified vegetable oil as a coating material

verfasst von: Can Yildirim, A. Tuncer Erciyes, Yusuf Yagci

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 4/2013

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Abstract

In this article, a new synthetic approach for the modification of partial glycerides (PG) obtained from sunflower oil with thermally curable benzoxazine units and its potential use as a coating material are described. For this purpose, hydroxyl-containing benzoxazine monomer was first prepared by conventional ring-forming reaction of phenol with paraformaldehyde in the presence of 6-amino-1-hexanol. The subsequent urethane reaction between PG and the benzoxazine monomer using toluene diisocyanate yields corresponding modified oil. The structures of the intermediates, and the modified triglycerides are confirmed by FTIR and 1H NMR spectral analysis. Thermally activated curing behaviors of the precursor and the modified oil in the absence of any catalyst were studied by differential scanning calorimetry. Thermal and film properties of the cured products were also investigated.
Vorheriger Artikel Improving hydrophobicity on polyurethane-based synthetic leather through plasma polymerization for easy care effect
Nächster Artikel Preparation and characterization of poly(trifluoropropylmethyl)siloxane-block-polyurethane-urea elastomers

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Metadaten
Titel
Thermally curable benzoxazine-modified vegetable oil as a coating material
verfasst von
Can Yildirim
A. Tuncer Erciyes
Yusuf Yagci
Publikationsdatum
01.07.2013
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 4/2013
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-013-9472-8

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