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International Journal of Plastics Technology
Erschienen in: International Journal of Plastics Technology 3/2014

01.12.2014 | Conference Report

Influence of surface modified nanoclay on electrochemical properties of PVDF-HFP composite electrolytes

verfasst von: K. Prabakaran, S. Mohanty, S. K. Nayak

Erschienen in: International Journal of Plastics Technology | Ausgabe 3/2014

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Abstract

Polymer electrolyte membranes have prepared for dye sensitized solar cells based on Polyvinylidene fluoride-co-hexaflouropropylene (PVDF-HFP) filled with silane modified Sodium montmorillonite (Na-MMT) nanofillers. Na-MMT nanoclay has modified using Aminopropyltrimethoxysilane and it is confirmed by FTIR and XRD. The XRD patterns of PVDF-HFP/Si-NaMMT proved that Si-NaMMT layers were completely exfoliated within the PVDF-HFP matrix. The influence of silane modified clay on the degree of crystallinity of the polymer matrix was studied by using DSC. The Electrochemical studies indicated that the addition of surface modified nanoclay increases the ionic conductivity up to 6.45 × 10−4 S/cm for 4 wt%, whereas the ionic conductivity about 1.14 × 10−4 S/cm with the addition of unmodified counterpart as the filler into the PVDF-HFP. The solid state dye sensitized solar cell has been fabricated by using silane modified Na-MMT/PVdF-HFP polymer nanocomposites electrolyte and Eosin-Y as a sensitizer. The photovoltaic characteristics showed an enhancement in open circuit voltage (Voc) from 0.26 to 0.32 V.
Vorheriger Artikel Numerical analysis of double pipe heat exchanger using heat transfer augmentation techniques
Nächster Artikel Dielectric characteristics of conductive carbon black filled ethylene-octene copolymer vulcanizates

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Literatur
1.
Lee RH, Liu JK, Ho JH, Chang JW, Liu BT, Wang HJ, Jeng RJ (2011) Synthesis of quaternized ammonium iodide-containing conjugated polymer electrolytes and their application in dye-sensitized solar cells. Polym Int 60:483–490CrossRef
2.
Sakamoto H, Igarashi S, Niume K, Nagai M (2011) Highly efficient all solid state dye-sensitized solar cells by the specific interaction of CuI with NCS groups. Org Electron 12:1247–1252CrossRef
3.
Kawano R, Katakabe T, Shimosawa H, Nazeeruddin MK, Grätzel M, Matsui H, Kitamura T, Tanabe N, Watanabe M (2010) Solid-state dye-sensitized solar cells using polymerized ionic liquid electrolyte with platinum-free counter electrode. Phys Chem Chem Phys 12:1916–1921CrossRef
4.
Wang P, Zakeeruddin SM, Moser JE, Nazeeruddin MK, Sekiguchi T, Grätzel M (2003) A stable quasi-solid-state dye-sensitized solar cell with an amphiphilic ruthenium sensitizer and polymer gel electrolyte. Nat Mater 2:402–407CrossRef
5.
Wu J, Hao S, Lan Z, Lin J et al (2008) All-solid-state dye-sensitized solar cell-based poly(N-alkyl-4-vinyl-pyridine iodide) electrolyte with efficiency of 5.64%. J Am Chem Soc 130:11568–11569CrossRef
6.
Kalaignan GP, Kang MS, Kang YS (2006) Effect of compositios on properties of PEO—KI-I2 salts polymer electrolytes for DSSC. Solid State Ionics 177:1091–1097CrossRef
7.
Nogueira AF, Durrant JR, De Paoli MA (2001) Dye-sensitized nanocrystalline solar cells employing a polymer electrolyte. Adv Mater 13:826–830CrossRef
8.
Li X, Zhao Y, Cheng L et al (2005) Enhanced ionic conductivity of poly(ethylene oxide) (PEO) electrolyte by adding mesoporous molecular sieve LiAlSBA. J Solid State Electrochem 9:609–615CrossRef
9.
Yoon S, Ichikawa K et al (1995) Spectroscopic analysis of chain conformation of poly(propylene oxide)-based polymer electrolytes. Macromolecules 28:4278–4283CrossRef
10.
Chew KW, Tan KW (2011) The effects of ceramic fillers on PMMA-based polymer electrolyte salted with lithium triflate, LiCF3SO3. Int J Electrochem Sci 6:5792–5801
11.
Yang Y, Zhang J et al (2008) Effect of lithium iodide addition on poly(ethylene oxide)-poly(vinylidene fluoride) polymer-blend electrolyte for dye-sensitized nanocrystalline solar cell. J Phys Chem B 112:6594–6602CrossRef
12.
Lee K-M, Suryanarayanan V, Ho K-C (2009) High efficiency quasi-solid-state dye-sensitized solar cell based on polyvinyidene fluoride-co-hexafluoro propylene containing propylene carbonate and acetonitrile as plasticizers. J Photochem Photobiol A Chem 207:224–230CrossRef
13.
Wang P, Zakeeruddin SM, Exnar I, Grätzel M (2002) High efficiency dye-sensitized nanocrystalline solar cells based on ionic liquid polymer gel electrolyte. Chem Commun 8:2972–2973. doi:10.​1039/​B209322G CrossRef
14.
Angulakshmi N, Thomas S, Nahm KS, Manuel Stephan A, Nimma Elizabeth R (2011) Electrochemical and mechanical properties of nanochitin-incorporated PVDF-HFP-based polymer electrolytes for lithium batteries. Ionics 17:407–414CrossRef
15.
Huo Z, Dai S, Wang K, Kong F, Zhang C, Pan X, Fang X (2007) Nanocomposite gel electrolyte with large enhanced charge transport properties of an I− 3/I− redox couple for quasi-solid-state dye-sensitized solar cells. Energy Mater Sol Cells 91:1959–1965CrossRef
16.
Singh PK, Bhattacharya B, Nagarle RK (2010) Effect of nano-TiO2 dispersion on PEO polymer electrolyte property. J Appl Polym Sci 118:2976–2980CrossRef
17.
Park S-J et al (2009) Effects of a silane treatment on the mechanical interfacial properties of montmorillonite/epoxy nanocomposites. Mater Sci Eng A 526:74–78CrossRef
18.
Liu Y, Lee JY, Hong L (2002) Synthesis, characterization and electrochemical properties of poly(methyl methacrylate)-grafted-poly(vinylidene fluoride-hexafluoropropylene) gel electrolytes. Solid State Ionics 150:317–326CrossRef
19.
Abbrent S, Plestil J et al (2001) Crystallinity and morphology of PVdF–HFP-based gel electrolytes. Polymer 42:1407–1416CrossRef
20.
Zhao J, Milanova M et al (2012) Colloids Surf A Physicochem Eng Asp 413:273–279CrossRef
21.
Chen-Rui et al (2001) Preparation and crystallization behavior of syndiotactic polystyrene–clay nanocomposites. Polymer 42:10063–10070CrossRef
22.
Nakagawa K, Ishida Y (1973) Dielectric relaxations and molecular motions in poly (vinylidene fluoride) with crystal form II. J Polym Sci: Polym Phys Ed 11:1503–1533
23.
Nakagawa K, Ishida Y (1973) Annealing effects in poly(Vinylidene Fluoride) as revealed by specific volume measurements differential scanning calorimetry, and electron microscopy. J Polym Sci B Polym Phys 1:2153–2171CrossRef
24.
Kodama H, Takahashi Y, Furukawa T (1999) Nonlinear dielectric investigation of trifluoroethylene-rich copolymers of vinylidene fluoride. Jpn J Appl Phys 38:3589–3595CrossRef
25.
Deka M, Kumar A (2011) Electrical and electrochemical studies of poly (vinylidene fluoride)–clay nanocomposite gel polymer electrolytes for Li-ion batteries. J Power Sources 196:1358–1364CrossRef
26.
Sharma AL, Thakur AK (2010) Polymer-ion-clay interaction based model for ion conduction in interaction-type polymer nanocomposite. Ionics 16:339–350CrossRef
27.
Soboleva T, Xie Z, Shi Z et al (2008) Investigation of the through-plane impedance technique for evaluation of anisotropy of proton conducting polymer membranes. J Electroanal Chem 622:145–152CrossRef
28.
Wang JC (1993) Model for impedance of a solid ionic conductor sandwiched between blocking electrodes. Electrochim Acta 38:2111–2114CrossRef
29.
Chiang CY, Jaipal Reddy M, Chu PP (2004) Nano-tube TiO2 composite PVdF/LiPF6 solid membranes. Solid State Ionics 175:631–635CrossRef
30.
Ramesh S, Ramesh K, Arof AK (2013) Fumed silica doped poly(Vinyl Chloride) poly(Ethylene Oxide) (PVC/PEO) based polymer electrolyte for lithium ion battery. Int J Electrochem Sci 8:8348–8355
31.
Rajkumar N, Kanmani SS, Ramachandran K (2011) Performance of dye-sensitized solar cell based on TiO2:ZnO nanocomposites. Adv Sci Lett 4:627–633CrossRef
32.
Lee KM, Suryanarayanan V, Hoc KC (2009) High efficiency quasi-solid-state dye-sensitized solar cell based on poly vinyidene fluoride-co-hexa fluoro propylene containing propylene carbonate and acetonitrile as plasticizers. J Photochem Photobiol A Chem 207:224–23015CrossRef
Metadaten
Titel
Influence of surface modified nanoclay on electrochemical properties of PVDF-HFP composite electrolytes
verfasst von
K. Prabakaran
S. Mohanty
S. K. Nayak
Publikationsdatum
01.12.2014
Verlag
Springer India
Erschienen in
International Journal of Plastics Technology / Ausgabe 3/2014
Print ISSN: 0972-656X
Elektronische ISSN: 0975-072X
DOI
https://doi.org/10.1007/s12588-014-9089-5

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