Trace elements in Holocene sediments of the southern Doñana National Park (SW Spain): historical pollution and applications

The multidisciplinary analysis of core sediments from Doñana National Park, south Spain, permits to delimitate both the paleoenvironmental changes and the geochemical evolution of this area during the Holocene. In a first phase (10–6.5 kyr cal), this area was occupied by freshwater/brackish marshes with periodical alternation of dry periods and humid intervals. In a second phase, these marshes were inundated during the Flandrian transgression (~6.5 kyr cal), with the deposition of bioclastic sands. The third phase (6.5–3.6 kyr cal) is characterized by the transition to an old lagoon, with unpolluted, bottom sediments. The geochemical concentrations of these clayey sediments can be used as a geochemical background for present-day and future environmental evaluations of this area. In the following 600 years approximately, two tsunamis caused the partial infilling of this area with bioclastic, marine sediments. In the interval comprised between these two tsunamis, this lagoon was polluted with heavy metals derived from historical mining activities. This environmental contamination represents one of the oldest evidences of mining pollution in the world (>3 kyr cal BP).