nach oben

Wood Science and Technology

Erschienen in:

01.04.2004 | Original

Hornification—its origin and interpretation in wood pulps

verfasst von: J. M. B. Fernandes Diniz, M. H. Gil, J. A. A. M. Castro

Erschienen in: Wood Science and Technology | Ausgabe 6/2004

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Although perfectly diagnosed in terms of the occurrence of physical changes, the hornification phenomenon, in its origin, has frequently been associated with the formation of irreversible or partially reversible hydrogen bonding in wood pulps or paper upon drying or water removal. Its characterisation has therefore been confusing and unsatisfactory. The authors propose that a sufficiently varied source of experimental data already exists to show that hornification is only a particular case of lactone bridge formation in lignocellulosic materials.

Vorheriger Artikel Chemical modification employed as a means of probing the cell-wall micropore of pine sapwood

Nächster Artikel Measurement of urea-formaldehyde resin distribution as a function of MDF fiber size by laser scanning microscopy

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Back EL (1967) Thermal auto-crosslinking in cellulose material. Pulp Pap Mag Can 68:T165–T171

Bawden AD, Kibblewhite RP (1995) Effects of multiple drying treatments on kraft fibre walls. In: Third research forum on recycling. CPPA, Vancouver, pp 171–177

Brecht W, Globig C (1954) Untersuchung eines gebleichten Strohzellstoffes auf seine papiertechnologischen Eigenschaften. Wochenbl Papierfabr 82:807–813

Ehrnrooth EML (1984) The swelling of dried and never-dried acid chlorite delignified fibers. Svensk Papperstidn 87:R74–R77

Fernandes Diniz JMB (1996) Application of chemical equilibrium to wood pulps. Holzforschung 50:429–433

Fernandes Diniz JMB, Pethybridge AD (1995) Interfering lactone formation in alkalimetric studies of paper woodpulps. Holzforschung 49:81–83

Frey-Wyssling A (1951) Über verbänderte Cellulosemikrofibrillen in Zellwänden. Holz als Roh- und Werkstoff 9:333–334

Gruber E, Weigert J (1998) Chemische Modifizierung von Zellstoffen zur Verminderung ihrer Verhornungsneigung. Papier 52:V20–V26

Higgins HG, McKenzie AW (1963) The structure and properties of paper. XIV. Effects of drying on cellulose fibres and the problem of maintaining pulp strength. Appita J 16:145–161

Howard RC (1990) The effects of recycling on paper quality. J Pulp Pap Sci 16:J143–J149

Israelachvili JN (1991) Intermolecular and surface forces, 2nd edn. Academic, San Diego, pp 123–125

Jayme G (1943) Über die Reaktionsfähigkeit von Zellstoffen. Cellulosechemie 21:73–86

Jayme G (1944) Mikro-Quellungsmessungen an Zellstoffen. Wochenbl Papierfabr 6:187–194

Jayme G, Hunger G (1956) Verhornungserscheinungen an Cellulosefaserstrukturen in elektroneoptischer Sicht. Monatshefte für Chemie 87:8–23

Jayme G, Hunger G (1957) The rearrangement of microfibrils in dried cellulose and the implication of this structure alteration on pulp properties. In: Bolam F (ed) Fundamentals of papermaking fibres. BPBMA, Cambridge, pp 263–270

Kato KL, Cameron RE (1999) A review of the relationship between thermally-accelerated ageing of paper and hornification. Cellulose 6:23–40CrossRef

Kaverzneva ED, Ivanov VI, Salova AS (1952) Chemical transformations of the macromolecule of cellulose under the action of oxidizing agents. VI. The presence in oxycelluloses of the groupings of carbonic esters and their effect on the determination of uronic carboxylic groups. Izvest Akad Nauk SSSR, Otdel Khim Nauk, pp 185–189

Kitayama T, Okayama T, Oye R (1983) Changes of chemical pulp fibres during recycling. In: International symposium on wood and pulping chemistry, vol 3. Japanese TAPPI, Tsukuba, pp 118–123

Klungness JH, Caufield DF (1982) Mechanisms affecting fiber bonding during drying and aging of pulps. TAPPI J 65:94–97

Krässig H (1984) Struktur und Reaktivität von Cellulosefasern. Papier 38:571–582

Laivins GV, Scallan AM (1993) The mechanism of hornification of wood pulps. In: Baker CF (ed) Products of papermaking. Trans 10th fundamental research symposium. Pira International, Oxford, pp 1235–1260

Lindström T (1986) The porous lamellar structure of the cell wall. In: Bristow JA, Kolseth P (eds) Paper, structure and properties. Marcel Dekker, New York, pp 99–109

Lindström T, Carlsson G (1982) The effect of carboxyl groups and their ionic form during drying on the hornification of cellulose fibers. Svensk Papperstidn 85:R146–R151

Maloney TC, Li TQ, Weise U, Paulapuro H (1997) Intra- and inter-fibre pore closure in wet pressing. Appita J 50:301–306

Minor JL (1994) Hornification—its origin and meaning. Progr Pap Recycling 3:93–95

Oksanen T, Buchert J, Viikari L (1997) The role of hemicelluloses in the hornification of bleached kraft pulps. Holzforschung 51:355–360

Rácz I, Borsa J (1997) Swelling of carboxymethylated cellulose fibres. Cellulose 4:293–303CrossRef

Robertson AA (1964) Some observations on the effects of drying papermaking fibres. Pulp Pap Mag Can 65:T161–T168

Ruffini G (1966) Improvement in bonding of wood pulps by the presence of acidic groups. Svensk Papperstidn 69:72–76

Samuelson O, Törnell B (1961) Influence of lactones upon the determination of carboxyl groups in cellulose. Svensk Papperstidn 64:198–203

Samuelson O, Wennerblom A (1955) Determination of carboxyl groups in cellulose. Svensk Papperstidn 58:713–716

Scallan AM, Katz S, Argyropoulos DS (1989) Conductometric titration of cellulose fibres. In: Schuerch C (ed) Cellulose and wood-chemistry and technology. Wiley, New York, pp 1457–1471

Slavik I, Kucerova M (1967) Formation of lactone bonds in cellulose during acidification and drying. Faserforsch Textiltech 18:396–397

Slavik I, Pasteka M, Kucerova M (1967) The behavior of lactone groups in cellulosic materials during the determination of carboxyl groups by different methods. Faserforsch Textiltech 18:4–8

Slavik I, Kucerova M (1969) Time profile of lactone and ester formation in cellulose upon acidification and drying. Faserforsch Textiltech 20:346–347

Smook GA (1990) Hornification (keyword). In: Handbook of pulp & paper terminology. Angus Wilde, Vancouver, p 135

Stakheeva-Kaverzneva ED, Salova AS (1951) Chemical changes of cellulose macromolecule under action of oxidizing agents. IV. Lactone links in the macromolecule of oxycellulose and their effect on determination of carbonyl groups by condensation with hydroxylamine. Izvest Akad Nauk SSSR, Otdel Khim Nauk 782–790

Stakheeva-Kaverzneva ED, Salova AS (1953). Specific method of determination of carbonyl groups in oxycellulose. Zhur Anal Khim 8:365–369

Stone JE, Scallan AM (1966) Influence of drying on the pore structures of the cell wall. In: Bolam F (ed) Consolidation of the paper web. BPBMA, London, pp 145–174

Stone JE, Scallan AM (1968) A structural model for the cell wall of waterswollen wood pulp fibres based on their accessability to macromolecules. Cell Chem Technol 2:343–358

Stone JE, Scallan AM, Abrahamson B (1968) Influence of beating on cell wall swelling and internal fibrillation. Svensk Papperstidn 71:687–694

Streitwieser A, Heathcock CH (1989) Introduction to organic chemistry, 3rd edn. Macmillan, New York, p 859

Weise U (1998) Hornification—mechanisms and terminology. Paperi Puu 80:110–115

Weise U, Hiltunen LE, Paulapuro H (1998) Verhornung von Zellstoff und Maßnahmen zu ihrer Reversion. Papier 52:V14–V19

Weise U, Paulapuro H (1996) The effect of drying and re-wetting cycles on fibre swelling. In: Proc fourth European workshop on lignocellulosics and pulp, advances in characterization and processing of wood, non-woody and secondary fibres, Stresa, Italy, 8–11 September 1996, pp 389–394

Wilson K (1966) Determination of carboxyl groups in cellulose. Svensk Papperstidn 69:386–390

Yasnovsky VM, MacDonald DM (1983) Prevention of hornification of dissolving pulp. US Patent 4,385,172, assigned to International Paper Co

Titel: Hornification—its origin and interpretation in wood pulps
verfasst von: J. M. B. Fernandes Diniz
M. H. Gil
J. A. A. M. Castro
Publikationsdatum: 01.04.2004
Verlag: Springer-Verlag
Erschienen in: Wood Science and Technology / Ausgabe 6/2004
Print ISSN: 0043-7719
Elektronische ISSN: 1432-5225
DOI: https://doi.org/10.1007/s00226-003-0216-2

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 6/2004

Measurement of urea-formaldehyde resin distribution as a function of MDF fiber size by laser scanning microscopy

Combined shear and compression analysis using the Iosipescu device: analytical and experimental studies of medium density fiberboard

Static bending properties of Finnish birch wood

Modification of wood with silicon compounds. Treatment systems based on organic silicon compounds — a review

Chemical modification employed as a means of probing the cell-wall micropore of pine sapwood

Effect of oxalic, acetic acid, and ammonia on leaching of Cr and Cu from preserved wood