Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Polymer Bulletin
Erschienen in: Polymer Bulletin 5/2013

01.05.2013 | Original Paper

Synthesis of ambient temperature self-crosslinking VTES-based core–shell polyacrylate emulsion via modified micro-emulsion polymerization process

verfasst von: Yun-fei Zhang, Lei Miao, Chao-long Yang, Man-geng Lu

Erschienen in: Polymer Bulletin | Ausgabe 5/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Modified micro-emulsion polymerization was successfully used to synthesize a kind of ambient temperature self-crosslinking core–shell emulsion, consisting of polyacrylate core and vinyltriethoxysilane (VTES) modified polyacrylate shell, by varying the ratio of soft monomer (BA) and hard monomer (MMA) which is different in the core and shell. The emulsion and its film formed at ambient temperature were characterized by attenuated total reflectance-fourier transform infrared spectroscopy (ATR-FTIR), transmission electron microscopy (TEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Core–shell structure was clearly shown in TEM micrographs, and two distinct glass transition temperatures (T g) were confirmed by DSC analysis. Lower T g of core phase analyzed by DSC and self-crosslinking properties of VTES characterized by crosslinking degree cause latex particles form continuous film at ambient temperature. Thermal and mechanical properties and the surface properties of the latex films were also investigated. Results showed that the core–shell latex films containing 5 and 7.5 % VTES exhibited higher thermal stability, better mechanical properties, higher contact angle, and water resistance compared with pure polyacrylate film.
Vorheriger Artikel Characterization and biodegradability of agricultural residue-filled polyester ecocomposites
Nächster Artikel Molecularly imprinted hydrogels for application in aqueous environment

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Amalvy JI (1996) Semicontinuous emulsion polymerization of methyl methacrylate, ethyl acrylate, and methacrylic acid. J Appl Polym Sci 59:339–344CrossRef
2.
Tigli RS, Evren V (2005) Synthesis and characterization of pure poly(acrylate) latexes. Prog Org Coat 52:144–150CrossRef
3.
Bakhshi H, Mohammad J, Mehr Z, Bouhendi H, Kabiri K (2011) Effect of functional monomer GMA on the physical–mechanical properties of coatings from poly(BA-MMA) latexes. J Mater Sci 46:2771–2777CrossRef
4.
Chen YJ, Zhang CC, Wang YF, Cheng SY, Chen PZ (2003) Study of self-crosslinking acrylate latex containing fluorine. J Appl Polym Sci 90:3609–3616CrossRef
5.
Esser RJ, Devona JE, Setzke DE, Wagemans L (1999) Waterbased crosslinkable surface coatings. Prog Org Coat 36:45–52CrossRef
6.
Inigo G, Jose MA, Jose RL (2006) Crosslinking in acetoacetoxy functional waterborne crosslinkable latexes. Macromol Symp 243:53–62CrossRef
7.
Liu XH, Zhang CZ, Xiong T, Chen DB, Zhong AY (2007) Rheological and curing behavior of aqueous ambient self-crosslinkable polyacrylate emulsion. J Appl Polym Sci 106:1448–1455CrossRef
8.
Christos K, Irini DS (2010) Synthesis and characterization of latexes based on copolymers BA\MMA\DAAM and BA\MMA\VEOVA-10\DAAM and the corresponding 1 K crosslinkable binder using the adipic acid dihydrazide as crosslinking agent. Prog Org Coat 69:504–509CrossRef
9.
Huang SQ, Fan DQ, Lei YQ, Huang H (2004) Alkoxysilane-functionalized acrylic copolymer latexes. I. Particle size, morphology, and film-forming properties. J Appl Polym Sci 94:954–960CrossRef
10.
Guo TY, Chen X, Hao GJ, Song MD, Zhang BH (2005) Preparation and properties of room temperature self-crosslinking poly(MMA-co-BA-co-St-co-VTES) latex film. Adv Polym Technol 24:288–295CrossRef
11.
Chen X, Guo TY, Hao GJ, Song MD, Zhang BH (2007) Preparation of (tri-isopropoxidesilane) acrylate latex and the properties of its film formed in room temperature. e-Polymers no. 084
12.
Zhu XL, Wang HY, Kong XZ, Zhang ZG (2009) Preparation and characterization of ambient self-crosslinking acrylic polymer latexes. Acta Polym Sin 1(5):471–477CrossRef
13.
Guo TY, Chen X, Song MD, Zhang BH (2006) Preparation and properties of core [poly(styrene-n-butyl acrylate)]-shell [poly(styrene-methyl methacrylate-vinyl triethoxide silane)] structured latex particles with self-crosslinking characteristics. J Appl Polym Sci 100:1824–1830CrossRef
14.
Liu BL, Deng XB, Cao SS, Li SJ, Luo R (2006) Preparation and characterization of core/shell particles with siloxane in the shell. Prog Org Coat 252:2235–2241
15.
Liu BL, Zhang BT, Cao SS, Deng XB, Hou XH, Chen HL (2008) Preparation of the stable core–shell latex particles containing organic-siloxane in the shell. Prog Org Coat 61:21–27CrossRef
16.
Mu YC, Qiu T, Li XY (2009) Monodisperse and multilayer core–shell latex via surface cross-linking emulsion polymerization. Mater Lett 63:1614–1617CrossRef
17.
Cheng XL, Chen ZX, Shi TS, Wang HY (2007) Synthesis and characterization of core–shell LIPN-fluorine-containing polyacrylate latex. Colloid Surf A 292:119–124CrossRef
18.
Cui XJ, Zhong SL, Gao Y, Wang HY (2008) Preparation and characterization of emulsifier-free core–shell interpenetrating polymer network-fluorinated polyacrylate latex particles. Colloid Surf A 324:14–21CrossRef
19.
Lami EB, Tissot I, Lefebvre F (2002) Synthesis and characterization of SiOH-functionalized polymer latexes using methacryloxy propyl trimethoxysilane in emulsion polymerization. Macromolecules 35:6185–6191CrossRef
20.
Ni KF, Shan GR, Weng ZX, Othman NS, Fevotte G, Lefebvre S, Lami EB (2005) Synthesis of hybrid core–shell nanoparticles by emulsion (co)polymerization of styrene and γ-methacryloxypropyltrimethoxysilane. Macromolecules 38:7321–7329CrossRef
21.
Suresh KI, Vishwanatham S, Bartsch E (2007) Viscoelastic and damping characteristics of poly(n-butyl acrylate)-poly(n-butyl methacrylate) semi-IPN latex films. Polym Adv Technol 18:364–372CrossRef
22.
Zhang JD, Yang MJ, Zhu YR, Yang H (2006) Synthesis and characterization of crosslinkable latex with interpenetrating network structure based on polystyrene and polyacrylate. Polym Int 55:951–960CrossRef
23.
Chen LJ, Wu FQ, Zhuang XY, Yang J, Li RX (2008) Preparation of styrene-acrylate latex used in ultra-low VOC building internal wall coating. J Wuhan Univ Technol 23:65–70CrossRef
24.
Pérez-Carrillo LA, Puca M, Rabelero M, Meza KE, Puig JE, Mendizábal E, López-Serranob F, Lópezc RG (2007) Effect of particle size on the mechanical properties of polystyrene and poly(butyl acrylate) core/shell polymers. Polymer 48:1212–1218CrossRef
25.
Liang JY, He L, Li WD, Luo HJ (2009) Synthesis and analysis of properties of a new core–shell silicon-containing fluoroacrylate latex. Polym Int 58:1283–1290CrossRef
26.
Xiao XY, Xu R (2011) Preparation and surface properties of core–shell polyacrylate latex containing fluorine and silicon in the shell. J Appl Polym Sci 119:1576–1585CrossRef
27.
Landfester K, Rothe R, Antonietti M (2002) Convenient synthesis of fluorinated latexes and core–shell structures by miniemulsion polymerization. Macromolecules 35:1658–1662CrossRef
28.
Cui XJ, Zhong SL, Wang HY (2007) Emulsifier-free core–shell polyacrylate latex nanoparticles containing fluorine and silicon in shell. Polymer 48:7241–7248CrossRef
29.
Cui XJ, Zhong SL, Wang HY (2007) Synthesis and characterization of emulsifier-free core–shell fluorine-containing polyacrylate latex. Colloid Surf A 303:173–178CrossRef
30.
Aguiar A, Villegas SG, Rabelero M, Mendizabal E, Puig JE (1999) Core–shell polymers with improved mechanical properties prepared by microemulsion polymerization. Macromolecules 32:6767–6771CrossRef
31.
Ming WH, Jones FN, Fu SK (1998) Synthesis of nanosize poly(methyl methacrylate) microlatexes with high polymer content by a modified microemulsion polymerization. Polym Bull 40:749–756CrossRef
32.
He GW, Pan QM, Rempel GL (2003) Synthesis of poly(methyl methacrylate) nanosize particles by differential microemulsion polymerization. Macromol Rapid Commun 24:585–588CrossRef
33.
He GW, Pan QM (2004) Synthesis of polystyrene and polystyrene/poly(methyl methacrylate) nanoparticles. Macromol Rapid Commun 25:1545–1548CrossRef
34.
Xu P, Zhong W, Wang HT, Tong R, Du QG (2004) On the copolymerization of acrylates in the modified microemulsion process. Colloid Polym Sci 282:1409–1414CrossRef
35.
Zhang L, Zhang C, Li GM (2007) Synthesis and properties of copolymer microemulsions of siloxane and acrylate with a high solid content. J Appl Polym Sci 104:851–857CrossRef
36.
Feng XP, Zhong AY, Chen DB (2006) Preparation and properties of poly(silicone-co-acrylate)/montmorillonite nanocomposite emulsion. J Appl Polym Sci 101:3963–3970CrossRef
Metadaten
Titel
Synthesis of ambient temperature self-crosslinking VTES-based core–shell polyacrylate emulsion via modified micro-emulsion polymerization process
verfasst von
Yun-fei Zhang
Lei Miao
Chao-long Yang
Man-geng Lu
Publikationsdatum
01.05.2013
Verlag
Springer-Verlag
Erschienen in
Polymer Bulletin / Ausgabe 5/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-012-0867-y

Weitere Artikel der Ausgabe 5/2013

Polymer Bulletin 5/2013 Zur Ausgabe

Original Paper

Influence of intercalated organoclay on the phase structure and physical properties of PTT–PTMO block copolymers

Original Paper

Molecularly imprinted hydrogels for application in aqueous environment

Original Paper

An insight on the effect of rubbing textile fiber on morphology of some semi-alicyclic polyimides for liquid crystal orientation

Original Paper

Characterization and biodegradability of agricultural residue-filled polyester ecocomposites

Original Paper

Synthesis of poly(arylene ether nitrile ketone)s bearing phthalazinone moiety and their properties

Original Paper

Electrical and rheological properties of MWCNT/polycarbonate nanocomposites

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise