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Polymer Bulletin
Erschienen in: Polymer Bulletin 11/2013

01.11.2013 | Original Paper

Thermal properties and characterization of surface-treated RSF-reinforced polylactide composites

verfasst von: Chin-San Wu, Hsin-Tzu Liao, Jheng-Jie Jhang, Jen-Taut Yeh, Chi-Yuan Huang, San-Lang Wang

Erschienen in: Polymer Bulletin | Ausgabe 11/2013

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Abstract

The thermal, mechanical, and biodegradation properties of composite materials made from polylactide (PLA) and rice straw fibre (RSF) were evaluated. To improve the properties of PLA/RSF composites, glycidyl methacrylate (GMA)-grafted polylactide (PLA-g-GMA) and treated (crosslinked) rice straw fibre (TRSF) were used to prepare the composites. The result showed that PLA-g-GMA/TRSF had noticeably superior mechanical properties compared with PLA/RSF because of greater compatibility between the polymer and TRSF. The dispersion of TRSF in the PLA-g-GMA matrix was more homogeneous, because branched and crosslinked macromolecules formed via condensation of the glycidyl methacrylate groups of PLA-g-GMA and the hydroxyl groups in TRSF. In addition, the PLA-g-GMA/TRSF composites were more easily processed because of their lower melt viscosities. The water resistance of PLA-g-GMA/TRSF was higher than that of PLA/RSF, although the weight loss of composites buried in soil compost indicated that both were biodegradable, especially at high levels of RSF substitution. The PLA/RSF and PLA-g-GMA/TRSF composites were more biodegradable than was pure PLA.
Vorheriger Artikel Synthesis and self-assembly properties of well-defined four-arm star poly(ε-caprolactone)-b-poly(N-vinylpyrrolidone) amphiphilic block copolymers

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Metadaten
Titel
Thermal properties and characterization of surface-treated RSF-reinforced polylactide composites
verfasst von
Chin-San Wu
Hsin-Tzu Liao
Jheng-Jie Jhang
Jen-Taut Yeh
Chi-Yuan Huang
San-Lang Wang
Publikationsdatum
01.11.2013
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 11/2013
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-013-1018-9

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