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Erschienen in: Polymer Bulletin 7/2017

04.11.2016 | Original Paper

Nanocomposites of polypropylene with halloysite nanotubes employing in situ polymerization

verfasst von: Maria de Fátima Vieira Marques, Jefferson Luis da Silva Rosa, Marcelo Cosme Vasconcelos da Silva

Erschienen in: Polymer Bulletin | Ausgabe 7/2017

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Abstract

Halloysite was used in its original form and also modified with vinyltrimethoxysilane (VTMS) or silicon chloride (SiCl4) for the synthesis of Ziegler–Natta catalysts supported on both magnesium chloride and halloysite. The polypropylenes synthesized with these catalysts were characterized as to their thermal properties and by dynamic mechanical measurements (DMTA). The results showed that throughout the investigated temperature range, the value of storage modulus (E′) of the PPs obtained with halloysite modified with SiCl4 was higher than that observed in the PP obtained without clay, as was the glass transition temperature. Therefore, good dispersion of natural halloysite nanotubes in the polymer matrix was obtained, as confirmed in the SEM micrographs.

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Literatur
1.
Zurück zum Zitat Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204CrossRef Paul DR, Robeson LM (2008) Polymer nanotechnology: nanocomposites. Polymer 49:3187–3204CrossRef
2.
Zurück zum Zitat Liaw WC, Huang PC, Chen CS, Lo CL, Chang JL (2008) J Appl Polym Sci 109:1871–1880CrossRef Liaw WC, Huang PC, Chen CS, Lo CL, Chang JL (2008) J Appl Polym Sci 109:1871–1880CrossRef
3.
Zurück zum Zitat Wang L, He A (2015) Microstructure and thermal properties of polypropylene/clay nanocomposites with TiCl4/MgCl2/Clay compound catalyst. J Nanomaterials 2015:1–5 Wang L, He A (2015) Microstructure and thermal properties of polypropylene/clay nanocomposites with TiCl4/MgCl2/Clay compound catalyst. J Nanomaterials 2015:1–5
4.
Zurück zum Zitat Du K, A-h He, F-y Bi, Han CC (2013) Synthesis of exfoliated isotactic polypropylene/functional alkyl-triphenylphosphonium-modified clay nanocomposites by in situ polymerization. Chin J Polym Sci 31(11):1501–1508CrossRef Du K, A-h He, F-y Bi, Han CC (2013) Synthesis of exfoliated isotactic polypropylene/functional alkyl-triphenylphosphonium-modified clay nanocomposites by in situ polymerization. Chin J Polym Sci 31(11):1501–1508CrossRef
5.
Zurück zum Zitat Yang K, Huang Y, Dong J-Y (2007) Efficient preparation of isotactic polypropylene/montmorillonite nanocomposites by in situ polymerization technique via a combined use of functional surfactant and metallocene catalysis. Polymer 48(21):6254–6261CrossRef Yang K, Huang Y, Dong J-Y (2007) Efficient preparation of isotactic polypropylene/montmorillonite nanocomposites by in situ polymerization technique via a combined use of functional surfactant and metallocene catalysis. Polymer 48(21):6254–6261CrossRef
6.
Zurück zum Zitat Kamble R, Ghag M, Gaikawad S, Panda BK (2012) Halloysite nanotubes and applications: a review. J Adv Scient Res 3(2):25–29 Kamble R, Ghag M, Gaikawad S, Panda BK (2012) Halloysite nanotubes and applications: a review. J Adv Scient Res 3(2):25–29
7.
Zurück zum Zitat Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39(8):1498–1525CrossRef Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39(8):1498–1525CrossRef
8.
Zurück zum Zitat Zhao M, Liu P (2008) Halloysite nanotubes/polystyrene (HNTS/PS) nanocomposites via in situ bulk polymerization. J Thermal Anal Calorim 94(1):103–107CrossRef Zhao M, Liu P (2008) Halloysite nanotubes/polystyrene (HNTS/PS) nanocomposites via in situ bulk polymerization. J Thermal Anal Calorim 94(1):103–107CrossRef
9.
Zurück zum Zitat Lin Y, Ng KM, Chan C-M, Sun G, Wu J (2011) High-impact polystyrene/halloysite nanocomposites prepared by emulsion polymerization using sodium dodecyl sulfate as surfactant. J Colloid Interface Sci 358(2):423–429CrossRef Lin Y, Ng KM, Chan C-M, Sun G, Wu J (2011) High-impact polystyrene/halloysite nanocomposites prepared by emulsion polymerization using sodium dodecyl sulfate as surfactant. J Colloid Interface Sci 358(2):423–429CrossRef
10.
Zurück zum Zitat Zhang L, Wang T, Liu P (2008) Polyaniline-coated halloysite nanotubes via in situ chemical polymerization. Appl Surf Sci 255(5):2091–2097CrossRef Zhang L, Wang T, Liu P (2008) Polyaniline-coated halloysite nanotubes via in situ chemical polymerization. Appl Surf Sci 255(5):2091–2097CrossRef
11.
Zurück zum Zitat Guo N, DiBenedetto SA, Kown D-K, Wang L, Russel MT, Lanagan MT, Facchetti A, Marks TJ (2007) Supported metallocene catalysis for in situ synthesis of high energy density metal oxide nanocomposites. J Am Chem Soc 129(4):766–767CrossRef Guo N, DiBenedetto SA, Kown D-K, Wang L, Russel MT, Lanagan MT, Facchetti A, Marks TJ (2007) Supported metallocene catalysis for in situ synthesis of high energy density metal oxide nanocomposites. J Am Chem Soc 129(4):766–767CrossRef
12.
Zurück zum Zitat Shamiri A, Chakrabarti MH, Jahan S, Hussain MA, Kaminsky W, Aravind PV, Yehye WA (2014) The influence of Ziegler–Natta and metallocene catalysts on polyolefin structure, properties, and processing ability. Materials 7:5069–5108CrossRef Shamiri A, Chakrabarti MH, Jahan S, Hussain MA, Kaminsky W, Aravind PV, Yehye WA (2014) The influence of Ziegler–Natta and metallocene catalysts on polyolefin structure, properties, and processing ability. Materials 7:5069–5108CrossRef
13.
Zurück zum Zitat Tong X, Liu C, Cheng H-M, Zhao H, Yang F, Zhang X (2004) Surface modification of single-walled carbon nanotubes with polyethylene via in situ Ziegler–Natta polymerization. J Appl Polym Sci 92(6):3697–3700CrossRef Tong X, Liu C, Cheng H-M, Zhao H, Yang F, Zhang X (2004) Surface modification of single-walled carbon nanotubes with polyethylene via in situ Ziegler–Natta polymerization. J Appl Polym Sci 92(6):3697–3700CrossRef
14.
Zurück zum Zitat Panupakorn P, Chaichana E, Praserthdam P, Jongsomjit B (2013) Polyethylene/clay nanocomposites produced by in situ polymerization with zirconocene/MAO catalyst. J Nanomaterials 2013:1–9CrossRef Panupakorn P, Chaichana E, Praserthdam P, Jongsomjit B (2013) Polyethylene/clay nanocomposites produced by in situ polymerization with zirconocene/MAO catalyst. J Nanomaterials 2013:1–9CrossRef
15.
Zurück zum Zitat Du M, Guo B, Jia D (2006) Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene). Eur Polym J 42(6):1362–1369CrossRef Du M, Guo B, Jia D (2006) Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene). Eur Polym J 42(6):1362–1369CrossRef
16.
Zurück zum Zitat Deepak R, Agrawal YK (2012) Study of nanocomposites with emphasis to halloysite nanotubes. Rev Adv Mater Sci 32(2):149–157 Deepak R, Agrawal YK (2012) Study of nanocomposites with emphasis to halloysite nanotubes. Rev Adv Mater Sci 32(2):149–157
Metadaten
Titel
Nanocomposites of polypropylene with halloysite nanotubes employing in situ polymerization
verfasst von
Maria de Fátima Vieira Marques
Jefferson Luis da Silva Rosa
Marcelo Cosme Vasconcelos da Silva
Publikationsdatum
04.11.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Polymer Bulletin / Ausgabe 7/2017
Print ISSN: 0170-0839
Elektronische ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-016-1848-3

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