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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 3/2016

01.03.2016 | Original Contribution

Thermal and morphological studies of poly(vinyl alcohol)/poly(vinyl pyrrolidone)/organoclay nanocomposites containing L-leucine moiety

verfasst von: S. Mallakpour, M. Khani

Erschienen in: Colloid and Polymer Science | Ausgabe 3/2016

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Abstract

This work is devoted to the synthesis and characterization of poly(vinyl alcohol) (PVA)/poly(vinyl pyrrolidone) (PVP)/organoclay (OC) (PPOC) hybrid and comparison between PPOC, PVA/PVP matrix, and PVA/OC (POC) nanocomposite (NC). The PPOC NCs were prepared by mixing a colloidal swelled solution consisting of OC with a water solution of PVA and PVP in the 3:1 weight ratio of PVA to PVP. L-Leucine ammonium ion-exchanged clay was utilized as the nanofiller. The obtained NCs were characterized by Fourier transform infrared, X-ray diffraction, field emission scanning electron microscopy, thermogravimetric analysis, and transmission electron microscopy. The morphological studies indicate that the flake structured OC is rather homogeneously dispersed in host matrix. The PPOC NCs exhibited improved thermal stability compared with pure polymers and POC NC. The improvement of thermal properties was attributed to the homogeneous and good dispersion of OC in the polymeric matrix and the strong hydrogen bonding between O–H of PVA, C = O of PVP, and Si–O of OC.
Vorheriger Artikel Surface structure of aqueous ionic surfactant solutions and effects of solvent therein—a computer simulation study
Nächster Artikel Ionic dye–surfactant nanoassemblies: interplay of electrostatics, hydrophobic effect, and π–π stacking

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Metadaten
Titel
Thermal and morphological studies of poly(vinyl alcohol)/poly(vinyl pyrrolidone)/organoclay nanocomposites containing L-leucine moiety
verfasst von
S. Mallakpour
M. Khani
Publikationsdatum
01.03.2016
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 3/2016
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3820-4

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