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Clean Technologies and Environmental Policy

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01.03.2015 | Original paper

Removal of lead (II) and nickel (II) ions from aqueous solution using activated carbon prepared from rapeseed oil cake by Na₂CO₃ activation

verfasst von: Suat Uçar, Murat Erdem, Turgay Tay, Selhan Karagöz

Erschienen in: Clean Technologies and Environmental Policy | Ausgabe 3/2015

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Abstract

In this study, rapeseed oil cake as a precursor was used to prepare activated carbons by chemical activation with sodium carbonate (Na₂CO₃) at 600 and 800 °C. The activated carbon with the highest surface area of 850 m² g⁻¹ was produced at 800 °C. The prepared activated carbons were mainly microporous. The activated carbon having the highest surface area was used as an adsorbent for the removal of lead (II) and nickel (II) ions from aqueous solutions. The effects of pH, contact time, and initial ion concentration on the adsorption capacity of the activated carbon were investigated. The kinetic data of adsorption process were studied using pseudo-first-order, pseudo-second-order kinetic models and intraparticle diffusion model. The experimental data were well adapted to the pseudo-second-order model for both tested ions. The adsorption data for both ions were well correlated with Langmuir isotherm. The maximum monolayer adsorption capacities of the activated carbon for the removal of lead (II) and nickel (II) ions were determined as 129.87 and 133.33 mg g⁻¹, respectively.

Vorheriger Artikel Nitrification and denitrification characteristics in a sequencing batch reactor treating tannery wastewater

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Adamson AW (1960) Physical Chemistry of Surface. Interscience Publication, New York

Addoun A, Dentze J, Ehrburger P (2002) Porosity of carbons obtained by chemical activation: effect of the nature of the alkaline carbonates. Carbon 40(7):1140–1143CrossRef

Amin MN, Mustafa AI, Khalil MI, Rahman M, Nahid I (2012) Adsorption of phenol onto rice straw biowaste for water purification. Clean Technol Environ Policy 14:837–844CrossRef

Anoop Krishnan K, Sreejalekshmi KG, Baiju RS (2011) Nickel (II) adsorption onto biomass based activated carbon obtained from sugarcane bagasse pith. Biores Technol 102:10239–10247CrossRef

Bacaoui A, Yaacoubi A, Dahbi A, Bennouna C, Phan Tan Luu R, Maldonado-Hodar FJ, Rivera-Utrilla J, Moreno-Castilla C (2001) Optimization of conditions for the preparation of activated carbons from olive-waste cakes. Carbon 39:425–432CrossRef

Basso MC, Cerella EG, Cukierman AL (2002) Activated carbons developed from a rapidly renewable biosource for removal of Cadmium (II) and Nickel (II) Ions from dilute aqueous solution. Ind Eng Chem Res 41:180–189CrossRef

Boehm HP (1966) Chemical identification of surface groups. Adv Catal 16:179–274

Chouchene A, Jeguirim M, Trouve G (2014) Biosorption performance, combustion behavior, and leaching characteristics of olive solid waste during the removal of copper and nickel from aqueous solutions. Clean Technol Environ Policy 16:979–986CrossRef

Cimino G, Cappello RM, Caristi C, Toscano G (2005) Characterization of carbons from olive cake by sorption of wastewater pollutants. Chemosphere 61:947–955CrossRef

Dias JM, Alvim-Ferraz MCM, Almeida MF, Rivera-Utrilla J, Sánchez-Polo M (2007) Waste materials for activated carbon preparation and its use in aqueous-phase treatment: a review. J Environ Manag 85:833–846CrossRef

El-Ashtoukhya ESZ, Amin NK, Abdelwahabb O (2008) Removal of lead (II) and copper (II) from aqueous solution using pomegranate peel as a new adsorbent. Desalination 223:162–173CrossRef

Freundlich HMF (1906) Over the adsorption in solution. J Phys Chem 57:385–471

Giraldo-Gutierrez L, Moreno-Pirajan JC (2008) Pb(II) and Cr(VI) adsorption from aqueous solution on activated carbons obtained from sugar cane husk and sawdust. J Anal Appl Pyrolysis 81:278–284CrossRef

Hall KR, Eagleton LC, Acrivos A, Vermeulen T (1966) Pore- and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions. Ind Eng Chem Fundam 5:212–223CrossRef

Haroun AA, El-Halawany NR (2011) Preparation and evaluation of novel interpenetrating polymer network-based on newspaper pulp for removal of copper ions. Polym-Plast Technol 50:232–238CrossRef

Haroun AA, Mashaly HM, El-Sayed NH (2013) Novel nanocomposites based on gelatin/HPET/chitosan with high performance acid red 150 dye adsorption. Clean Technol Environ Policy 15:367–374CrossRef

Hasar H (2003) Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from almond husk. J Hazard Mater B97:49–57CrossRef

Hebeish A, Ramadan MA, Abdel-Halim E, Abo-Okeil A (2011) An effective adsorbent based on sawdust for removal of direct dye from aqueous solutions. Clean Technol Environ Policy 13:713–718CrossRef

Ho YS, McKay G (1998) Kinetic models for the sorption of dye from aqueous solution by wood. Process Saf Environ Prot 76:183–191CrossRef

Huang L, Sun Y, Yang T, Li L (2011) Adsorption behavior of Ni (II) on lotus stalks derived active carbon by phosphoric acid activation. Desalination 268:12–19CrossRef

Imamoglu M, Tekir O (2008) Removal of copper (II) and lead (II) ions from aqueous solutions by adsorption on activated carbon from a new precursor hazelnut husks. Desalination 228:108–113CrossRef

Ioannidou O, Zabaniotou A (2007) Agricultural residues as precursors for activated carbon production—A review. Renew Sust Energ Rev 11:1966–2005CrossRef

Ismadji S, Sudaryanto Y, Hartono SB, Setiawan LEK, Ayucitra A (2005) Activated carbon from char obtained from vacuum pyrolysis of teak sawdust: pore structure development and characterization. Biores Technol 96:1364–1369CrossRef

Issabayeva G, Aroua MK, Sulaiman NMN (2006) Removal of lead from aqueous solutions on palm shell activated carbon. Biores Technol 97:2350–2355CrossRef

Kadirvelu K, Thamaraiselvi K, Namasivayam C (2001) Adsorption of nickel (II) from aqueous solution onto activated carbon prepared from coirpith. Sep Purif Technol 24:497–505CrossRef

Kadirvelu K, Senthilkumar P, Thamaraiselvi K, Subburam V (2002) Activated carbon prepared from biomass as adsorbent: elimination of Ni(II) from aqueous solution. Bioresour Technol 81:87–90CrossRef

Karagoz S, Tay T, Ucar S, Erdem M (2008) Activated carbons from waste biomass by sulfuric acid activation and their use on methylene blue adsorption. Biores Technol 99:6214–6222CrossRef

Kardam A, Raj KR, Srivastava S, Srivastava MM (2014) Nanocellulose fibers for biosorption of cadmium, nickel, and lead ions from aqueous solution. Clean Technol Environ Policy 16:385–393CrossRef

Kılıç M, Kırbıyık Ç, Çepelioğullar Ö, Pütün AE (2013) Adsorption of heavy metal ions from aqueous solutions by bio-char, a by-product of pyrolysis. Appl Surf Sci 283:856–862CrossRef

Lagergren S (1898) Zur theorie der sogenannten adsorption geloster stoffe. Kungliga Svenska Vetenskapsakademiens Handlingar 24(4):1–39

Langmuir I (1918) The adsorption of gases on plane surfaces of glass, mica and platinum. J Am Chem Soc 40:1361–1403CrossRef

Li K, Wang X (2009) Adsorptive removal of Pb(II) by activated carbon prepared from Spartina alterniflora: equilibrium, kinetics and thermodynamics. Biores Technol 100:2810–2815CrossRef

Li S, Xu S, Liu S, Yang C, Lu Q (2004) Fast pyrolysis of biomass in free-fall reactor for hydrogen-rich gas. Fuel Process Technol 85:1201–1211CrossRef

Liu H, Dai P, Zhang J, Zhang C, Bao N, Cheng C, Ren L (2013) Preparation and evaluation of activated carbons from lotus stalk with trimethyl phosphate and tributyl phosphate activation for lead removal. Chem Eng J 228:425–434CrossRef

Marsh H, Rodríguez-Reinoso F (2006) Activation Processes (Chemical) Activated Carbon. Elsevier Ltd, Oxford, pp 322–365CrossRef

McKee DW (1983) Mechanisms of the alkali metal catalyzed gasification of carbon. Fuel 62:170–175CrossRef

Menéndez JA, Illán-Gómez MJ, y León CAL, Radovic LR (1995) On the difference between the isoelectric point and the point of zero charge of carbons. Carbon 33:1655–1659CrossRef

Merrikhpour H, Jalali M (2013) Comparative and competitive adsorption of cadmium, copper, nickel, and lead ions by Iranian natural zeolite. Clean Technol Environ Policy 15:303–316CrossRef

Nethaji S, Sivasamy A (2014) Removal of hexavalent chromium from aqueous solution using activated carbon prepared from walnut shell biomass through alkali impregnation processes. Clean Technol Environ Policy 16:361–368CrossRef

Okman I, Karagöz S, Tay T, Erdem M (2014) Activated carbons from grape seeds by chemical activation with potassium carbonate and potassium hydroxide. Appl Surf Sci 293:138–142CrossRef

Patterson JW (1985) Industrial Wastewater Treatment Technology, 2nd edn. Butterworth Publishers, London

Qiu Y, Cheng H, Xu C, Sheng GD (2008) Surface characteristics of crop-residue-derived black carbon and lead (II) adsorption. Water Res 42:567–574CrossRef

Sentorun-Shalaby C, Ucak-Astarlioglu MG, Artok L, Sarici C (2006) Preparation and characterization of activated carbons by one-step steam pyrolysis/activation from apricot stones. Microporous Mesoporous Mat 88:126–134CrossRef

Singh CK, Sahu JN, Mahalik KK, Mohanty CR, Mohan BR, Meikap BC (2008) Studies on the removal of Pb(II) from wastewater by activated carbon developed from Tamarind wood activated with sulphuric acid. J Hazard Mater 153:221–228CrossRef

Song X, Liu H, Cheng L, Qu Y (2010) Surface modification of coconut-based activated carbon by liquid-phase oxidation and its effects on lead ion adsorption. Desalination 255:78–83CrossRef

Sudaryanto Y, Hartono SB, Irawaty W, Hindarso H, Ismadji S (2006) High surface area activated carbon prepared from cassava peel by chemical activation. Biores Technol 97:734–739CrossRef

Tay T, Ucar S, Karagöz S (2009) Preparation and characterization of activated carbon from waste biomass. J Hazard Mater 165:481–485CrossRef

Visa M, Pricop F, Duta A (2011) Sustainable treatment of wastewaters resulted in the textile dyeing industry. Clean Technol Environ Policy 13:855–861CrossRef

Weber WJ, Morris JC (1963) Kinetics of adsorption on carbon from solution. J Sanit Eng Div 89:31–60

Yalçın N, Sevinç V (2000) Studies of the surface area and porosity of activated carbons prepared from rice husks. Carbon 38:1943–1945CrossRef

Zhang J, Jin L, Zhu S, Hu H (2012) Preparation of mesoporous activated carbons from coal liquefaction residue for methane decomposition. J Nat Gas Chem 21:759–766CrossRef

Titel: Removal of lead (II) and nickel (II) ions from aqueous solution using activated carbon prepared from rapeseed oil cake by Na2CO3 activation
verfasst von: Suat Uçar
Murat Erdem
Turgay Tay
Selhan Karagöz
Publikationsdatum: 01.03.2015
Verlag: Springer Berlin Heidelberg
Erschienen in: Clean Technologies and Environmental Policy / Ausgabe 3/2015
Print ISSN: 1618-954X
Elektronische ISSN: 1618-9558
DOI: https://doi.org/10.1007/s10098-014-0830-8

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