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Erschienen in: Cellulose 5/2014

01.10.2014 | Original Paper

Nanocrystalline cellulose acetate (NCCA)/graphene oxide (GO) nanocomposites with enhanced mechanical properties and barrier against water vapor

verfasst von: Roya Kabiri, Hassan Namazi

Erschienen in: Cellulose | Ausgabe 5/2014

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Abstract

Highly flexible nanocomposite films of nanocrystalline cellulose acetate (NCCA) and graphene oxide (GO) were synthesized by combining NCCA and GO sheets in a well-controlled manner. By adjusting the GO content, various NCCA/GO nanocomposites with 0.3–1 wt% GO were obtained. Films of these nanocomposites were prepared using the solvent casting method. Microscopic and X-ray diffraction (XRD) measurements demonstrated that the GO nanosheets were uniformly dispersed in the NCCA matrix. Mechanical properties of the composite films were also studied. The best GO composition of the samples tested was 0.8 wt%, giving tensile strength of 157.49 MPa, which represents a 61.92 % enhancement compared with NCCA. On the other hand, the composite films showed improved barrier properties against water vapor. This simple process for preparation of NCCA/GO films is attractive for potential development of high-performance films for electrical and electrochemical applications.

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Literatur
Zurück zum Zitat Abdul Khalil H, Bhat A, Ireana Yusra A (2012) Green composites from sustainable cellulose nanofibrils: a review. Carbohydr Polym 87(2):963–979CrossRef Abdul Khalil H, Bhat A, Ireana Yusra A (2012) Green composites from sustainable cellulose nanofibrils: a review. Carbohydr Polym 87(2):963–979CrossRef
Zurück zum Zitat Adsul MG, Rey DA, Gokhale DV (2011) Combined strategy for the dispersion/dissolution of single walled carbon nanotubes and cellulose in water. J Mater Chem 21(7):2054–2056CrossRef Adsul MG, Rey DA, Gokhale DV (2011) Combined strategy for the dispersion/dissolution of single walled carbon nanotubes and cellulose in water. J Mater Chem 21(7):2054–2056CrossRef
Zurück zum Zitat Ahmad A, Jawad Z, Low S, Zein S (2014) A cellulose acetate/multi-walled carbon nanotube mixed matrix membrane for CO2/N2 separation. J Membr Sci 451:55–66CrossRef Ahmad A, Jawad Z, Low S, Zein S (2014) A cellulose acetate/multi-walled carbon nanotube mixed matrix membrane for CO2/N2 separation. J Membr Sci 451:55–66CrossRef
Zurück zum Zitat Bai W, Holbery J, Li K (2009) A technique for production of nanocrystalline cellulose with a narrow size distribution. Cellulose 16(3):455–465CrossRef Bai W, Holbery J, Li K (2009) A technique for production of nanocrystalline cellulose with a narrow size distribution. Cellulose 16(3):455–465CrossRef
Zurück zum Zitat Barkhordari S, Yadollahi M, Namazi H (2014) pH sensitive nanocomposite hydrogel beads based on carboxymethyl cellulose/layered double hydroxide as drug delivery systems. J Polym Res 21(6):1–9CrossRef Barkhordari S, Yadollahi M, Namazi H (2014) pH sensitive nanocomposite hydrogel beads based on carboxymethyl cellulose/layered double hydroxide as drug delivery systems. J Polym Res 21(6):1–9CrossRef
Zurück zum Zitat Chang C-H, Huang T-C, Peng C-W, Yeh T-C, Lu H-I, Hung W-I, Weng C-J, Yang T-I, Yeh J-M (2012) Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon 50(14):5044–5051CrossRef Chang C-H, Huang T-C, Peng C-W, Yeh T-C, Lu H-I, Hung W-I, Weng C-J, Yang T-I, Yeh J-M (2012) Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon 50(14):5044–5051CrossRef
Zurück zum Zitat Choudalakis G, Gotsis A (2009) Permeability of polymer/clay nanocomposites: a review. Eur Polym J 45(4):967–984CrossRef Choudalakis G, Gotsis A (2009) Permeability of polymer/clay nanocomposites: a review. Eur Polym J 45(4):967–984CrossRef
Zurück zum Zitat Corrêa AC, de Morais Teixeira E, Pessan LA, Mattoso LHC (2010) Cellulose nanofibers from curaua fibers. Cellulose 17(6):1183–1192CrossRef Corrêa AC, de Morais Teixeira E, Pessan LA, Mattoso LHC (2010) Cellulose nanofibers from curaua fibers. Cellulose 17(6):1183–1192CrossRef
Zurück zum Zitat Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39(1):228–240CrossRef Dreyer DR, Park S, Bielawski CW, Ruoff RS (2010) The chemistry of graphene oxide. Chem Soc Rev 39(1):228–240CrossRef
Zurück zum Zitat El-Fiqi A, Kim H-W (2014) Mesoporous bioactive nanocarriers in electrospun biopolymer fibrous scaffolds designed for sequential drug delivery. RSC Adv 4(9):4444–4452CrossRef El-Fiqi A, Kim H-W (2014) Mesoporous bioactive nanocarriers in electrospun biopolymer fibrous scaffolds designed for sequential drug delivery. RSC Adv 4(9):4444–4452CrossRef
Zurück zum Zitat Feng Y, Zhang X, Shen Y, Yoshino K, Feng W (2012) A mechanically strong, flexible and conductive film based on bacterial cellulose/graphene nanocomposite. Carbohydr Polym 87(1):644–649CrossRef Feng Y, Zhang X, Shen Y, Yoshino K, Feng W (2012) A mechanically strong, flexible and conductive film based on bacterial cellulose/graphene nanocomposite. Carbohydr Polym 87(1):644–649CrossRef
Zurück zum Zitat Gao K, Shao Z, Li J, Wang X, Peng X, Wang W, Wang F (2013) Cellulose nanofiber–graphene all solid-state flexible supercapacitors. J Mater Chem A 1(1):63–67CrossRef Gao K, Shao Z, Li J, Wang X, Peng X, Wang W, Wang F (2013) Cellulose nanofiber–graphene all solid-state flexible supercapacitors. J Mater Chem A 1(1):63–67CrossRef
Zurück zum Zitat Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500CrossRef Habibi Y, Lucia LA, Rojas OJ (2010) Cellulose nanocrystals: chemistry, self-assembly, and applications. Chem Rev 110(6):3479–3500CrossRef
Zurück zum Zitat Hummers Jr WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339 Hummers Jr WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80(6):1339–1339
Zurück zum Zitat Jansen JC, Cassano R, Trombino S, Cilea A, Picci N, Drioli E, Giorno L (2011) Polymeric membranes with antioxidant activity based on cellulose esters and poly (vinylidene fluoride)/cellulose ester blends. Cellulose 18(2):359–370CrossRef Jansen JC, Cassano R, Trombino S, Cilea A, Picci N, Drioli E, Giorno L (2011) Polymeric membranes with antioxidant activity based on cellulose esters and poly (vinylidene fluoride)/cellulose ester blends. Cellulose 18(2):359–370CrossRef
Zurück zum Zitat Kabiri R, Namazi H (2014) Surface grafting of reduced graphene oxide using nanocrystalline cellulose via click reaction. J Nanopart Res 16(7):2474–2487CrossRef Kabiri R, Namazi H (2014) Surface grafting of reduced graphene oxide using nanocrystalline cellulose via click reaction. J Nanopart Res 16(7):2474–2487CrossRef
Zurück zum Zitat Kim C-J, Khan W, Kim D-H, Cho K-S, Park S-Y (2011) Graphene oxide/cellulose composite using NMMO monohydrate. Carbohydr Polym 86(2):903–909CrossRef Kim C-J, Khan W, Kim D-H, Cho K-S, Park S-Y (2011) Graphene oxide/cellulose composite using NMMO monohydrate. Carbohydr Polym 86(2):903–909CrossRef
Zurück zum Zitat Kwon S, Singh RK, Kim T-H, Patel KD, Kim J–J, Chrzanowski W, Kim H-W (2014) Luminescent mesoporous nanoreservoirs for the effective loading and intracellular delivery of therapeutic drugs. Acta Biomater 10(3):1431–1442CrossRef Kwon S, Singh RK, Kim T-H, Patel KD, Kim J–J, Chrzanowski W, Kim H-W (2014) Luminescent mesoporous nanoreservoirs for the effective loading and intracellular delivery of therapeutic drugs. Acta Biomater 10(3):1431–1442CrossRef
Zurück zum Zitat Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose—its barrier properties and applications in cellulosic materials: a review. Carbohydr Polym 90(2):735–764CrossRef Lavoine N, Desloges I, Dufresne A, Bras J (2012) Microfibrillated cellulose—its barrier properties and applications in cellulosic materials: a review. Carbohydr Polym 90(2):735–764CrossRef
Zurück zum Zitat Li D, Kaner RB (2006) Shape and aggregation control of nanoparticles: not shaken, not stirred. J Am Chem Soc 128(3):968–975CrossRef Li D, Kaner RB (2006) Shape and aggregation control of nanoparticles: not shaken, not stirred. J Am Chem Soc 128(3):968–975CrossRef
Zurück zum Zitat Li W, Yue J, Liu S (2012) Preparation of nanocrystalline cellulose via ultrasound and its reinforcement capability for poly (vinyl alcohol) composites. Ultrason Sonochem 19(3):479–485CrossRef Li W, Yue J, Liu S (2012) Preparation of nanocrystalline cellulose via ultrasound and its reinforcement capability for poly (vinyl alcohol) composites. Ultrason Sonochem 19(3):479–485CrossRef
Zurück zum Zitat Li Z, Zhang D, Weng J, Chen B, Liu H (2014) Synthesis and characterization of photochromic azobenzene cellulose ethers. Carbohydr Polym 99:748–754CrossRef Li Z, Zhang D, Weng J, Chen B, Liu H (2014) Synthesis and characterization of photochromic azobenzene cellulose ethers. Carbohydr Polym 99:748–754CrossRef
Zurück zum Zitat Luong ND, Pahimanolis N, Hippi U, Korhonen JT, Ruokolainen J, Johansson L-S, Nam J-D, Seppälä J (2011) Graphene/cellulose nanocomposite paper with high electrical and mechanical performances. J Mater Chem 21(36):13991–13998CrossRef Luong ND, Pahimanolis N, Hippi U, Korhonen JT, Ruokolainen J, Johansson L-S, Nam J-D, Seppälä J (2011) Graphene/cellulose nanocomposite paper with high electrical and mechanical performances. J Mater Chem 21(36):13991–13998CrossRef
Zurück zum Zitat Ma T, Chang PR, Zheng P, Ma X (2013) The composites based on plasticized starch and graphene oxide/reduced graphene oxide. Carbohydr Polym 94(1):63–70CrossRef Ma T, Chang PR, Zheng P, Ma X (2013) The composites based on plasticized starch and graphene oxide/reduced graphene oxide. Carbohydr Polym 94(1):63–70CrossRef
Zurück zum Zitat Malho J-M, Laaksonen Pi, Walther A, Ikkala O, Linder MB (2012) Facile method for stiff, tough, and strong nanocomposites by direct exfoliation of multilayered graphene into native nanocellulose matrix. Biomacromolecules 13(4):1093–1099CrossRef Malho J-M, Laaksonen Pi, Walther A, Ikkala O, Linder MB (2012) Facile method for stiff, tough, and strong nanocomposites by direct exfoliation of multilayered graphene into native nanocellulose matrix. Biomacromolecules 13(4):1093–1099CrossRef
Zurück zum Zitat Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM (2010) Improved synthesis of graphene oxide. ACS Nano 4(8):4806–4814CrossRef Marcano DC, Kosynkin DV, Berlin JM, Sinitskii A, Sun Z, Slesarev A, Alemany LB, Lu W, Tour JM (2010) Improved synthesis of graphene oxide. ACS Nano 4(8):4806–4814CrossRef
Zurück zum Zitat Moon IK, Lee J, Ruoff RS, Lee H (2010) Reduced graphene oxide by chemical graphitization. Nat Commun 1:73CrossRef Moon IK, Lee J, Ruoff RS, Lee H (2010) Reduced graphene oxide by chemical graphitization. Nat Commun 1:73CrossRef
Zurück zum Zitat Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40(7):3941–3994CrossRef Moon RJ, Martini A, Nairn J, Simonsen J, Youngblood J (2011) Cellulose nanomaterials review: structure, properties and nanocomposites. Chem Soc Rev 40(7):3941–3994CrossRef
Zurück zum Zitat Namazi H, Jafari Rad S (2004) Synthesis of block and grafted copolymers containing spacer-linked chromophore based on cellulose and polyethylene glycol. J Appl Polym Sci 94(3):1175–1185CrossRef Namazi H, Jafari Rad S (2004) Synthesis of block and grafted copolymers containing spacer-linked chromophore based on cellulose and polyethylene glycol. J Appl Polym Sci 94(3):1175–1185CrossRef
Zurück zum Zitat Namazi H, Jafarirad S (2008) Preparation of the new derivatives of cellulose and oligomeric species of cellulose containing magneson II chromophore. J Appl Polym Sci 110(6):4034–4039CrossRef Namazi H, Jafarirad S (2008) Preparation of the new derivatives of cellulose and oligomeric species of cellulose containing magneson II chromophore. J Appl Polym Sci 110(6):4034–4039CrossRef
Zurück zum Zitat Namazi H, Fathi F, Heydari A (2012) Nanoparticles based on modified polysaccharides. Deliv Nanopart 8:149–184 (Ed by Hashim A inTech) Namazi H, Fathi F, Heydari A (2012) Nanoparticles based on modified polysaccharides. Deliv Nanopart 8:149–184 (Ed by Hashim A inTech)
Zurück zum Zitat Namazi H, Mosadegh M, Hayasi M (2014) New developments in polycaprolactone-layered silicate nano-biocomposites: fabrication and properties. In: Jitendra KP, Kummetha RR, Amar Kumar M, Manjusri M (Ed) Handbook of polymer nanocomposites. Processing, performance and application. Springer, Heidelberg, pp 21–52 Namazi H, Mosadegh M, Hayasi M (2014) New developments in polycaprolactone-layered silicate nano-biocomposites: fabrication and properties. In: Jitendra KP, Kummetha RR, Amar Kumar M, Manjusri M (Ed) Handbook of polymer nanocomposites. Processing, performance and application. Springer, Heidelberg, pp 21–52
Zurück zum Zitat Nishiyama Y, Langan P, Wada M, Forsyth VT (2010) Looking at hydrogen bonds in cellulose. Acta Crystallogr D Biol Crystallogr 66(11):1172–1177CrossRef Nishiyama Y, Langan P, Wada M, Forsyth VT (2010) Looking at hydrogen bonds in cellulose. Acta Crystallogr D Biol Crystallogr 66(11):1172–1177CrossRef
Zurück zum Zitat Novoselov KS, Geim AK, Morozov S, Jiang D, Zhang Y, Dubonos S, Grigorieva I, Firsov A (2004) Electric field effect in atomically thin carbon films. Science 306(5696):666–669CrossRef Novoselov KS, Geim AK, Morozov S, Jiang D, Zhang Y, Dubonos S, Grigorieva I, Firsov A (2004) Electric field effect in atomically thin carbon films. Science 306(5696):666–669CrossRef
Zurück zum Zitat Peng B, Han X, Liu H, Berry RC, Tam KC (2013) Interactions between surfactants and polymer-grafted nanocrystalline cellulose. Colloids Surf A 421:142–149CrossRef Peng B, Han X, Liu H, Berry RC, Tam KC (2013) Interactions between surfactants and polymer-grafted nanocrystalline cellulose. Colloids Surf A 421:142–149CrossRef
Zurück zum Zitat Pirani S, Hashaikeh R (2013) Nanocrystalline cellulose extraction process and utilization of the byproduct for biofuels production. Carbohydr Polym 93(1):357–363CrossRef Pirani S, Hashaikeh R (2013) Nanocrystalline cellulose extraction process and utilization of the byproduct for biofuels production. Carbohydr Polym 93(1):357–363CrossRef
Zurück zum Zitat Qi H, Mäder E, Liu J (2013) Electrically conductive aerogels composed of cellulose and carbon nanotubes. J Mater Chem A 1(34):9714–9720CrossRef Qi H, Mäder E, Liu J (2013) Electrically conductive aerogels composed of cellulose and carbon nanotubes. J Mater Chem A 1(34):9714–9720CrossRef
Zurück zum Zitat Siqueira G, Tapin-Lingua S, Bras J, da Silva Perez D, Dufresne A (2011) Mechanical properties of natural rubber nanocomposites reinforced with cellulosic nanoparticles obtained from combined mechanical shearing, and enzymatic and acid hydrolysis of sisal fibers. Cellulose 18(1):57–65CrossRef Siqueira G, Tapin-Lingua S, Bras J, da Silva Perez D, Dufresne A (2011) Mechanical properties of natural rubber nanocomposites reinforced with cellulosic nanoparticles obtained from combined mechanical shearing, and enzymatic and acid hydrolysis of sisal fibers. Cellulose 18(1):57–65CrossRef
Zurück zum Zitat Thakur S, Karak N (2013) Bio-based tough hyperbranched polyurethane–graphene oxide nanocomposites as advanced shape memory materials. RSC Adv 3(24):9476–9482CrossRef Thakur S, Karak N (2013) Bio-based tough hyperbranched polyurethane–graphene oxide nanocomposites as advanced shape memory materials. RSC Adv 3(24):9476–9482CrossRef
Zurück zum Zitat Tunc S, Angellier H, Cahyana Y, Chalier P, Gontard N, Gastaldi E (2007) Functional properties of wheat gluten/montmorillonite nanocomposite films processed by casting. J Membr Sci 289(1):159–168CrossRef Tunc S, Angellier H, Cahyana Y, Chalier P, Gontard N, Gastaldi E (2007) Functional properties of wheat gluten/montmorillonite nanocomposite films processed by casting. J Membr Sci 289(1):159–168CrossRef
Zurück zum Zitat Wang B, Lou W, Wang X, Hao J (2012) Relationship between dispersion state and reinforcement effect of graphene oxide in microcrystalline cellulose–graphene oxide composite films. J Mater Chem 22(25):12859–12866CrossRef Wang B, Lou W, Wang X, Hao J (2012) Relationship between dispersion state and reinforcement effect of graphene oxide in microcrystalline cellulose–graphene oxide composite films. J Mater Chem 22(25):12859–12866CrossRef
Zurück zum Zitat Wilbon PA, Chu F, Tang C (2013) Progress in renewable polymers from natural terpenes, terpenoids, and rosin. Macromol Rapid Commun 34(1):8–37CrossRef Wilbon PA, Chu F, Tang C (2013) Progress in renewable polymers from natural terpenes, terpenoids, and rosin. Macromol Rapid Commun 34(1):8–37CrossRef
Zurück zum Zitat Williams CK, Hillmyer MA (2008) Polymers from renewable resources: a perspective for a special issue of Polymer Reviews. Polym Rev 48(1):1–10CrossRef Williams CK, Hillmyer MA (2008) Polymers from renewable resources: a perspective for a special issue of Polymer Reviews. Polym Rev 48(1):1–10CrossRef
Zurück zum Zitat Xu S, Girouard N, Schueneman G, Shofner ML, Meredith JC (2013) Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals. Polymer 54(24):6589–6598CrossRef Xu S, Girouard N, Schueneman G, Shofner ML, Meredith JC (2013) Mechanical and thermal properties of waterborne epoxy composites containing cellulose nanocrystals. Polymer 54(24):6589–6598CrossRef
Zurück zum Zitat Yadollahi M, Namazi H (2013) Synthesis and characterization of carboxymethyl cellulose/layered double hydroxide nanocomposites. J Nanopart Res 15(4):1–9CrossRef Yadollahi M, Namazi H (2013) Synthesis and characterization of carboxymethyl cellulose/layered double hydroxide nanocomposites. J Nanopart Res 15(4):1–9CrossRef
Zurück zum Zitat Yadollahi M, Namazi H, Barkhordari S (2014) Preparation and properties of carboxymethyl cellulose/layered double hydroxide bionanocomposite films. Carbohydr Polym 108:83–90CrossRef Yadollahi M, Namazi H, Barkhordari S (2014) Preparation and properties of carboxymethyl cellulose/layered double hydroxide bionanocomposite films. Carbohydr Polym 108:83–90CrossRef
Zurück zum Zitat Yan L, Ishihara K (2008) Graft copolymerization of 2-methacryloyloxyethyl phosphorylcholine to cellulose in homogeneous media using atom transfer radical polymerization for providing new hemocompatible coating materials. J Polym Sci Part A Polym Chem 46(10):3306–3313CrossRef Yan L, Ishihara K (2008) Graft copolymerization of 2-methacryloyloxyethyl phosphorylcholine to cellulose in homogeneous media using atom transfer radical polymerization for providing new hemocompatible coating materials. J Polym Sci Part A Polym Chem 46(10):3306–3313CrossRef
Zurück zum Zitat Yan C, Zhang J, Lv Y, Yu J, Wu J, Zhang J, He J (2009) Thermoplastic cellulose-graft-poly (L-lactide) copolymers homogeneously synthesized in an ionic liquid with 4-dimethylaminopyridine catalyst. Biomacromolecules 10(8):2013–2018CrossRef Yan C, Zhang J, Lv Y, Yu J, Wu J, Zhang J, He J (2009) Thermoplastic cellulose-graft-poly (L-lactide) copolymers homogeneously synthesized in an ionic liquid with 4-dimethylaminopyridine catalyst. Biomacromolecules 10(8):2013–2018CrossRef
Zurück zum Zitat Yousefi N, Gudarzi MM, Zheng Q, Lin X, Shen X, Jia J, Sharif F, Kim J-K (2013) Highly aligned, ultralarge-size reduced graphene oxide/polyurethane nanocomposites: mechanical properties and moisture permeability. Compos A Appl Sci Manuf 49:42–50CrossRef Yousefi N, Gudarzi MM, Zheng Q, Lin X, Shen X, Jia J, Sharif F, Kim J-K (2013) Highly aligned, ultralarge-size reduced graphene oxide/polyurethane nanocomposites: mechanical properties and moisture permeability. Compos A Appl Sci Manuf 49:42–50CrossRef
Zurück zum Zitat Yu L, Petinakis S, Dean K, Bilyk A, Wu D (2007) Green polymeric blends and composites from renewable resources. Macromol Symp 249–250:535–539 (Wiley Online Library) Yu L, Petinakis S, Dean K, Bilyk A, Wu D (2007) Green polymeric blends and composites from renewable resources. Macromol Symp 249–250:535–539 (Wiley Online Library)
Zurück zum Zitat Zhan Y, Lavorgna M, Buonocore G, Xia H (2012) Enhancing electrical conductivity of rubber composites by constructing interconnected network of self-assembled graphene with latex mixing. J Mater Chem 22(21):10464–10468CrossRef Zhan Y, Lavorgna M, Buonocore G, Xia H (2012) Enhancing electrical conductivity of rubber composites by constructing interconnected network of self-assembled graphene with latex mixing. J Mater Chem 22(21):10464–10468CrossRef
Metadaten
Titel
Nanocrystalline cellulose acetate (NCCA)/graphene oxide (GO) nanocomposites with enhanced mechanical properties and barrier against water vapor
verfasst von
Roya Kabiri
Hassan Namazi
Publikationsdatum
01.10.2014
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 5/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-014-0366-4

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