Skip to main content
Erschienen in: Cellulose 5/2015

01.10.2015 | Original Paper

Properties of hydroxypropyl guar/TEMPO-oxidized cellulose nanofibrils composite films

verfasst von: Lei Dai, Bin Wang, Zhu Long, Le Chen, Dan Zhang, Shuai Guo

Erschienen in: Cellulose | Ausgabe 5/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Flexible hydroxypropyl guar/TEMPO-oxidized cellulose nanofibrils (HPG/TOCNs) composite films were prepared using a conventional solvent-casting technique. Their properties were investigated with a variety of techniques including tensile test, Fourier-transform infrared spectroscopy, scanning electron microscopy, oxygen permeability test, water vapor permeability test, thermogravimetric analysis and water contact angle measurement. The results indicate that HPG and TOCNs have an excellent miscibility and their blending mass ratio can significantly affect the physical, thermal, oxygen barrier and water vapor barrier properties of the composite films. Compared with pure HPG film, the composite films exhibit higher tensile strength and oxygen barrier properties. The water vapor resistance and thermal stability of the composite films are slightly lower than those of HPG film. However, the excellent flexibility, transparency and gas-barrier properties of the environmentally friendly HPG/TOCNs composite film make it a promising packaging material for food and pharmaceutical industries.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Aulin C, Strom G (2013) Multilayered alkyd resin/nanocellulose coatings for use in renewable packaging solutions with a high level of moisture resistance. Ind Eng Chem Res 52(7):2582–2589CrossRef Aulin C, Strom G (2013) Multilayered alkyd resin/nanocellulose coatings for use in renewable packaging solutions with a high level of moisture resistance. Ind Eng Chem Res 52(7):2582–2589CrossRef
Zurück zum Zitat Cheng Y, Brown KM, Prud’homme RK (2002) Characterization and intermolecular interactions of hydroxypropyl guar solutions. Biomacromolecules 3(3):456–461CrossRef Cheng Y, Brown KM, Prud’homme RK (2002) Characterization and intermolecular interactions of hydroxypropyl guar solutions. Biomacromolecules 3(3):456–461CrossRef
Zurück zum Zitat Dai L, Long Z, Lv Y, Feng Q-C (2014) The role of formic acid pretreatment in improving the carboxyl content of TEMPO-oxidized cellulose. Cellul. Chem Technol 5–6(48):469–475 Dai L, Long Z, Lv Y, Feng Q-C (2014) The role of formic acid pretreatment in improving the carboxyl content of TEMPO-oxidized cellulose. Cellul. Chem Technol 5–6(48):469–475
Zurück zum Zitat Das D, Ara T, Dutta S, Mukherjee A (2011) New water resistant biomaterial biocide film based on guar gum. Bioresour Technol 102(10):5878–5883CrossRef Das D, Ara T, Dutta S, Mukherjee A (2011) New water resistant biomaterial biocide film based on guar gum. Bioresour Technol 102(10):5878–5883CrossRef
Zurück zum Zitat Dong J, Ozaki Y (1997) FTIR and FT-Raman studies of partially miscible poly(methyl methacrylate)/poly(4-vinylphenol) blends in solid states. Macromolecules 30(2):286–292CrossRef Dong J, Ozaki Y (1997) FTIR and FT-Raman studies of partially miscible poly(methyl methacrylate)/poly(4-vinylphenol) blends in solid states. Macromolecules 30(2):286–292CrossRef
Zurück zum Zitat Fujisawa S, Okita Y, Fukuzumi H, Saito T, Isogai A (2011) Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups. Carbohydr Polym 84(1):579–583CrossRef Fujisawa S, Okita Y, Fukuzumi H, Saito T, Isogai A (2011) Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups. Carbohydr Polym 84(1):579–583CrossRef
Zurück zum Zitat Fukuya MN, Senoo K, Kotera M, Yoshimoto M, Sakata O (2014) Enhanced oxygen barrier property of poly(ethylene oxide) films crystallite-oriented by adding cellulose single nanofibers. Polymer 55(22):5843–5846CrossRef Fukuya MN, Senoo K, Kotera M, Yoshimoto M, Sakata O (2014) Enhanced oxygen barrier property of poly(ethylene oxide) films crystallite-oriented by adding cellulose single nanofibers. Polymer 55(22):5843–5846CrossRef
Zurück zum Zitat Fukuzumi H, Saito T, Iwata T, Kumamoto Y, Isogai A (2009) Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. Biomacromolecules 10(1):162–165CrossRef Fukuzumi H, Saito T, Iwata T, Kumamoto Y, Isogai A (2009) Transparent and high gas barrier films of cellulose nanofibers prepared by TEMPO-mediated oxidation. Biomacromolecules 10(1):162–165CrossRef
Zurück zum Zitat Fukuzumi H, Fujisawa S, Saito T, Isogai A (2013a) Selective permeation of hydrogen gas using cellulose nanofibril film. Biomacromolecules 14(5):1705–1709CrossRef Fukuzumi H, Fujisawa S, Saito T, Isogai A (2013a) Selective permeation of hydrogen gas using cellulose nanofibril film. Biomacromolecules 14(5):1705–1709CrossRef
Zurück zum Zitat Fukuzumi H, Saito T, Isogai A (2013b) Influence of TEMPO-oxidized cellulose nanofibril length on film properties. Carbohydr Polym 93(1):172–177CrossRef Fukuzumi H, Saito T, Isogai A (2013b) Influence of TEMPO-oxidized cellulose nanofibril length on film properties. Carbohydr Polym 93(1):172–177CrossRef
Zurück zum Zitat Homma I, Fukuzumi H, Saito T, Isogai A (2013) Effects of carboxyl-group counter-ions on biodegradation behaviors of TEMPO-oxidized cellulose fibers and nanofibril films. Cellulose 20(5):2505–2515CrossRef Homma I, Fukuzumi H, Saito T, Isogai A (2013) Effects of carboxyl-group counter-ions on biodegradation behaviors of TEMPO-oxidized cellulose fibers and nanofibril films. Cellulose 20(5):2505–2515CrossRef
Zurück zum Zitat Iwatake A, Nogi M, Yano H (2008) Cellulose nanofiber-reinforced polylactic acid. Compos Sci Technol 68(9):2103–2106CrossRef Iwatake A, Nogi M, Yano H (2008) Cellulose nanofiber-reinforced polylactic acid. Compos Sci Technol 68(9):2103–2106CrossRef
Zurück zum Zitat Jradi K, Bideau B, Chabot B, Daneault C (2012) Characterization of conductive composite films based on TEMPO-oxidized cellulose nanofibers and polypyrrole. J Mater Sci 47(8):3752–3762CrossRef Jradi K, Bideau B, Chabot B, Daneault C (2012) Characterization of conductive composite films based on TEMPO-oxidized cellulose nanofibers and polypyrrole. J Mater Sci 47(8):3752–3762CrossRef
Zurück zum Zitat Kato Y, Kaminaga J, Matsuo R, Isogai A (2005) Oxygen permeability and biodegradability of polyuronic acids prepared from polysaccharides by TEMPO-mediated oxidation. J Polym Environ 13(3):261–266CrossRef Kato Y, Kaminaga J, Matsuo R, Isogai A (2005) Oxygen permeability and biodegradability of polyuronic acids prepared from polysaccharides by TEMPO-mediated oxidation. J Polym Environ 13(3):261–266CrossRef
Zurück zum Zitat Keating BA, Hill CAS, Sun DY, English R, Davies P, McCue C (2013) The water vapor sorption behavior of a galactomannan cellulose nanocomposite film analyzed using parallel exponential kinetics and the Kelvin-Voigt viscoelastic model. J Appl Polym Sci 129(4):2352–2359CrossRef Keating BA, Hill CAS, Sun DY, English R, Davies P, McCue C (2013) The water vapor sorption behavior of a galactomannan cellulose nanocomposite film analyzed using parallel exponential kinetics and the Kelvin-Voigt viscoelastic model. J Appl Polym Sci 129(4):2352–2359CrossRef
Zurück zum Zitat Kong LL, Zhang DL, Shao ZQ, Han BX, Lv YX, Gao KZ, Peng XQ (2014) Superior effect of TEMPO-oxidized cellulose nanofibrils (TOCNs) on the performance of cellulose triacetate (CTA) ultrafiltration membrane. Desalination 332(1):117–125CrossRef Kong LL, Zhang DL, Shao ZQ, Han BX, Lv YX, Gao KZ, Peng XQ (2014) Superior effect of TEMPO-oxidized cellulose nanofibrils (TOCNs) on the performance of cellulose triacetate (CTA) ultrafiltration membrane. Desalination 332(1):117–125CrossRef
Zurück zum Zitat Kurihara T, Isogai A (2014) Properties of poly(acrylamide)/TEMPO-oxidized cellulose nanofibril composite films. Cellulose 21(1):291–299CrossRef Kurihara T, Isogai A (2014) Properties of poly(acrylamide)/TEMPO-oxidized cellulose nanofibril composite films. Cellulose 21(1):291–299CrossRef
Zurück zum Zitat Lu C, Kostanski L, Ketelson H, Meadows D, Pelton R (2005) Hydroxypropyl guar-borate interactions with tear film mucin and lysozyme. Langmuir 21(22):10032–10037CrossRef Lu C, Kostanski L, Ketelson H, Meadows D, Pelton R (2005) Hydroxypropyl guar-borate interactions with tear film mucin and lysozyme. Langmuir 21(22):10032–10037CrossRef
Zurück zum Zitat Mueller CMO, Laurindo JB, Yamashita F (2009) Effect of cellulose fibers addition on the mechanical properties and water vapor barrier of starch-based films. Food Hydrocoll 23(5):1328–1333CrossRef Mueller CMO, Laurindo JB, Yamashita F (2009) Effect of cellulose fibers addition on the mechanical properties and water vapor barrier of starch-based films. Food Hydrocoll 23(5):1328–1333CrossRef
Zurück zum Zitat Nayak BR, Singh RP (2001) Synthesis and characterization of grafted hydroxypropyl guar gum by ceric ion induced initiation. Eur Polym J 37(8):1655–1666CrossRef Nayak BR, Singh RP (2001) Synthesis and characterization of grafted hydroxypropyl guar gum by ceric ion induced initiation. Eur Polym J 37(8):1655–1666CrossRef
Zurück zum Zitat Poinot T, Govin A, Grosseau P (2014) Importance of coil-overlapping for the effectiveness of hydroxypropylguars as water retention agent in cement-based mortars. Cement Concr Res 56:61–68CrossRef Poinot T, Govin A, Grosseau P (2014) Importance of coil-overlapping for the effectiveness of hydroxypropylguars as water retention agent in cement-based mortars. Cement Concr Res 56:61–68CrossRef
Zurück zum Zitat Qi ZD, Saito T, Fan YM, Isogai A (2012) Multifunctional coating films by layer-by-layer deposition of cellulose and chitin nanofibrils. Biomacromolecules 13(2):553–558CrossRef Qi ZD, Saito T, Fan YM, Isogai A (2012) Multifunctional coating films by layer-by-layer deposition of cellulose and chitin nanofibrils. Biomacromolecules 13(2):553–558CrossRef
Zurück zum Zitat Qing Y, Sabo R, Wu YQ, Cai ZY (2012) High-performance cellulose nanofibril composite films. BioResources 7(3):3064–3075 Qing Y, Sabo R, Wu YQ, Cai ZY (2012) High-performance cellulose nanofibril composite films. BioResources 7(3):3064–3075
Zurück zum Zitat Rodionova G, Eriksen Ø, Gregersen Ø (2012a) TEMPO-oxidized cellulose nanofiber films: effect of surface morphology on water resistance. Cellulose 19(4):1115–1123CrossRef Rodionova G, Eriksen Ø, Gregersen Ø (2012a) TEMPO-oxidized cellulose nanofiber films: effect of surface morphology on water resistance. Cellulose 19(4):1115–1123CrossRef
Zurück zum Zitat Rodionova G, Roudot S, Eriksen Ø, Männle F, Gregersen Ø (2012b) The formation and characterization of sustainable layered films incorporating microfibrillated cellulose (MFC). Bioresources 7(3):3690–3700 Rodionova G, Roudot S, Eriksen Ø, Männle F, Gregersen Ø (2012b) The formation and characterization of sustainable layered films incorporating microfibrillated cellulose (MFC). Bioresources 7(3):3690–3700
Zurück zum Zitat Rodionova G, Saito T, Lenes M, Eriksen Ø, Gregersen Ø, Fukuzumi H, Isogai A (2012c) Mechanical and oxygen barrier properties of films prepared from fibrillated dispersions of TEMPO-oxidized norway spruce and eucalyptus pulps. Cellulose 19(3):705–711CrossRef Rodionova G, Saito T, Lenes M, Eriksen Ø, Gregersen Ø, Fukuzumi H, Isogai A (2012c) Mechanical and oxygen barrier properties of films prepared from fibrillated dispersions of TEMPO-oxidized norway spruce and eucalyptus pulps. Cellulose 19(3):705–711CrossRef
Zurück zum Zitat Rosiaux Y, Muschert S, Chokshi R, Leclercq B, Siepmann F, Siepmann J (2013) Ethanol-resistant polymeric film coatings for controlled drug delivery. J Control Release 169(1–2):1–9CrossRef Rosiaux Y, Muschert S, Chokshi R, Leclercq B, Siepmann F, Siepmann J (2013) Ethanol-resistant polymeric film coatings for controlled drug delivery. J Control Release 169(1–2):1–9CrossRef
Zurück zum Zitat Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7(6):1687–1691CrossRef Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromolecules 7(6):1687–1691CrossRef
Zurück zum Zitat Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromolecules 8(8):2485–2491CrossRef Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromolecules 8(8):2485–2491CrossRef
Zurück zum Zitat Sharma S, Zhang XD, Nair SS, Ragauskas A, Zhu JY, Deng YL (2014) Thermally enhanced high performance cellulose nano fibril barrier membranes. RSC Adv 4(85):45136–45142CrossRef Sharma S, Zhang XD, Nair SS, Ragauskas A, Zhu JY, Deng YL (2014) Thermally enhanced high performance cellulose nano fibril barrier membranes. RSC Adv 4(85):45136–45142CrossRef
Zurück zum Zitat Shetty CS, Bhaskar N, Bhandary MH, Raghunath BS (1996) Effect of film-forming gums in the preservation of salted and dried Indian mackerel (Rastrelliger kanagurta cuvier). J Sci Food Agric 70(4):453–460CrossRef Shetty CS, Bhaskar N, Bhandary MH, Raghunath BS (1996) Effect of film-forming gums in the preservation of salted and dried Indian mackerel (Rastrelliger kanagurta cuvier). J Sci Food Agric 70(4):453–460CrossRef
Zurück zum Zitat Shimizu M, Saito T, Fukuzumi H, Isogai A (2014) Hydrophobic, ductile, and transparent nanocellulose films with quaternary alkylammonium carboxylates on nanofibril surfaces. Biomacromolecules 15(11):4320–4325CrossRef Shimizu M, Saito T, Fukuzumi H, Isogai A (2014) Hydrophobic, ductile, and transparent nanocellulose films with quaternary alkylammonium carboxylates on nanofibril surfaces. Biomacromolecules 15(11):4320–4325CrossRef
Zurück zum Zitat Sirvio JA, Kolehmainen A, Visanko M, Liimatainen H, Niinimaki J, Hormi OEO (2014) Strong, self-standing oxygen barrier films from nanocelluloses modified with regioselective oxidative treatments. ACS Appl Mater Interfaces 6(16):14384–14390CrossRef Sirvio JA, Kolehmainen A, Visanko M, Liimatainen H, Niinimaki J, Hormi OEO (2014) Strong, self-standing oxygen barrier films from nanocelluloses modified with regioselective oxidative treatments. ACS Appl Mater Interfaces 6(16):14384–14390CrossRef
Zurück zum Zitat Song ZP, Xiao HN, Zhao Y (2014) Hydrophobic-modified nano-cellulose fiber/PLA biodegradable composites for lowering water vapor transmission rate (WVTR) of paper. Carbohydr Polym 111:442–448CrossRef Song ZP, Xiao HN, Zhao Y (2014) Hydrophobic-modified nano-cellulose fiber/PLA biodegradable composites for lowering water vapor transmission rate (WVTR) of paper. Carbohydr Polym 111:442–448CrossRef
Zurück zum Zitat Takagi H, Asano A (2008) Effects of processing conditions on flexural properties of cellulose nanofiber reinforced “green” composites. Compos Part A-Appl S 39(4):685–689CrossRef Takagi H, Asano A (2008) Effects of processing conditions on flexural properties of cellulose nanofiber reinforced “green” composites. Compos Part A-Appl S 39(4):685–689CrossRef
Zurück zum Zitat Wang F, Kim S-S, Kee C-D, Shen Y-D, Oh I-K (2014a) Novel electroactive PVA-TOCN actuator that is extremely sensitive to low electrical inputs. Smart Mater Struct 23(7):1–10CrossRef Wang F, Kim S-S, Kee C-D, Shen Y-D, Oh I-K (2014a) Novel electroactive PVA-TOCN actuator that is extremely sensitive to low electrical inputs. Smart Mater Struct 23(7):1–10CrossRef
Zurück zum Zitat Wang Z, Ma HY, Hsiao BS, Chu B (2014b) Nanofibrous ultrafiltration membranes containing cross-linked poly(ethylene glycol) and cellulose nanofiber composite barrier layer. Polymer 55(1):366–372CrossRef Wang Z, Ma HY, Hsiao BS, Chu B (2014b) Nanofibrous ultrafiltration membranes containing cross-linked poly(ethylene glycol) and cellulose nanofiber composite barrier layer. Polymer 55(1):366–372CrossRef
Zurück zum Zitat Wu XY, Ye YQ, Chen YN, Ding B, Cui JJ, Jiang B (2010) Selective oxidation and determination of the substitution pattern of hydroxypropyl guar gum. Carbohydr Polym 80(4):1178–1182CrossRef Wu XY, Ye YQ, Chen YN, Ding B, Cui JJ, Jiang B (2010) Selective oxidation and determination of the substitution pattern of hydroxypropyl guar gum. Carbohydr Polym 80(4):1178–1182CrossRef
Zurück zum Zitat Wu C-N, Saito T, Fujisawa S, Fukuzumi H, Isogai A (2012) Ultrastrong and high gas-barrier nanocellulose/clay-layered composites. Biomacromolecules 13(6):1927–1932CrossRef Wu C-N, Saito T, Fujisawa S, Fukuzumi H, Isogai A (2012) Ultrastrong and high gas-barrier nanocellulose/clay-layered composites. Biomacromolecules 13(6):1927–1932CrossRef
Zurück zum Zitat Wu C-N, Saito T, Yang QL, Fukuzumi H, Isogai A (2014) Increase in the water contact angle of composite film surfaces caused by the assembly of hydrophilic nanocellulose fibrils and nanoclay platelets. ACS Appl Mater Interfaces 6(15):12707–12712CrossRef Wu C-N, Saito T, Yang QL, Fukuzumi H, Isogai A (2014) Increase in the water contact angle of composite film surfaces caused by the assembly of hydrophilic nanocellulose fibrils and nanoclay platelets. ACS Appl Mater Interfaces 6(15):12707–12712CrossRef
Zurück zum Zitat Xiao CB, Zhang JH, Zhang ZJ, Zhang LN (2003) Study of blend films from chitosan and hydroxypropyl guar gum. J Appl Polym Sci 90(7):1991–1995CrossRef Xiao CB, Zhang JH, Zhang ZJ, Zhang LN (2003) Study of blend films from chitosan and hydroxypropyl guar gum. J Appl Polym Sci 90(7):1991–1995CrossRef
Zurück zum Zitat Yang H, Tejado A, Alam N, Antal M, van de Ven TG (2012) Films prepared from electrosterically stabilized nanocrystalline cellulose. Langmuir 28(20):7834–7842CrossRef Yang H, Tejado A, Alam N, Antal M, van de Ven TG (2012) Films prepared from electrosterically stabilized nanocrystalline cellulose. Langmuir 28(20):7834–7842CrossRef
Zurück zum Zitat Yano H, Sugiyama J, Nakagaito AN, Nogi M, Matsuura T, Hikita M, Handa K (2005) Optically transparent composites reinforced with networks of bacterial nanofibers. Adv Mater 17(2):153–155CrossRef Yano H, Sugiyama J, Nakagaito AN, Nogi M, Matsuura T, Hikita M, Handa K (2005) Optically transparent composites reinforced with networks of bacterial nanofibers. Adv Mater 17(2):153–155CrossRef
Zurück zum Zitat Zhou YM, Fu SY, Zheng LM, Zhan HY (2012) Effect of nanocellulose isolation techniques on the formation of reinforced poly(vinyl alcohol) nanocomposite films. Express Polym Lett 6(10):794–804CrossRef Zhou YM, Fu SY, Zheng LM, Zhan HY (2012) Effect of nanocellulose isolation techniques on the formation of reinforced poly(vinyl alcohol) nanocomposite films. Express Polym Lett 6(10):794–804CrossRef
Metadaten
Titel
Properties of hydroxypropyl guar/TEMPO-oxidized cellulose nanofibrils composite films
verfasst von
Lei Dai
Bin Wang
Zhu Long
Le Chen
Dan Zhang
Shuai Guo
Publikationsdatum
01.10.2015
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 5/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-015-0691-2

Weitere Artikel der Ausgabe 5/2015

Cellulose 5/2015 Zur Ausgabe