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Cellulose

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24.10.2017 | Original Paper

Temperature-induced formation of cellulose nanofiber film with remarkably high gas separation performance

verfasst von: Xiong-Fei Zhang, Yi Feng, Chaobo Huang, Yichang Pan, Jianfeng Yao

Erschienen in: Cellulose | Ausgabe 12/2017

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Abstract

Free-standing cellulose nanofiber (CNF) films were prepared by a specially designed oven-drying approach. For the first time, the evaporation rate was carefully controlled to enhance the gas separation performance of the CNF film with the highest H₂/N₂ and H₂/O₂ selectivities of 159.4 and 218.2, respectively. The dense structure formed by the CNFs and the intra- and inter-fibrillar hydrogen bonds are believed to contribute to the separation property. Particularly, the specific role of floating-shape film precursor formed at the rapid evaporation stage (stage I) and the mechanism for film formation were investigated. This study demonstrated that the evaporation rate controlled by the heating temperature exhibited significant influence on surface, uniformity and gas separation of the CNF films.

Vorheriger Artikel Synthesis of hydrophobically modified cellulose-based flocculant and its application in treatments of kaolin suspension and machining wastewater

Nächster Artikel Effects of addition method and fibrillation degree of cellulose nanofibrils on furnish drainability and paper properties

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Titel: Temperature-induced formation of cellulose nanofiber film with remarkably high gas separation performance
verfasst von: Xiong-Fei Zhang
Yi Feng
Chaobo Huang
Yichang Pan
Jianfeng Yao
Publikationsdatum: 24.10.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 12/2017
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1529-x

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