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20.03.2018 | Original Paper

Facile fabrication of thiol-modified cellulose sponges for adsorption of Hg²⁺ from aqueous solutions

verfasst von: Liduo Rong, Zumei Zhu, Bijia Wang, Zhiping Mao, Hong Xu, Linping Zhang, Yi Zhong, Xiaofeng Sui

Erschienen in: Cellulose | Ausgabe 5/2018

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Abstract

Thiol-functionalised cellulose sponges were conveniently synthesised by reacting (2,2,6,6-tetramethylpiperidin-1-yl)oxyl oxidised cellulose nanofibrils (CNF) with (3-mercaptopropyl)-trimethoxysilane (MPTMS) at room temperature. The sponges, whose structures resemble honeycombs, were systematically characterised using Fourier transform infrared spectroscopy, solid-state ¹³C nuclear magnetic resonance spectroscopy, elemental analysis, scanning electron microscopy, energy-dispersive X-ray spectroscopy and compression tests. It was shown that the sponges could be used to selectively remove Hg²⁺ from an aqueous solution containing other metal ions and had excellent adsorption capacities of up to 700 mg/g. The sorption isotherm followed the typical Langmuir model and the adsorption kinetics fit a pseudo-second-order model. X-ray photoelectron spectroscopy was applied to confirm that sulfur and oxygen had significant roles in the adsorption of Hg²⁺. The sponges also showed high reusability after three adsorption–desorption cycles. This paper provides a simple method to prepare highly efficient adsorbents for the adsorption of Hg²⁺ from aqueous solutions.

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Nächster Artikel Artocarpus odoratissimus leaf-based cellulose as adsorbent for removal of methyl violet and crystal violet dyes from aqueous solution

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Titel: Facile fabrication of thiol-modified cellulose sponges for adsorption of Hg2+ from aqueous solutions
verfasst von: Liduo Rong
Zumei Zhu
Bijia Wang
Zhiping Mao
Hong Xu
Linping Zhang
Yi Zhong
Xiaofeng Sui
Publikationsdatum: 20.03.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 5/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1758-7

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