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19.05.2021 | Original Research

Cellulose nanocrystals from bleached rice straw pulp: acidic deep eutectic solvent versus sulphuric acid hydrolyses

verfasst von: Wei-Lun Lim, Ahmad Anas Nagoor Gunny, Farizul Hafiz Kasim, Subash C. B. Gopinath, Nor Helya Iman Kamaludin, Dachyar Arbain

Erschienen in: Cellulose | Ausgabe 10/2021

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Abstract

The present work aims to investigate the feasibility of oxalic acid-choline chloride deep eutectic solvent (OA-ChCl DES), which serves as a promising green solvent that utilized in the acidic deep eutectic solvent (DES) hydrolysis. Oxalic acid-choline chloride DES cellulose nanocrystal (OA-ChCl DES CNC) was isolated from the bleached DES treated pulp (BP) through the acidic DES hydrolysis using 1:1 molar ratio of OA-ChCl DES. The functional groups, crystallinity index, morphological structure, particle size, zeta potential, thermal stability and surface chemistry of the OA-ChCl DES CNC were compared with the sulphuric acid cellulose nanocrystal (SA-CNC) that prepared via sulphuric acid hydrolysis. The findings revealed the presence of negatively charged carboxyl groups on OA-ChCl DES CNC surface after the acidic DES hydrolysis. The physicochemical analyses verified that the OA-ChCl DES CNC was in nano-sized range with polydispersity index (PdI) of 0.56, indicating slightly monodispersed nanoparticles. A stable OA-ChCl DES CNC colloidal suspension with zeta potential value of −52.1 ± 5.2 mV was obtained. The OA-ChCl DES CNC outweighed the SA-CNC in term of thermal stability (288 °C) despite having a slightly lower crystallinity index (76.7%). In fact, the OA-ChCl DES CNC with a yield of 55.1% was achieved through the acidic DES hydrolysis, suggesting that the OA-ChCl DES was capable of promoting efficient cleavage of strong hydrogen bonds in BP.

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Vorheriger Artikel Efficient cleavage of strong hydrogen bonds in sugarcane bagasse by ternary acidic deep eutectic solvent and ultrasonication to facile fabrication of cellulose nanofibers

Nächster Artikel Novel green strategy to improve the hydrophobicity of cellulose nanocrystals and the interfacial elasticity of Pickering emulsions

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Titel: Cellulose nanocrystals from bleached rice straw pulp: acidic deep eutectic solvent versus sulphuric acid hydrolyses
verfasst von: Wei-Lun Lim
Ahmad Anas Nagoor Gunny
Farizul Hafiz Kasim
Subash C. B. Gopinath
Nor Helya Iman Kamaludin
Dachyar Arbain
Publikationsdatum: 19.05.2021
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 10/2021
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-021-03914-7

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