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Erschienen in: Journal of Materials Science 10/2014

01.05.2014

Study on the temperature dependence of the OH absorption band in Hf-doped LiNbO3 crystals

verfasst von: Xunan Shen, Wenbo Yan, Jianli Jing, Lihong Shi, Fangfang Jia, Guohong Liang, Yingying Huang, Meng Wu, Yuwei Zhang, Haiyun Dong, Jiushuang Zhang, Guifeng Chen, Hongjian Chen

Erschienen in: Journal of Materials Science | Ausgabe 10/2014

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Abstract

We study in this paper the temperature dependence of the OH absorption band in LiNbO3 crystals with different Hf-doping concentrations. It is found that the shoulder at 3500 cm−1 appears in the doping level of 2.6 mol%, becomes more evident at 3 and 4 mol%, and then gradually faints when the doping concentration increases. This result is explained by the non-monotonic change of Nb vacancy density in the three stages of the defect evolution involved in the Hf incorporation of LN lattice. Moreover, the absorption difference analysis of the OH bands is consistent with this explanation and reveals that the mobility of H+ ions may be reduced by the strong trapping of the highly electronegative Nb vacancies.

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Metadaten
Titel
Study on the temperature dependence of the OH− absorption band in Hf-doped LiNbO3 crystals
verfasst von
Xunan Shen
Wenbo Yan
Jianli Jing
Lihong Shi
Fangfang Jia
Guohong Liang
Yingying Huang
Meng Wu
Yuwei Zhang
Haiyun Dong
Jiushuang Zhang
Guifeng Chen
Hongjian Chen
Publikationsdatum
01.05.2014
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-014-8088-4

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