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Journal of Materials Science

Erschienen in:

01.10.2014

The key factor for fabricating through-hole TiO₂ nanotube arrays: a fluoride-rich layer between Ti substrate and nanotubes

verfasst von: Zhi-Yong Luo, Dong-Chuan Mo, Shu-Shen Lu

Erschienen in: Journal of Materials Science | Ausgabe 19/2014

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Abstract

Through-hole TiO₂ nanotube arrays (THTNA) are fabricated successfully by applying a large-voltage pulse (ΔV ≥ 40 V) at the end of anodization, and a mechanism is proposed that the fluoride-rich layer (FRL) between Ti substrate and nanotubes is the key factor for fabricating THTNA. In order to confirm the mechanism, the effects of temperature of voltage pulse on the morphology of the bottom of TiO₂ nanotubes are explored. The results show the inner diameter of the bottom became larger with the temperature increasing due to the wall thickness of bottom of TiO₂ nanotubes decreased and assisted by the increased fluorine content of the bottom, which is strong evidence for the mechanism proposed. What is more, the inner diameter of the bottom of THTNA can be manipulated via this novel mechanism.

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Macak JM, Zlamal M, Krysa J, Schmuki P (2007) Self-organized TiO₂ nanotube layers as highly efficient photocatalysts. Small 3:300–304CrossRef

Li SQ, Zhang GM, Guo DZ, Yu LG, Zhang W (2009) Anodization fabrication of highly ordered TiO₂ nanotubes. J Phys Chem C 113:12759–12765CrossRef

Su Z, Zhou W (2011) Formation, morphology control and applications of anodic TiO₂ nanotube arrays. J Mater Chem 21:8955CrossRef

Roy P, Berger S, Schmuki P (2011) TiO₂ nanotubes: synthesis and applications. Angew Chem Int Ed 50:2904–2939CrossRef

Paulose M, Shankar K, Varghese OK, Mor GK, Hardin B, Grimes CA (2006) Backside illuminated dye-sensitized solar cells based on titania nanotube array electrodes. Nanotechnology 17:1446–1448CrossRef

Lee J, Hong KS, Shin K, Jho JY (2012) Fabrication of dye-sensitized solar cells using ordered and vertically oriented TiO₂ nanotube arrays with open and closed ends. J Ind Eng Chem 18:19–23CrossRef

Wang J, Lin ZQ (2008) Freestanding TiO₂ nanotube arrays with ultrahigh aspect ratio via electrochemical anodization. Chem Mater 20:1257–1261CrossRef

Lin CJ, Yu WY, Lu YT, Chien SH (2008) Fabrication of open-ended high aspect-ratio anodic TiO₂ nanotube films for photocatalytic and photoelectrocatalytic applications. Chem Commun 6031–6033. doi:10.1039/b813937g

Liou YH, Kao LC, Tsai MC, Lin CJ (2012) Deposition of CdS nanoparticles within free-standing both-side-open stretched TiO₂ nanotube-array films for the enhancement of photoelectrochemical performance. Electrochem Commun 15:66–69CrossRef

10.

Chen Q, Xu D, Wu Z, Liu Z (2008) Free-standing TiO₂ nanotube arrays made by anodic oxidation and ultrasonic splitting. Nanotechnology 19:365708CrossRef

11.

Liao J, Lin S, Pan N, Li S, Cao X, Cao Y (2012) Fabrication and photocatalytic properties of free-standing TiO₂ nanotube membranes with through-hole morphology. Mater Charact 66:24–29CrossRef

12.

Liao J, Lin S, Pan N, Li D, Li S, Li J (2012) Free-standing open-ended TiO₂ nanotube membranes and their promising through-hole applications. Chem Eng J 211–212:343–352CrossRef

13.

Yip CT, Guo M, Huang H, Zhou L, Wang Y, Huang C (2012) Open-ended TiO₂ nanotubes formed by two-step anodization and their application in dye-sensitized solar cells. Nanoscale 4:448–450CrossRef

14.

Lin CJ, Yu WY, Chien SH (2010) Transparent electrodes of ordered opened-end TiO₂-nanotube arrays for highly efficient dye-sensitized solar cells. J Mater Chem 20:1073–1077CrossRef

15.

Sun LD, Zhang S, Wang Q, Zhao DL (2012) Conformal growth of anodic nanotubes for dye-sensitized solar cells: part I. Planar electrode. Nanosci Nanotechnol Lett 4:471–482CrossRef

16.

Albu SP, Ghicov A, Macak JM, Hahn R, Schmuki P (2007) Self-organized, free-standing TiO₂ nanotube membrane for flow-through photocatalytic applications. Nano Lett 7:1286–1289CrossRef

17.

Paulose M, Peng L, Popat K, Varghese O, Latempa T, Bao N, Desai T, Grimes C (2008) Fabrication of mechanically robust, large area, polycrystalline nanotubular/porous TiO₂ membranes. J Memb Sci 319:199–205CrossRef

18.

Liu G, Wang K, Hoivik N, Jakobsen H (2012) Progress on free-standing and flow-through TiO₂ nanotube membranes. Sol Energy Mater Sol Cells 98:24–38CrossRef

19.

Wan J, Yan X, Ding J, Wang M, Hu K (2009) Self-organized highly ordered TiO₂ nanotubes in organic aqueous system. Mater Charact 60:1534–1540CrossRef

20.

Zhang ZK, Guo DZ, Xing YJ, Zhang GM (2011) Fabrication of open-ended TiO₂ nanotube arrays by anodizing a thermally evaporated Ti/Au bilayer film. Appl Surf Sci 257:4139–4143CrossRef

21.

Prakasam HE, Shankar K, Paulose M, Varghese OK, Grimes CA (2007) A new benchmark for TiO₂ nanotube array growth by anodization. J Phys Chem C 111:7235–7241CrossRef

22.

Fang D, Huang K, Liu S, Qin D (2009) High density copper nanowire arrays deposition inside ordered titania pores by electrodeposition. Electrochem Commun 11:901–904CrossRef

23.

Choi J, Park SH, Kwon YS, Lim J, Song IY, Park T (2012) Facile fabrication of aligned doubly open-ended TiO₂ nanotubes, via a selective etching process, for use in front-illuminated dye sensitized solar cells. Chem Commun 48:8748–8750CrossRef

24.

Liao J, Lin S, Li X, Li S, Cao X, Cao Y (2012) Fabrication of free-standing TiO₂ nanotube membranes with through-hole morphology. Cryst Res Technol 47:731–737CrossRef

25.

Kant K, Losic D (2009) A simple approach for synthesis of TiO2 nanotubes with through-hole morphology. Phys Status Solidi (RRL) Rapid Res Lett 3:139–141CrossRef

26.

Jo Y, Jung I, Lee I, Choi J, Tak Y (2010) Fabrication of through-hole TiO₂ nanotubes by potential shock. Electrochem Commun 12:616–619CrossRef

27.

Wang D, Liu L (2010) Continuous fabrication of free-standing TiO₂ nanotube array membranes with controllable morphology for depositing interdigitated heterojunctions. Chem Mater 22:6656–6664CrossRef

28.

Ouyang HM, Fei GT, Zhang Y, Su H, Jin Z, Xu SH, De Zhang L (2013) Large scale free-standing open-ended TiO₂ nanotube arrays: stress-induced self-detachment and in situ pore opening. J Mater Chem C 1:7498CrossRef

29.

Bian H, Wang Y, Yuan B, Cui J, Shu X, Wu Y, Zhang X, Adeloju S (2013) Flow-through TiO₂ nanotube arrays: a modified support with homogeneous distribution of Ag nanoparticles and their photocatalytic activities. New J Chem 37:752–760CrossRef

30.

Liu G, Hoivik N, Wang K, Jakobsen H (2011) A voltage-dependent investigation on detachment process for free-standing crystalline TiO₂ nanotube membranes. J Mater Sci 46:7931–7935CrossRef

31.

Albu SP, Ghicov A, Aldabergenova S, Drechsel P, LeClere D, Thompson GE, Macak JM, Schmuki P (2008) Formation of double-walled TiO₂ nanotubes and robust anatase membranes. Adv Mater 20:4135–4139

32.

Berger S, Albu SP, Schmidt-Stein F, Hildebrand H, Schmuki P, Hammond JS, Paul DF, Reichlmaier S (2011) The origin for tubular growth of TiO₂ nanotubes: a fluoride rich layer between tube-walls. Surf Sci 605:L57–L60CrossRef

33.

Song YY, Roy P, Paramasivam I, Schmuki P (2010) Voltage-induced payload release and wettability control on TiO₂ and TiO₂ nanotubes. Angew Chem Int Ed 49:351–354CrossRef

34.

Ghicov A, Schmuki P (2009) Self-ordering electrochemistry: a review on growth and functionality of TiO₂ nanotubes and other self-aligned MO(x) structures. Chem Commun 2791–2808. doi:10.1039/b822726h

35.

Luan X, Guan D, Wang Y (2012) Facile synthesis and morphology control of bamboo-type TiO₂ nanotube arrays for high-efficiency dye-sensitized solar cells. J Phys Chem C 116:14257–14263CrossRef

36.

Guan D, Wang Y (2012) Synthesis and growth mechanism of multilayer TiO₂ nanotube arrays. Nanoscale 4:2968–2977CrossRef

37.

Chen J, Lin J, Chen X (2010) Self-assembled TiO₂ nanotube arrays with U-shaped profile by controlling anodization temperature. J Nanomater 2010:1–4

Titel: The key factor for fabricating through-hole TiO2 nanotube arrays: a fluoride-rich layer between Ti substrate and nanotubes
verfasst von: Zhi-Yong Luo
Dong-Chuan Mo
Shu-Shen Lu
Publikationsdatum: 01.10.2014
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 19/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-014-8368-z

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