Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Bücher
Zeitschriften
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
MTZ-Fachkongress

Antriebe und Energiesysteme von morgen


Austausch von Automobil- und Energiewirtschaft

Am 14./15. Mai geht es in Chemnitz um die Mobilitätswende durch Elektro- und Wasserstofffahrzeuge.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 3/2016

06.10.2015 | Original Paper

A microstructural and neutron-diffraction study on the interactions between microwave-irradiated multiwalled carbon nanotubes and hydrogen

verfasst von: Y. T. Lee, P. J. Tsai, V. K. Peterson, B. Yang, K. S. Lin, M. Zhu, K. L. Lim, Y. S. Tseng, S. L. I. Chan

Erschienen in: Journal of Materials Science | Ausgabe 3/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Microwave irradiation is a simple yet effective way of altering the properties of multiwalled carbon nanotubes (MWNTs). This work studies the interactions between microwave-irradiated MWNTs and hydrogen. Effects of MWNT diameter and irradiation duration on the hydrogen-storage capacity have been investigated. We find that microwave irradiation induces damage to the MWNTs that can enhance hydrogen-storage capacity, with excessive damage being detrimental. Smaller-diameter tubes suffer less damage than larger tubes do. MWNTs with a diameter of 20–40 nm irradiated for 10 min had the highest hydrogen uptake of the samples measured, of 0.87 wt% at room temperature and under a hydrogen pressure of 3 MPa. Neutron powder-diffraction data revealed structural changes that were consistent with the insertion of hydrogen in the interstitial cavities of the microwave-irradiated MWNTs, as well as an expansion between the graphene layers of samples that were microwave irradiated. Hence, this simple treatment could be a promising solution to improve the hydrogen-storage capacities of MWNTs.
Vorheriger Artikel Enhanced transparent conducting performance of Bi2Sr2Co2O8 thin films by adding gold nanoparticles
Nächster Artikel Adjustable, (super)hydrophobicity by e-beam deposition of nanostructured PTFE on textured silicon surfaces

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Ajayan PM, Ebbesen TW (1997) Nanometre-size tubes of carbon. Rep Prog Phys 60:1025–1062CrossRef
2.
Baughman RH, Zakhidov AA, Wad Heer (2002) Carbon nanotubes: the route toward applications. Science 297:787–792CrossRef
3.
Terrones M (2003) Science and technology of the twenty-first century: synthesis, properties and applications of carbon nanotubes. Annu Rev Mater Res 33:419–501CrossRef
4.
Hwa K-Y, Subramani B (2014) Synthesis of zinc oxide nanoparticles on graphene-carbon nanotube hybrid for glucose biosensor applications. Biosens Bioelectr. 62:127–133CrossRef
5.
Socas-Rodriguez B, Herrera-Herrera AV, Asensio-Ramos M, Hernandez-Borges J (2014) Recent applications of carbon nanotube sorbents in analytical chemistry. J Chromatogr A 1357:110–146CrossRef
6.
Barghi SH, Tsotsis TT, Sahimi M (2014) Chemisorption, physisorption and hysteresis during hydrogen storage in carbon nanotubes. Int J Hydrogen Energy 39:1390–1397CrossRef
7.
Liu C, Chen Y, Wu C-Z, Xu S-T, Cheng H-M (2010) Hydrogen storage in carbon nanotubes revisited. Carbon 48:452–455CrossRef
8.
Lin K-S, Mai Y-J, Li S-R, Shu C-W, Wang C-H (2012) Characterization and hydrogen storage of surface-modified multiwalled carbon nanotubes for fuel cell application. J Nanomater 2012:1–12
9.
Awasthi K, Kamalakaran R, Singh AK, Srivastava ON (2002) Ball-milled carbon and hydrogen storage. Int J Hydrogen Energy 27:425–432CrossRef
10.
Rather S, Nahm KS (2014) Hydrogen uptake of high-energy ball milled nickel-multiwalled carbon nanotube composites. Mater Res Bull 49:525–530CrossRef
11.
Chen C-H, Huang C-C (2007) Hydrogen storage by KOH-modified multi-walled carbon nanotubes. Int J Hydrogen Energy 32:237–246CrossRef
12.
Ma RZ, Wei BQ, Xu CL, Liang J, Wu DH (2000) The morphology changes of carbon nanotubes under laser irradiation. Carbon 38:636–638CrossRef
13.
Vladimir AB, Kensei K, Takeo K, Yoichi N, Elena VB, José-Manuel S-B (2002) Irradiation of single-walled carbon nanotubes with high-energy protons. Nano Lett 2:789–791CrossRef
14.
Uvarova IY, Basnukaeva RM, Dolbin AV, Danilchenko BA (2013) Hydrogen storage capacity of carbon nanotubes γ-irradiated in hydrogen and deuterium media. In: 36th International spring seminar on electronic technology, pp 309–313
15.
Takagi H, Hatori H, Yamada Y (2005) Reversible adsorption/desorption property of hydrogen on carbon surface. Carbon 43:3037–3039CrossRef
16.
Zacharia R, Kim KY, Fazle Kibria AKM, Nahm KS (2005) Enhancement of hydrogen storage capacity of carbon nanotubes via spill-over from vanadium and palladium nanoparticles. Chem Phys Lett 412:369–375CrossRef
17.
Yoo E, Gao L, Komatsu T, Yagai N, Arai K, Yamazaki T et al (2004) Atomic hydrogen storage in carbon nanotubes promoted by metal catalysts. J Phys Chem B 108:18903–18907CrossRef
18.
Chen J, Wang XG, Zhang HY (2013) Hydrogen storage in carbon nanotubes prepared by using copper nanoparticles as catalyst. New trends in mechanical engineering and materials. Appl Mech Mater 251:342–345CrossRef
19.
Imholt TJ, Dyke CA, Hasslacher B, Perez JM, Price DW, Roberts JA et al (2003) Nanotubes in microwave fields; light emission, intense heat, outgassing, and reconstruction. Chem Mat 15:3969–3970CrossRef
20.
Tour JM, Dyke CA, Stephenson JJ, Yakobson BI (2011) Interaction of microwaves with carbon nanotubes to facilitate modification. US 8080199 B2
21.
Raghuveer MS, Agrawal S, Bishop N, Ramanath G (2006) Microwave-assisted single-step functionalization and in situ derivatization of carbon nanotubes with gold nanoparticles. Chem Mater 18:1390–1393CrossRef
22.
Song JW, Seo HW, Park JK, Kim JE, Choi DG, Han CS (2008) Selective removal of metallic SWNTs using microwave radiation. Curr Appl Phys 8:725–728CrossRef
23.
Yuca N, Karatepe N (2011) Hydrogen storage in single-walled carbon nanotubes purified by microwaves digestion method. Int Sch Sci Res Innov 5:478–483
24.
Mu S-C, Tang H-I, Qian S-H, Pan M, Yuan R-Z (2006) Hydrogen storage in carbon nanotubes modified by microwave plasma etching and Pd decoration. Carbon 44:762–767CrossRef
25.
Geng H-Z, Kim TH, Lim SC, Jeong H-K, Jin MH, Jo YW et al (2010) Hydrogen storage in microwave-treated multi-walled carbon nanotubes. Int J Hydrogen Energy 35:2073–2082CrossRef
26.
Studer AJ, Hagen ME, Noakes TJ (2006) Wombat: the high-intensity powder diffractometer at the OPAL reactor. Physica B 385–386:1013–1015CrossRef
27.
Li X, Zhu H, Xu C, Mao Z, Wu D (2003) Measuring hydrogen storage capacity of carbon nanotubes by tangent-mass method. Int J Hydrogen Energy 28:1251–1253CrossRef
28.
Pan W, Zhang X, Li S, Wu D, Mao Z (2005) Measuring hydrogen storage capacity of carbon nanotubes by high-pressure microbalance. Int J Hydrogen Energy 30:719–722CrossRef
29.
Kokai F, Koshio A, Shiraishi M, Matsuta T, Shimoda S, Ishihara M et al (2005) Modification of carbon nanotubes by laser ablation. Diam Relat Mater 14:724–728CrossRef
30.
Hou P-X, Xu S-T, Ying Z, Yang Q-H, Liu C, Cheng H-M (2003) Hydrogen adsorption/desorption behavior of multi-walled carbon nanotubes with different diameters. Carbon 41:2471–2476CrossRef
31.
Reznik D, Olk CH, Neumann DA, Copley JRD (1995) X-ray powder diffraction from carbon nanotubes and nanoparticles. Phys Rev B 52:116–124CrossRef
32.
Schimmel HG, Nijkamp G, Kearley GJ, Riveraa A, de Jong KP, Mulder FM (2004) Hydrogen adsorption in carbon nanostructures compared. Mat Sci Eng B 108:124–129CrossRef
33.
Duclaux L, Los S, Azais P, Pellenq R, Breton Y, Isnard O (2006) Deuterium adsorption in carbon single walled carbon nanotubes doped by lithium and potassium: adsorption isotherms and in situ neutron diffraction. J Phys Chem Solids 67:1122–1126CrossRef
Metadaten
Titel
A microstructural and neutron-diffraction study on the interactions between microwave-irradiated multiwalled carbon nanotubes and hydrogen
verfasst von
Y. T. Lee
P. J. Tsai
V. K. Peterson
B. Yang
K. S. Lin
M. Zhu
K. L. Lim
Y. S. Tseng
S. L. I. Chan
Publikationsdatum
06.10.2015
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 3/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-015-9448-4

Weitere Artikel der Ausgabe 3/2016

Journal of Materials Science 3/2016 Zur Ausgabe

Original Paper

Indication of thermal roughening in the retrieved mean inner potential across a Σ5 grain boundary in SrTiO3 annealed at different temperatures

Original Paper

Enhanced transparent conducting performance of Bi2Sr2Co2O8 thin films by adding gold nanoparticles

Original Paper

The effects of thermal nitridation on phosphorus diffusion in strained SiGe and SiGe:C

Multiscale Modeling and Experiment

Multiscale modeling of sensory properties of Co–Ni–Al shape memory particles embedded in an Al metal matrix

Multiscale Modeling and Experiment

Bridging atomistic simulations and experiments via virtual diffraction: understanding homophase grain boundary and heterophase interface structures

Original Paper

Study of the initial stages of defect generation in ion-irradiated MgO at elevated temperatures using high-resolution X-ray diffraction

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise