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Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2016

28.06.2016 | Original Paper

The facile synthesis of PMMA polyHIPEs with highly interconnected porous microstructures

verfasst von: Zichao Li, Huarong Liu, Lai Zeng, Hewen Liu, Yanmei Wang

Erschienen in: Journal of Materials Science | Ausgabe 19/2016

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Abstract

It is difficult to prepare stable high internal phase emulsions (HIPEs) of methyl methacrylate (MMA) due to the considerable high solubility of MMA in water phase. Here, we present a facile method to prepare the stable HIPEs of MMA (MMA HIPEs) with the widely used sorbitan monooleate (Span 80) as surfactant just by adding hexadecane (HD) or hydroxyl-terminated polybutadiene (HTPB) as a costabilizer. The different roles of the two long-chain costabilizers (HD and HTPB) to improve the stability of the MMA HIPEs were studied. Poly(methyl methacrylate) porous monoliths were prepared based on the MMA HIPE templates and characterized by field emission scanning electron microscopy, transmission electron microscopy, and N2 sorption analysis, which showed the formation of highly interconnected pores. Factors that affected the stability of MMA HIPEs and the morphology of polyHIPEs were also investigated.
Vorheriger Artikel Factors limiting doping efficiency of Iridium in pulsed laser deposited TiO2 transparent conducting oxide
Nächster Artikel Influence of cross-linking density on the structure and properties of the interphase within supported ultrathin epoxy films

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Metadaten
Titel
The facile synthesis of PMMA polyHIPEs with highly interconnected porous microstructures
verfasst von
Zichao Li
Huarong Liu
Lai Zeng
Hewen Liu
Yanmei Wang
Publikationsdatum
28.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0154-7

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