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Journal of Materials Science

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08.07.2016 | Original Paper

Photosynthesis of poly(glycidyl methacrylate) microspheres: a component for making covalently cross-linked colloidosomes and organic/inorganic nanocomposites

verfasst von: Jianbo Tan, Lili Fu, Xuechao Zhang, Yuhao Bai, Li Zhang

Erschienen in: Journal of Materials Science | Ausgabe 20/2016

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Abstract

Herein, we report a photoinitiated RAFT dispersion polymerization for the preparation of highly monodisperse poly(glycidyl methacrylate) (PGMA) microspheres at room temperature. Fast polymerization rates were achieved, with near quantitative yields within 2 h of UV irradiation. The effect of reaction conditions (e.g., stabilizer concentration, monomer concentration and solvent composition) on particle morphologies was studied in detail. Amine-functionalized PGMA microspheres were prepared by treating PGMA microspheres with ethylene diamine (EDA) at 70 °C, and the obtained product was characterized by FT-IR and XPS. Such amine-functionalized PGMA microspheres were able to stabilize oil-in-water Pickering emulsions. Covalently cross-linked colloidosomes were formed by cross-linking primary amino groups on the particle surface using (tolylene 2,4-diisocyanate-terminated poly(propylene glycol) (PPG-TDI) as a cross-linker. Amine-functionalized PGMA microspheres were also employed as templates for the synthesis of PGMA/gold (Au) hybrid microspheres and large gold nanoplates.

Vorheriger Artikel Probing the structures, stabilities, and electronic properties of neutral and charged carbon-doped lithium CLi n μ (n = 2–20, μ = 0, ±1) clusters from unbiased CALYPSO method

Nächster Artikel Synthesis, characterization, and adsorption properties of silica aerogels crosslinked with diisocyanate under ambient drying

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Titel: Photosynthesis of poly(glycidyl methacrylate) microspheres: a component for making covalently cross-linked colloidosomes and organic/inorganic nanocomposites
verfasst von: Jianbo Tan
Lili Fu
Xuechao Zhang
Yuhao Bai
Li Zhang
Publikationsdatum: 08.07.2016
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 20/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-016-0190-3

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