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Erschienen in: Journal of Materials Science 3/2017

17.10.2016 | Original Paper

Boron-doped nanoporous carbons as promising materials for supercapacitors and hydrogen storage

verfasst von: Nataliya Shcherban, Svitlana Filonenko, Pavel Yaremov, Vyacheslav Dyadyun, Igor Bezverkhyy, Vladimir Ilyin

Erschienen in: Journal of Materials Science | Ausgabe 3/2017

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Abstract

Boron-doped carbon nanostructures were obtained via template and bulk synthesis from sucrose in the presence of boric acid. Synthesized B-containing mesoporous materials are characterized by high spatial ordering, developed surface (up to 870 m2/g), and porosity (up to 1.2 cm3/g). The obtained B-doped microporous materials exhibit high interfacial capacitance (up to 0.36 F/m2), which is higher than the available literature data and enables the use of synthesized samples as materials of supercapacitors. The capacity of electric double layer up to 300 F/g using sulfuric acid as the electrolyte was accumulated on microporous B-doped carbons.

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Literatur
1.
Zurück zum Zitat Stein A, Wang Z, Fierke MA (2009) Functionalization of porous carbon materials with designed pore architecture. Adv Mater 21:265–293CrossRef Stein A, Wang Z, Fierke MA (2009) Functionalization of porous carbon materials with designed pore architecture. Adv Mater 21:265–293CrossRef
2.
Zurück zum Zitat Xia Y, Yang Z, Zhu Y (2013) Porous carbon-based materials for hydrogen storage: advancement and challenges. J Mater Chem A 1:9365–9381CrossRef Xia Y, Yang Z, Zhu Y (2013) Porous carbon-based materials for hydrogen storage: advancement and challenges. J Mater Chem A 1:9365–9381CrossRef
3.
Zurück zum Zitat Burgess JS, Acharya CK, Lizarazo J, Yancey N, Flowers B, Kwon G, Klein T, Weaver M, Lane AM, Turner CH, Street S (2008) Boron-doped carbon powders formed at 1000 °C and one atmosphere. Carbon 46:1711–1717CrossRef Burgess JS, Acharya CK, Lizarazo J, Yancey N, Flowers B, Kwon G, Klein T, Weaver M, Lane AM, Turner CH, Street S (2008) Boron-doped carbon powders formed at 1000 °C and one atmosphere. Carbon 46:1711–1717CrossRef
4.
Zurück zum Zitat Jeong Y, Chung TCM (2010) The synthesis and characterization of a super-activated carbon containing substitutional boron (BC x ) and its applications in hydrogen storage. Carbon 48:2526–2537CrossRef Jeong Y, Chung TCM (2010) The synthesis and characterization of a super-activated carbon containing substitutional boron (BC x ) and its applications in hydrogen storage. Carbon 48:2526–2537CrossRef
5.
Zurück zum Zitat Paraknowitsch JP, Thomas A (2013) Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications. Energy Environ Sci 6:2839–2855CrossRef Paraknowitsch JP, Thomas A (2013) Doping carbons beyond nitrogen: an overview of advanced heteroatom doped carbons with boron, sulphur and phosphorus for energy applications. Energy Environ Sci 6:2839–2855CrossRef
6.
Zurück zum Zitat Wang L, Yang FH, Yang RT (2009) Hydrogen storage properties of B-and N-doped microporous carbon. AIChE J 55:1823–1833CrossRef Wang L, Yang FH, Yang RT (2009) Hydrogen storage properties of B-and N-doped microporous carbon. AIChE J 55:1823–1833CrossRef
7.
Zurück zum Zitat Zhai X, Song Y, Liu J, Li P, Zhong M, Ma C, Wang H, Guo Q, Zhi L (2012) In-situ preparation of boron-doped carbons with ordered mesopores and enhanced electrochemical properties in supercapacitors. J Electrochem Soc 159:E177–E182CrossRef Zhai X, Song Y, Liu J, Li P, Zhong M, Ma C, Wang H, Guo Q, Zhi L (2012) In-situ preparation of boron-doped carbons with ordered mesopores and enhanced electrochemical properties in supercapacitors. J Electrochem Soc 159:E177–E182CrossRef
8.
Zurück zum Zitat Arutyunyan NR, Arenal R, Obraztsova ED, Stephan O, Loiseau A, Pozharov AS, Grebenyukov VV (2012) Incorporation of boron and nitrogen in carbon nanomaterials and its influence on their structure and opto-electronical properties. Carbon 50:791–799CrossRef Arutyunyan NR, Arenal R, Obraztsova ED, Stephan O, Loiseau A, Pozharov AS, Grebenyukov VV (2012) Incorporation of boron and nitrogen in carbon nanomaterials and its influence on their structure and opto-electronical properties. Carbon 50:791–799CrossRef
9.
Zurück zum Zitat Wu X, Radovic LR (2004) Ab initio molecular orbital study on the electronic structures and reactivity of boron-substituted carbon. J Phys Chem A 108:9180–9187CrossRef Wu X, Radovic LR (2004) Ab initio molecular orbital study on the electronic structures and reactivity of boron-substituted carbon. J Phys Chem A 108:9180–9187CrossRef
10.
Zurück zum Zitat Morita T, Takami N (2004) Characterization of oxidized boron-doped carbon fiber anodes for Li-ion batteries by analysis of heat of immersion. Electrochim Acta 49:2591–2599CrossRef Morita T, Takami N (2004) Characterization of oxidized boron-doped carbon fiber anodes for Li-ion batteries by analysis of heat of immersion. Electrochim Acta 49:2591–2599CrossRef
11.
Zurück zum Zitat Shiraishi S, Kibe M, Yokoyama T, Kurihara H, Patel N, Oya A, Kaburagi Y, Hishiyama Y (2006) Electric double layer capacitance of multi-walled carbon nanotubes and B-doping effect. Appl Phys A 82:585–591CrossRef Shiraishi S, Kibe M, Yokoyama T, Kurihara H, Patel N, Oya A, Kaburagi Y, Hishiyama Y (2006) Electric double layer capacitance of multi-walled carbon nanotubes and B-doping effect. Appl Phys A 82:585–591CrossRef
12.
Zurück zum Zitat Zhong DH, Sano H, Uchiyama Y, Kobayashi K (2000) Effect of low-level boron doping on oxidation behavior of polyimide-derived carbon films. Carbon 38:1199–1206CrossRef Zhong DH, Sano H, Uchiyama Y, Kobayashi K (2000) Effect of low-level boron doping on oxidation behavior of polyimide-derived carbon films. Carbon 38:1199–1206CrossRef
13.
Zurück zum Zitat Niu L, Li Z, Hong W, Sun J, Wang Z, Ma L, Wang J, Yang S (2013) Pyrolytic synthesis of boron-doped graphene and its application as electrode material for supercapacitors. Electrochim Acta 108:666–673CrossRef Niu L, Li Z, Hong W, Sun J, Wang Z, Ma L, Wang J, Yang S (2013) Pyrolytic synthesis of boron-doped graphene and its application as electrode material for supercapacitors. Electrochim Acta 108:666–673CrossRef
14.
Zurück zum Zitat Chen SM, Ramachandran R, Mani V, Saraswathi R (2014) Recent advancements in electrode materials for the high performance electrochemical supercapacitors: a review. Int J Electrochem Sci 9:4072–4085 Chen SM, Ramachandran R, Mani V, Saraswathi R (2014) Recent advancements in electrode materials for the high performance electrochemical supercapacitors: a review. Int J Electrochem Sci 9:4072–4085
15.
Zurück zum Zitat Fang H, Yu C, Ma T, Qiu J (2014) Boron-doped graphene as a high-efficiency counter electrode for dye-sensitized solar cells. Chem Commun 50(25):3328–3330CrossRef Fang H, Yu C, Ma T, Qiu J (2014) Boron-doped graphene as a high-efficiency counter electrode for dye-sensitized solar cells. Chem Commun 50(25):3328–3330CrossRef
16.
Zurück zum Zitat Yu C, Fang H, Liu Z, Hu H, Meng X, Qiu J (2016) Chemically grafting graphene oxide to B N co-doped graphene via ionic liquid and their superior performance for triiodide reduction. Nano Energy 25:184–192CrossRef Yu C, Fang H, Liu Z, Hu H, Meng X, Qiu J (2016) Chemically grafting graphene oxide to B N co-doped graphene via ionic liquid and their superior performance for triiodide reduction. Nano Energy 25:184–192CrossRef
17.
Zurück zum Zitat Ling Z, Wang G, Zhang M, Fan X, Yu C, Yang J, Qiu J (2015) Boric acid-mediated B N-codoped chitosan-derived porous carbons with a high surface area and greatly improved supercapacitor performance. Nanoscale 7(12):5120–5125CrossRef Ling Z, Wang G, Zhang M, Fan X, Yu C, Yang J, Qiu J (2015) Boric acid-mediated B N-codoped chitosan-derived porous carbons with a high surface area and greatly improved supercapacitor performance. Nanoscale 7(12):5120–5125CrossRef
18.
Zurück zum Zitat Ling Z, Wang Z, Zhang M, Yu C, Wang G, Dong Y, Qiu J (2016) Sustainable synthesis and assembly of biomass-derived B/N co-doped carbon nanosheets with ultrahigh aspect ratio for high-performance supercapacitors. Adv Funct Mater 26(1):111–119CrossRef Ling Z, Wang Z, Zhang M, Yu C, Wang G, Dong Y, Qiu J (2016) Sustainable synthesis and assembly of biomass-derived B/N co-doped carbon nanosheets with ultrahigh aspect ratio for high-performance supercapacitors. Adv Funct Mater 26(1):111–119CrossRef
19.
Zurück zum Zitat He X, Ling P, Qiu J, Yu M, Zhang X, Yu C, Zheng M (2013) Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density. J Power Sour 240:109–113CrossRef He X, Ling P, Qiu J, Yu M, Zhang X, Yu C, Zheng M (2013) Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density. J Power Sour 240:109–113CrossRef
20.
Zurück zum Zitat Wang DW, Li F, Chen ZG, Lu GQ, Cheng HM (2008) Synthesis and electrochemical property of boron-doped mesoporous carbon in supercapacitor. Chem Mater 20:7195–7200CrossRef Wang DW, Li F, Chen ZG, Lu GQ, Cheng HM (2008) Synthesis and electrochemical property of boron-doped mesoporous carbon in supercapacitor. Chem Mater 20:7195–7200CrossRef
21.
Zurück zum Zitat Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279(5350):548–552CrossRef Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279(5350):548–552CrossRef
22.
Zurück zum Zitat Dubinin MM (1965) Theory of the bulk saturation of microporous activated charcoals during adsorption of gases and vapors. Russ J Phys Chem 39:697–704 Dubinin MM (1965) Theory of the bulk saturation of microporous activated charcoals during adsorption of gases and vapors. Russ J Phys Chem 39:697–704
23.
Zurück zum Zitat Horvath G, Kawazoe K (1983) Method for calculation of effective pore size distribution in molecular sieve carbon. J Chem Eng Jpn 16:470–475CrossRef Horvath G, Kawazoe K (1983) Method for calculation of effective pore size distribution in molecular sieve carbon. J Chem Eng Jpn 16:470–475CrossRef
24.
Zurück zum Zitat Gregg SG, Sing KSW (1982) Adsorption Surface Area and Porosity. Academic Press, New York Gregg SG, Sing KSW (1982) Adsorption Surface Area and Porosity. Academic Press, New York
25.
Zurück zum Zitat Chen F, Xu XJ, Shen S, Kawi S, Hidajat K (2004) Microporosity of SBA-3 mesoporous molecular sieves. Microporus Mesoporus. Mater 75:231–235CrossRef Chen F, Xu XJ, Shen S, Kawi S, Hidajat K (2004) Microporosity of SBA-3 mesoporous molecular sieves. Microporus Mesoporus. Mater 75:231–235CrossRef
26.
Zurück zum Zitat Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380CrossRef Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380CrossRef
27.
Zurück zum Zitat Adolphs J (2007) Excess surface work—a modelless way of getting surface energies and specific surface areas directly from sorption isotherms. Appl Surf Sci 253:5645–5649CrossRef Adolphs J (2007) Excess surface work—a modelless way of getting surface energies and specific surface areas directly from sorption isotherms. Appl Surf Sci 253:5645–5649CrossRef
28.
Zurück zum Zitat Nemodruk AA, Karalova ZK (1965) Analytical chemistry of boron. Israel Program for Scientific Translations, Jerusalelm Nemodruk AA, Karalova ZK (1965) Analytical chemistry of boron. Israel Program for Scientific Translations, Jerusalelm
29.
Zurück zum Zitat Han J, Zhang LL, Lee S, Oh J, Lee KS, Potts JR, Park S (2012) Generation of B-doped graphene nanoplatelets using a solution process and their supercapacitor applications. ACS Nano 7(1):19–26CrossRef Han J, Zhang LL, Lee S, Oh J, Lee KS, Potts JR, Park S (2012) Generation of B-doped graphene nanoplatelets using a solution process and their supercapacitor applications. ACS Nano 7(1):19–26CrossRef
30.
Zurück zum Zitat Shcherban ND, Yaremov PS, Ilyin VG, Ovcharova MV (2014) Influence of the method of activation on the structural and sorption properties of the products of carbonization of sucrose. J Anal Appl Pyrol 107:155–164CrossRef Shcherban ND, Yaremov PS, Ilyin VG, Ovcharova MV (2014) Influence of the method of activation on the structural and sorption properties of the products of carbonization of sucrose. J Anal Appl Pyrol 107:155–164CrossRef
31.
Zurück zum Zitat Chung TM, Jeong Y, Chen Q, Kleinhammes A, Wu Y (2008) Synthesis of microporous boron-substituted carbon (B/C) materials using polymeric precursors for hydrogen physisorption. J Am Chem Soc 130:6668–6669CrossRef Chung TM, Jeong Y, Chen Q, Kleinhammes A, Wu Y (2008) Synthesis of microporous boron-substituted carbon (B/C) materials using polymeric precursors for hydrogen physisorption. J Am Chem Soc 130:6668–6669CrossRef
32.
Zurück zum Zitat Chen LF, Zhang XD, Liang HW, Kong M, Guan QF, Chen P, Wu Z-Y, Yu SH (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 6:7092–7102CrossRef Chen LF, Zhang XD, Liang HW, Kong M, Guan QF, Chen P, Wu Z-Y, Yu SH (2012) Synthesis of nitrogen-doped porous carbon nanofibers as an efficient electrode material for supercapacitors. ACS Nano 6:7092–7102CrossRef
33.
Zurück zum Zitat Lowell CE (1967) Solid solution of boron in graphite. J Am Ceram Soc 50:142–144CrossRef Lowell CE (1967) Solid solution of boron in graphite. J Am Ceram Soc 50:142–144CrossRef
Metadaten
Titel
Boron-doped nanoporous carbons as promising materials for supercapacitors and hydrogen storage
verfasst von
Nataliya Shcherban
Svitlana Filonenko
Pavel Yaremov
Vyacheslav Dyadyun
Igor Bezverkhyy
Vladimir Ilyin
Publikationsdatum
17.10.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 3/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0447-x

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